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http://dx.doi.org/10.7854/JPSK.2015.24.2.141

Evaluation of LA-ICP-MS Whole Rock Trace Element Analysis Using Fused Glass Bead of Silicate Rocks  

Kim, Myong Jung (Department of Earth Environmental Sciences, Pukyong National University)
Kim, Taehoon (Division of Polar Earth-System Sciences, Korea Polar Research Institute)
Park, Kye-Hun (Department of Earth Environmental Sciences, Pukyong National University)
Lee, Ye Ji (Department of Earth Environmental Sciences, Pukyong National University)
Yang, Yun Seok (Division of Polar Earth-System Sciences, Korea Polar Research Institute)
Moon, Jeongjin (Division of Polar Earth-System Sciences, Korea Polar Research Institute)
Publication Information
The Journal of the Petrological Society of Korea / v.24, no.2, 2015 , pp. 141-147 More about this Journal
Abstract
Using laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), we evaluated the reliability of trace element abundance data measured from the silicate rock references of JR-3, JG-3, JGb-1 and JB-1b using glass discs made by alkali fusion. For 28 elements including rare earth elements, relative standard deviations (RSD) are better than 7% in case when the concentrations of the elements in the rock samples are greater than 10 ppm. However, RSD shows somewhat increased values for the concentrations less than 10 ppm, but never exceeds 25%. Compared with previously reported averages of the compiled abundance data, our data display satisfactory results for the most cases with differences less than 10%. We suggest that LA-ICP-MS analysis using fused glass beads is a reliable, precise and time-saving method of trace element analysis for the silicate rocks spanning from mafic to felsic compositions.
Keywords
Trace element; Laser ablation; ICP-MS; Rock reference material;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
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1 Choi, M.-S., Cheong, C.-S., and Park, K.-H., 1994, An experimental study on the trace element analysis of rock samples with regard to the decomposition method. Journal of the Petrological Society of Korea, 3, 41-48. (in Korean with English abstract)
2 Guevara, M., Verma, S.P., and Velasco-Tapia, F., 2001, Evaluation of GSJ intrusive rocks JG1, JG2, JG3, JG1a, and JGb1 by an objective outlier rejection statistical procedure. Revista Mexicana de Ciencia Geolgicas, 18, 74-88.
3 Imai, N., Terashima, S., Itoh, S. and Ando, A., 1995, 1994 compilation values for GSJ reference samples, "Igneous rock series". Geochemical Journal, 29, 91-95.   DOI
4 Kil, Y. and Jung, H., 2015, LA-ICP-MS analysis of natural rock samples using XRF glass beads. Geosciences Journal, 19, 45-52.   DOI
5 Kim, T., Tanaka, T., Lee, S-G., Han, S., Yoo, I-S., Park, SB., Lee, J-I., 2014, Quantitative analysis of REEs in geological samples using ICP-MS: effect of oxide and hydroxide interference on REEs. Proceed. Annual Joint Conf., the Petrol. Soc. Korea and Min. Soc. Korea, 29-30. (Korean abstract)
6 Kon, Y., Murakami, H., Takagi, T., and Watanabe, Y., 2011, The development of whole rock analysis of major and trace elements in XRF glass beads by fsLA-ICPMS in GSJ geochemical reference samples. Geochemical Journal, 45, 387-416.   DOI
7 Kurosawa, M., Shima, K., Ishii, S., an Sara, K., 2006, Trace element analysis of fused whole-rock glasses by laser ablation-ICP-MS and PIXE. Geostandards and Geoanalytical Research, 30, 17-30.   DOI
8 Lee, S.-G., Kim, K.-H., Song, Y.S., and Kim, Y., 2005, A role of standard material in rare earth element analysis by ICP-MS. Journal of the Petrological Society of Korea, 14, 237-250. (in Korean with English abstract)
9 Lee, S.-G., Kim, T., Han, S., Kim, H.C., Lee, H.M., Tanaka, T., Lee, S.R., and Lee, J.I., 2014, Effect of zircon on rare-earth element determination of granitoids by ICPMS. Journal of the Petrological Society of Korea, 23, 337-349. (in Korean with English abstract)   DOI
10 Orihashi, Y. and Hirata, T., 2003. Rapid quantitative analysis of Y and REE abyndances in XRF glass bead for selected GSJ reference rock standards using Nd-YAG 266 nm UV laser ablation ICP-MS. Geochemical Journal, 37, 401-412.   DOI   ScienceOn
11 Park, C.-S., Shin, H.S., Oh, H., Moon, J.H., and Cheong, C.-S., 2011, Low dilution glass bead digestion technique for the trace element analysis of rock samples. Journal of the Petrological Society of Korea, 20, 161-172. (in Korean with English abstract)   DOI   ScienceOn
12 Terashima, S., Takiguchi, M., Mikoshiba, M., and Imai, N., 1998, Preparation of two new GSJ geochemical reference materials: basalt JB-1b and coal fly ash JCFA-1. Geostandards Newsletter, 22, 113-117.   DOI