• Title/Summary/Keyword: 암석화학

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Petrochemistry and magma process of Jurassic Boeun granodiorite in the central Ogcheon belt (중부 옥천대에 분포하는 쥬라기 보은 화강섬록암의 암석화학과 마그마과정)

  • 좌용주
    • The Journal of the Petrological Society of Korea
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    • v.5 no.2
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    • pp.188-199
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    • 1996
  • Boeun granodiorite, which intruded into the metasedimentary rocks of the Ogcheon Group, show chemical natures of metaluminous and calc-alkaline. Generating and emplacing environment of the Boeun granodiorite would have been a active continental margin. Comparing to the contemporaneous Inje-Hongcheon granodiorite in the Gyeonggi massif, the Boeun granodiorite seems likely to have formed under more immature continental arc environment. Compositional changes of major, trace and rare earth elements in granodiorite and felsic dyke are not certain to indicate crystallization differentiation. From this fact, the simple fractional crystallization model would be in question to explain the magma process which controlled the formation of the Boeun granitic mass. The model calculations for Rayleigh fractionation, fractionation with variable major-component composition, assimilation-fractional crystallization (AFC) were carried out to examine the magma process of the mass. The results of former two models do not agree with the compositional variations in the mass. The AFC model can be, however, applied to the magma process. The conditions for AFC process are (1) composition of assimilated wallrock is similar to that of primary magma. (2) assimilating rate is similar to crystallizing rate, and (3) mass of assimilated wallrock is about 10% of that of the magma. These conditions deny a possibility that the assimilated wallrock was the metasedimentary rocks of the Ogcheon Group. This indicates that after having experienced the assimilation process in deeper crust, the granodiorite magma intruded into the Ogcheon group. Every model calculating suggests that the felsic dyke was differentiated not from the granodiorite magma, but from a different source magma.

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Petrochemical Study of Igneous Rocks Occurring in the Northwestern Part of Keumsan Area, Chungnam-do (충남 금산군 서북부에 분포하는 화성암류에 대한 암석화학적 연구)

  • Kim, Won-Sa;Min, Kyoung-Nam
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.2 s.48
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    • pp.99-109
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    • 2006
  • Igneous rocks occurring in the northwesern part of Keumsan area, Chungcheongnam-do were studied petrogeochemically. The geology of this area is composed mainly of the Precambrian biotite gneiss, age-unknown Ogchon supergroup, Jurassic biotite granite, and Cretaceous volcanic rocks, pink feldspar granite and quartz porphyry. The biotite granite is gradually changes to leucocratic nature by going from center to periphery of the rock mass. It shows variation, with distance from the center, in chemical components: $SiO_2,\;Na_2O\;and\;K_2O$ increase, whereas $Fe_2O_3,\;CaO,\;P_2O_5,\;MgO,\;and\;TiO_2$ decrease. Based on geochemical data, the biotite granite and quartz porphyry belong to subalkaline series and I-type. They show calc-alkaline differentiation trend. The biotite granite shows little negative Eu-anomaly pattern, whereas quartz porphyry show marked negative Eu-anomaly pattern, indicating that quartz porphyry was evolved further, when compared with biotite granite.

Variation of Geomechanical Characteristics of Granite and Orthogneiss in Wonju Area due to Accelerated Artificial Chemical Weathering Tests (강원도 원주일대에 분포하는 화강암 및 화강편마암의 화학풍화실험에 의한 물성 변화 연구)

  • Woo, Ik;Um, Jeong-Gi;Park, Hyuck-Jin
    • Tunnel and Underground Space
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    • v.19 no.3
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    • pp.213-225
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    • 2009
  • The purpose of the study is to evaluate the effects of chemical weathering on the granite and orthogneiss in Wonju area based on accelerated artificial chemical weathering. The rock samples were scrutinized the variation of index properties and ion exchanges caused by artificial chemical weathering which was implemented with leaching test for 170 days using double soxhlet extractor. The differential weathering and decrease of p wave velocity were obtained by weathering process without significant changes of porosity. In case of granite samples, the uniaxial compression strength was reduced by 20% and 16% for the F-grade and SW-grade, respectively. For MW-grade granite, however, was not able to examine the effect of strength reduction due to lack of sample number. Also, for orthogneiss, it is difficult to compare the values of uniaxial compressive strength between before and after the test because of its strong anisotropy.

Characteristics of surface pollutants on stone materials and its cleaning measures in Gyeongju Soekbinggo (경주석빙고 구성석재에 형성된 표면오염물의 특징과 그 제거방안)

  • Do, Jinyoung
    • 한국문화재보존과학회:학술대회논문집
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    • 2005.03a
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    • pp.71-88
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    • 2005
  • With biological organism brown pollutants layers are thickly formed on inner stone materials in Gyeongjuseokbinggo(Ice storage in Gyeongju). Some simples were taken from this layer and its chemical composition, mineral composition, salt and microstructures were analyzed. This study shows that the pollutants layer can be removed easily, because it attached softly in stone surface. But because of its serious weathering state the stone surface also can be removed during the removing process. The origins of brown layer are assumed to be the soil in the mound over the Seokbinggo and the coarse sandy soil in the entrance. For the preservation of the Seokbinggo Waterproof and replacement of the coarse sandy soil should take precedence over the remove works. Subsequently moistureproof works should be enforced.

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Petrochemical Characteristics and Review on Petrogenesis on Cretaceous to Tertiary Volcanic Rocks in the Kyongsang Basin (경상분지 백악기~제3기 화산암류의 암석화학적 특징과 암석 성인 고찰)

  • Sung, Jong-Gyu;Kim, Jin-Seop
    • The Journal of the Petrological Society of Korea
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    • v.21 no.2
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    • pp.217-233
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    • 2012
  • Major elements abundances of Cretaceous to Tertiary volcanic rocks in Kyongsang basin are similar with Southern Volcanic Zone (SVZ) in Andes. Sr, K, Rb, $Ba{\pm}Th$ abundances, which have low ionic charge, are selectively fertile, on the other hand Ta, Nb, Ce, P, Zr, Hf, Sm, Ti, Y, Yb, Sc, Cr abundances are low. K, Sr, Th show characteristic spikes and Nb show remarkable trough on trace elements spider diagram. Trace elements abundances are higher than that of Andes which is supposed to mantle sources of Kyongsang basin volcanic rocks are produced lower degree of partial melting than SVZ in Andes.

Geochemical Study on Geological Groups of Stream Sediments in the Gwangju Area (광주지역 하상퇴적물에 대한 지질집단별 지구화학적 연구)

  • Kim, Jong-Kyun;Park, Yeung-Seog
    • Economic and Environmental Geology
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    • v.38 no.4 s.173
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    • pp.481-492
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    • 2005
  • The purpose of this study is to determine geochemical characteristics for stream sediments in the Gwangju area. We collect the stream sediments samples by wet sieving along the primary channels and dry these samples slowly in the laboratory and grind to under 200mesh using an alumina mortar fur chemical analysis. Major elements, trace and rare earth elements are determined by XRF, ICP-AES and NAA analysis methods. For geochemical characteristics on geological groups of stream sediments, we separate geologic groups which are derived from Precambrian granite gneiss area, Jurassic granite area and Cretaceous Hwasun andesite area. Contents range of major elements for stream sediments in the Gwangju area are $SiO_2\;51.89\~70.63\;wt.\%,\;Al_2O-3\;12.91\~21.95\;wt.\%,\;Fe_2O_3\;3.22\~9.89\;wt.\%,\;K_2O\;1.85\~4.49\;wt.\%,\;MgO\;0.68\~2.90\;wt.\%,\;Na_2O\;0.48\~2.34\;wt.\%,\;CaO\;0.42\~6.72\;wt.\%,\;TiO_2\;0.53\~l.32\;wt.\%,\;P_2O_5\;0.06\~0.51\;wt.\%\;and\;MnO\;0.05\~0.69\;wt.\%.$ According to the AMF diagram for stream sediments and rocks, the stream sediments are plotted on boundary of tholeiitic series and calk alkaline series, which shows that contents of $Fe_2O_3$ are higher in stream sediments than rocks. According to variation diagram of $SiO_2$ versus $(K_2O+Na_2O),$ stream sediments are plotted on subalkaline series. Contents range of trace and rare earth elements for stream sediments in the Gwangiu area are Ba$590\~2170$ppm, Be1\~2.4$ppm, Cu$13\~79$ppm, Nb$20\~34$ppm, Ni$10\~50$ppm, Pb$17\~30$ppm, Sr$70\~1025$ ppm, V$42\~135$ppm, Zr$45\~171$ppm, Li$19\~77$ppm, Co$4.3\~19.3$ppm, Cr$28\~131$ppm, Cs$3.1\~17.6$ppm, Hf$5\~27.6$ppm, Rb$388\~202$ppm, Sb$0.2\~l.2$ ppm, Sc$6.4\~17$ppm, Zn$47\~389$ppm, Pa$8.8\~68.8$ppm, Ce$62\~272$ppm, Eu$1\~2.7$ppm and Yb$0.9\~6$ppm.

Petrogenetic Study on the Foliated Granitoids in the Chonju and the Sunchang Area(I) -In the Light of Petrochemical Properties- (전주 및 순창지역에 분포하는 엽리상화강암류의 성인에 대한 연구(I) - 암석지화학적 특성을 중심으로 -)

  • Na, Choon-Ki;Lee, In-Sung;Chung, Jae-Il
    • Journal of the Korean earth science society
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    • v.18 no.6
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    • pp.480-492
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    • 1997
  • In order to understand the processes involved in the petrogenesis and the differentiation of the primary magma spectrum, a petrological and geochemical properties were investigated for the Chonju and the Sunchang foliated granites, which are located in the southwestern part of the Okchon zone and extends up to the northwestern boundary of the Ryongnam massif as two subparallel batholiths. Major element analyses show that the Chonju and Sunchang foliated granites are classified petrologically into a weakly to strongly peraluminous or calc-alkaline, but do not fit neatly into either of the I/S-type or magnetite/ilmenite-series classification schemes for granites, although the I-type and magnetite-series characteristics seem to be predominant based on the major element chemistry. In normative compositions, the Chonju granite is petrographically evolved from granodiorite to granite, whereas the Sunchang granite is from granodiorite to quartz monzodiorite. It seems to suggest a difference of the magmatic evolution processes such as crustal assimilation and/or fractional crystallization in magma. The REE patterns of both batholiths show high similarity and strongly fractionated REE distributions which show high $(Ce/Yb)_N$ ratios and little or no Eu anomalies. These REE patterns correspond broadly to those seen in the pre-Cretaceous granitoids of Korea. Apparently, the evidences obtained from the bulk compositions strongly suggest that the two foliated granitoids were formed by partial meltings of a relatively restricted and similar, may be common, source material which contains a continental crust component having an igneous composition, and have undergone a similar magmatic differentiation processes.

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The Study on Weathering Hollows Developed on the Coast of Dapyeong-ri, Sacheon-si (사천시 다평리 해안에서 발달한 풍화혈에 관한 연구)

  • Tak, Hanmyeong
    • Journal of the Korean Geographical Society
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    • v.50 no.5
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    • pp.459-472
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    • 2015
  • Weathering hollows which develop on various rocks are the terrain whose lithological characteristics and formation of the bed rock is under active discussion. The shore in Dapyeong-ri, Sacheon-si has alternation of strata of pelite and sandstone, and the weathering hollows develop on the shore platform and the sea cliff where sandstone is exposed. To analyze the development characteristics of weathering hollows by development of joints, interpenetration of veins and physical and chemical features of the stone, the study conducted a topographic investigation, XRD analysis and an observation using a polarizing microscope. As the result of the investigation and analysis, tafoni and gnamma are spread in the same area and new tafoni is being formed as the existing weathering hollows are destroyed by the expansion and growth of the joint. The vein, which was found to be a quartz vein, may accelerate the development of weathering hollows combining with the joint but may also hamper their growth if the veins are penetrating perpendicularly. It is generally known that weathering hollows develop regardless of the type of rocks, however, the analysis on the lithological features show that the development is limited on the fractured and broken rocks.

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A Study on Characteristics of Jointed Rock Masses and Thermo-hydro-mechanical Behavior of Rock Mass under High Temperature (방사성 폐기물 저장을 위한 불연속 암반의 특성 및 고온하에서의 암반의 수리열역학적 상호작용에 관한 연구)

  • 이희근;김영근;이희석
    • Tunnel and Underground Space
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    • v.8 no.3
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    • pp.184-193
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    • 1998
  • In order to dispose radioactive wastes safely, it is needed to understand the mechanical, thermal, fluid behavior of rockmass and physico-chemical interactions between rockmass and water. Also, the knowledge about mechanical and hydraulic properties of rocks is required to predict and to model many conditions of geological structure, underground in-situ stress, folding, hot water interaction, intrusion of magma, plate tectonics etc. This study is based on researches about rock mechanics issues associated with a waste disposal in deep rockmass. This paper includes the mechanical and hydraulic behavior of rocks in varying temperature conditions, thermo-hydro-mechanical coupling analysis in rock mass and deformation behavior of discontinuous rocks. The mechanical properties were measured with Interaken rock mechanics testing systems and hydraulic properties were measured with transient pulse permeability measuring systems. In all results, rock properties were sensitive to temperature variation.

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Quantitative Analysis and Archaeogeological Interpretation of Stone Implements from the Unjeonri Bronze Age Relic Site (천안 운전리 청동기 유적지에서 출토된 석기의 정량분석과 고고지질학적 해석)

  • Lee, Chan Hee;Oh, Kuy Jin;Lee, Hyo Min;Lee, Myeong Seong
    • Journal of Conservation Science
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    • v.12 no.1 s.15
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    • pp.31-47
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    • 2003
  • The stone implements from the Unjeonri relic sites were studied on the basis of petrology, geochemistry and archaeogeological interpretations. Magnetic susceptibility (MS) of the stone implements were mainly lest than 0.5 $(10^{-3}\;SI\;unit)$, however, stone axe of syenitic rock (2.37), stone axe of schist (0.19) and stone knife of slate (0.11) showed different from the some measured rocks of an outcrop. Geochemical evolution trend of both a stone implement and the surface rock were identical when it a normalization to use the behavior, enrichment, compatibility and incompatibility of the elements. But, some rocks of a axe (schist), a knife (slate), a arrowhead (shale) could not confirm typical occurrence and the distribution area within the Unjeonri site and a radius 10 km. In the Unjeonri site, the stone implements suggest that coexisting two types as domestic- and foreign-type lithic artifacts.

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