• 제목/요약/키워드: 알칼리-골재 반응

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A Case Study for Deterioration due to Alkali-Silica Reaction in the Cement Concrete Pavement (알칼리-실리카 반응에 의한 시멘트 콘크리트 포장 파손 사례)

  • Hong, Seung-Ho;Han, Seung-Hwan;Yun, Kyong-Ku
    • Journal of the Korea Concrete Institute
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    • 제18권3호
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    • pp.355-360
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    • 2006
  • The Alkali-Silica Reaction(ASR) may cause a serious failure in the concrete pavements and structures. Several researches in some nations have conducted the continuous studies to prevent failure of the concrete structures by the ASR distress as well as the studies to manifest the mechanism. The researches on the ASR have not been performed affluently in Korea because the distress due to ASR has seldom been reported literarily. In this study, we tried to set up the systematic scheme practically for verifying the cause of distress due to ASR by using the visual inspections in field, the chemical method, petrographic analysis, and Electron Dispersive X-ray Spectrometer(EDX) method of Scanning Electron Microscopy(SEM) in laboratory. The chemical method, petrographic method using SEM, and X-ray method were used to verify the cause of pattern crack on the surface and internal crack in the plain concrete pavement. It can be concluded that the distress of a specific site in plain concrete pavement was mainly due to ASR. The chemical method, the petrographic method and EDX method using SEM may be the effective tools for verifying the cause of AAR distresses.

Properties of High Volume Blast Furnace Slag Concrete using Recycled Aggregate with Incineration Waste Ash (소각장애시의 치환에 따른 고로슬래그 미분말 다량치환 순환골재 콘크리트의 특성)

  • Han, Cheon-Goo;Lee, Hyang-Jae;Kim, Jun-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • 제1권2호
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    • pp.107-113
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    • 2013
  • This study is the study desiring to solve the problem by utilizing the kinds of recycled resources considered to be troubled complementarily. Namely the reaction of potential hydraulicity of Blast Furnace Slag Powder (BS) shall be reacted with the alkali of Recycled Fine Aggregates Coarse Aggregate, it has been experimented to obtain the optimum value with the replacement ratio of incineration plant ash (WA) treated with the slaked lime as the experiment variable by solving the alkali of shortage with the Ordinary Portland Cement (OPC). As a result, the liquidity and the air volume are declined slightly as the replacement ratio of incineration plant ash WA increases, the mixture of incineration plant ash WA 1% has been analyzed to be the most suitable considering the viewpoint of effective handling of waste as the compression and the tensile strength showed the maximum value before and after 1% even though it was disadvantageous with the increase of chloride content.

Performance Evaluation of Admixture for Durability Improvement of Shielding Materials Used Waste Glass as Fine Aggregate (폐유리를 잔골재로 사용한 차폐채움재의 내구성 개선을 위한 혼화재료의 성능평가)

  • Hwang, Byoung-Il;Kim, Hyo-Jung;Song, Yong-Soon;Yi, Seong-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • 제23권2호
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    • pp.20-27
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    • 2019
  • Compared to the development and manufacturing technology of electronic goods, the development of waste glass recycling technology is relatively insufficient, leading to the acceleration of waste of resources and environmental pollution. Although waste glass recycling technology is being actively developed overseas, waste glass recycling technology is insufficient in Korea, leading to the illegal dumping or burial of waste glass. Waste glass has been confirmed to have pozzolan reaction potential when having hydration reaction with cement. Waste glass is also reported to be effective in reducing bleeding and inhibiting the development of hydration heat by improving the physical properties of concrete and the rheology properties of fresh concrete. Therefore, this paper analyzed the strength characteristics and the effect of alkalic-silica reaction on the expansion of shielding concrete that used waste glass as fine aggregate. Where, suitable admixture materials were used as a measure to suppress the expansion.

Carbonation Mechanism of Hydrated Cement Paste by Supercritical Carbon Dioxide (초임계 이산화탄소에 의한 시멘트 페이스트의 중성화 반응 메커니즘)

  • Park, Jeong-Won;Kim, Ji-Hyun;Lee, Min-Hee;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • 제18권5호
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    • pp.403-412
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    • 2018
  • Recently, needs for utilization of recycled aggregate have been increasing. However, its utilization has been limited due to its high alkalinity, which mostly came from the unremoved cement paste particles that were attached at the surface of recycled aggregate. Various efforts has been made to reduce its alkalinity by using $CO_2$, but currently available methods that uses $CO_2$ generate the problem with pH recovery. Considering the fact that supercritical $CO_2$ ($scCO_2$) can provide more rapid carbonation of cement paste than by normal $CO_2$, $scCO_2$ was utilized in this work. The reaction between $scCO_2$ and hydrated cement paste has been systematically evaluated. According to the results, it was found that powder type showed higher carbonation compared to that of cube specimens. It seems the carbonation by $scCO_2$ has occurred only at the surface of the specimen, and therefore still showed some amount of $Ca(OH)_2$ calcium aluminates after reaction with $scCO_2$. With powder type specimen, all $Ca(OH)_2$ was converted into $CaCO_3$. Moreover, additional calcium that came from both calcium aluminate hydrates and calcium silicate hydrates reacted with $scCO_2$ to form $CaCO_3$. After carbonation with $scCO_2$, the powder type specimen did not show pH recovery, but cube specimens did show due to the presence of portlandite.

Alkali-Silica Reaction of Mortar Containing Waste Glass Aggregates (폐유리 골재를 혼입한 모르터의 알칼리 실리카 반응에 관한 연구)

  • 박승범;이봉춘;권혁준
    • Journal of the Korea Concrete Institute
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    • 제13권3호
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    • pp.213-220
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    • 2001
  • Incorporation of wastes glass aggregate in mortar may cause crack and this may result in the strength reduction due to alkali-silica reaction(ASR) and expansion. The purposes of this study were to investigate the properties of alkali-silica expansion and strength loss through a series of experiments which had a main experimental variables such as waste glass aggregate contents, glass colors, fiber types, and fiber contents. The steel fibers and polypropylene fibers were used for constraining the ASR expansion and mortar cracking. From the result, green waste glass was more suitable than brown one because of low expansion. And in this accelerated ASTM C 1260 test of waste glass, pessimum content can not be found. Also, when used the fibers with waste glass, there is an effect on reduction of expansion and strength loss due to ASR between the alkali in the cement paste and the silica in the waste glass. Specially, adding 1.5 vol.% of steel fiber to 20% of waste glass, the expansion ratio was reduced by 40% and flexural strength was developed by up to 110% comparing with only waste glass(80$\^{C}$ H$_2$O curing).

Property change of geopolymers after immersion (지오폴리머의 침지 후 물성변화)

  • Kim, Hakmin;Kim, Yootaek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • 제31권6호
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    • pp.247-257
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    • 2021
  • This study was started to investigate why autoclave curing (AC) specimen showed an improvement in compressive strength after immersion in water for a long time, although AC specimen did not showed a high initial compressive strength unlike our expectations. Distilled water and alkaline solutions were used for immersion and three different curing methods were engaged. It was expected that the compressive strength would be improved after immersion in alkaline solutions; however, there was little difference in compressive strength after 21 day immersion because both new crystallites produced by additional geopolymerization and expansion caused by the alkaline aggregate reaction may prevent the additional improvement in compressive strength. It was concluded that in order to secure the long-term commonality and underwater stability of the geopolymers, it is desirable aging geopolymers while immersing it underwater for more than 21 days after curing using an autoclave.

Mechanism of change in compressive strength of geopolymers by immersion method (침지방법에 따른 지오폴리머의 압축강도 변화 메커니즘)

  • Kim, Hakmin;Kim, Yootaek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • 제32권2호
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    • pp.68-76
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    • 2022
  • This study was performed to investigate the mechanism of the change in compressive strength of autoclave cured geopolymers. Specimens were immerged in distilled water, 2M, 8M, and 14M alkaline solutions for 3, 7, and 21 days. The change in the specimens immersed in a short period of time was not significant, but the compressive strength of the specimens immersed in the distilled water and 8M alkali solution) for 21 days increased more than twice as much as before immersion because of additional geopolymerization. However, compressive strength decreased due to the alkaline aggregate reaction when alkaline solution was supplied more than a certain level of concentration. Therefore, immersing the specimens for more than 21 days in the distilled water or 8M alkaline solution would be desirable for the improvement of compressive strength of autoclave cured specimens.

A Study on the Strength Property of Recycled Fine Aggregate (Wet Type) Mortar with Blast Furnace Slag (고로슬래그를 사용한 습식 순환 잔골재 모르타르의 강도 특성에 관한 연구)

  • Shim, Jong-Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • 제14권5호
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    • pp.153-160
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    • 2010
  • This study aims to obtain technical data for improvement of utilization of Blast Furnace Slag(BFS), recycled aggregate in the future by complementing fundamental problems of BFS such as manifestation of initial strength and excessive alkali quantity as well as weakness of recycled fine aggregate through manufacturing of recycled fine aggregate mortar using BFS. The recycled aggregate includes the cement paste hardened as the surface and the type of the aggregate, which contains plenty of calcium hydroxide($Ca(OH)_2$) as well as the unhydrated cement. Accordingly, the objectives of this study are to inspect the manufacturing the recycled fine aggregate mortar used with blast furnace slag, to consider the effects of the recycled aggregate on the strength development of ground granulated blast furnace slag, and then to acquire the technical data to take into consideration the further usages of the recycled aggregate and blast furnace slag. In eluted ions from recycled aggregate, it showed that there were natrium($Na^+$) and kalium($K^+$), expected to be flown out of unhydrated cement, as well as calcium hydroxide($Ca(OH)_2$). Application of this water to mix cement mortar with ground granulated blast furnace slag was observed to expedite hydration as calcium hydroxide($Ca(OH)_2$) and unhydrated cement component were expressed to give stimuli effects on ground granulated blast furnace slag. The results of the experiment show that the recycled aggregate mixed with blast furnace slag has comparatively higher hydration activity in 7 day than the mortar not mixed with one in 3 day mortar does, causing the calcium hydroxide in the recycled fine aggregate to work on as a stimulus to the hydration of ground granulated blast furnace slag.

Petrographic Analysis for the Alkali-aggregate Reactivity (알칼리 골재의 반응성에 관한 광물학적 분석)

  • 김해인;이장화;심재황;임명혁
    • Proceedings of the Korea Concrete Institute Conference
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    • 한국콘크리트학회 1989년도 가을 학술발표회 논문집
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    • pp.1-4
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    • 1989
  • Recently, as the natural aggregates are exhausted, using the crashed stones bring the possibility of the alkali-aggregate reactivity. In this study, the samples are collected from the stony moutains chosen by using a geoligical survey map and analyzed in terms of the amount and the shape of the reaction minerals by a polarization microscope and X-ray diffraction which beling to the petrographic examination of aggregates for concrete. From this study, most samples of the sedimentary rocks and the granitte of the ignious rocks show the possibility of the alkali-aggregate reactivity.

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Effectiveness of Silica Fume on Alkali-Silica Reaction in the Presence of Sodium Chloride and Sea Water (해수 및 염화 나트륨이 공급되는 환경에서 실리카 흄의 알칼리-실리카 반응에 대한 억제 효과)

  • 김창길;삼포상;강원호
    • Magazine of the Korea Concrete Institute
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    • 제10권5호
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    • pp.129-137
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    • 1998
  • 본 연구에서는 해수 및 염화나트륨이 공급되는 환경에서 실리카 흄의 알칼리실리카 반응에 대한 억제효과를 구명한 것이다. 연구에 사용된 염화나트륨 농도는 2.8%, 10%, 20%여Tdmaum 반응성 골재는 일본산 안산암이었다. 실리카 흄은 노르웨이산으로 비표면적인 20$m^2$/g인 것을 사용했다. 실리카 흄의 치환율은 시멘트 중량에 대해 5%, 7%, 10%로 하였다. 연구결과, 20%의 염화나트륨이 공급되는 환경에서 알칼리실리카반응에 의한 유해한 팽창이 억제는 본 연구에서 사용된 실리카 흄의 경우, 치환율 % 이상에서 달성되었다.