• Title/Summary/Keyword: 알칼리 결합재

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Properties of Alkali Activated Inorganic Binder using Replacement Materials Alkali Activator with Red Mud (알칼리 자극제 대체재로써 레드머드를 사용한 알칼리 활성 무기결합재의 특성)

  • Park, Sun-Gyu
    • Proceedings of the Korea Contents Association Conference
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    • 2014.11a
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    • pp.139-140
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    • 2014
  • 최근 건선산업에서 문제점으로 지적되고 있는 것은 제조과정 중 이산화탄소를 다량 방생시키는 시멘트의 사용이다. 이는 알칼리활성 무기결합재로 대체함으로써 시멘트보다 이산화탄소 배출량을 저감할 수 있지만 고가의 알칼리 자극제를 다량 사용하기 때문에 경제적 측면 및 사용성을 고려하지 않으면 사용할 수 없기 때문에 이에 대한 대체재에 관한 연구가 필요한 실정이다. 이에 본 연구에서는 고로슬래그를 기반으로 하는 알칼리 활성 무기결합재에 알칼리 자극제의 사용량을 저감하기 위해 레드머드를 사용하고, 레드머드에 적합한 알칼리 자극제의 종류와 사용방법에 대하여 연구하고자 하였다.

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Evaluation of Absorbent-Pervious Alkali-Activated Block Using Recycled Aggregate (순환골재를 이용한 보투수성 알칼리 결합재 블록의 성능평가)

  • Park, Kwang-Min;Kim, Hyung-Suk;Cho, Young-Keun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.2
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    • pp.160-167
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    • 2017
  • The purpose of this study is to identify the possibility of developing the 100% Recycled-resources Absorbent-Pervious Alkali-activated Blocks using both the alkalli-binder and the recycled aggregate. In addition, It established a test method such as Void ratio, compressive strength, coefficient permeability, absorption, and evaporation. As a result, an alkali-activated using recycled aggregate block was able to manufacture an 24 MPa class absorbent-pervious blocks with a liquid type sodium silicate and early high temperature curing. In this case, water-holding capacity, absorption and relative absorption were more effective than the natural aggregates. In conclusion, Absorbent-pervious alkali-activated Block Using recycled aggregate has a surface temperature reducing effect of approximately 10 % compared to ordinary concrete block.

Effect of the Combined Using of Fly Ash and Blast Furnace Slag as Cementitious Materials on Properties of Alkali-Activated Mortar (결합재(結合材)로 플라이애시와 고로(高爐)슬래그의 혼합사용(混合使用)이 알칼리 활성(活性) 모르타르의 특성(特性)에 미치는 영향(影響))

  • Koh, Kyung-Taek;Kang, Su-Tae;Park, Jung-Jun;Ryu, Gum-Sung;Lee, Jang-Hwa;Kang, Hyun-Jin
    • Resources Recycling
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    • v.19 no.4
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    • pp.19-28
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    • 2010
  • Attempts to increase the utilization of a by-products such as fly ash and blast furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. However, most study deal only with alkali-activated blast furnace slag or fly ash, as for the combined use of the both, little information is reported. In this study, we investigated the influence of mixture ratio of fly ash/slag, type of alkaline activator and curing condition on the workability and compressive strength of mortar in oder to develop cementless alkali-activated concrete. In view of the results, we found out that the mixture ratio of fly ash/slag and the type of alkaline activator always results to be significant factors. But the influence of curing temperature in the strength development of mortar is lower than the contribution due to other factors. At the age of 28days, the mixture 50% fly ash and 50% slag activated with 1:1 the mass ratio of 9M NaOH and sodium silicate, develop compressive strength of about 65 MPa under $20^{\circ}C$ curing.

Mechanical Properties of Alkali Treated Kenaf Fiber Filled PP Bio-Composites (알칼리 처리된 Kenaf 섬유가 충전된 Polypropylene/Kenaf 바이오복합재의 기계적 특성)

  • Kim, Samsung;Lee, Byoung-Ho;Kim, Hyun-Joong;Oh, Sei Chang;Ahn, Sye-Hee
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.3
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    • pp.222-230
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    • 2009
  • This study was to investigate the effect of alkali treatment for long kenaf fiber to improve fiber surface characterics by removal of wax, lignin and hemicellulose which affect adversely for matrix union. SEM observation was also studied to check out the interface adhesion improvement by the alkali pre-treatment. From the result, interface coherence increased by 3% alkali pre-treatment and reached a maximum by 5% alkali pre-treatment. However, the 3% the bio-composites treated with 3% alkali was highest tensile and flexural strength than other.

Properties of the Flowability and Strength of Cementless Alkali-Activated Mortar Using the Mixed Fly Ash and Ground Granulated Blast-Furnace Slag (플라이애쉬와 고로슬래그 미분말의 혼합 사용한 무시멘트 알칼리 활성 모르터의 유동성 및 강도 특성)

  • Koh, Kyung-Taek;Ryu, Gum-Sung;Lee, Jang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.114-121
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    • 2010
  • Portland cement production is under critical review due to high amount of CO2 gas released to the atmosphere. Attempts to increase the utilization of a by-products such as fly ash and ground granulated blast-furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. However, most study deal only with alkali-activated ground granulated blast furnace slag or fly ash, as for the combined use of the both, little information is reported. In this study, we investigated the influence of mixture ratio of fly ash/ blast furnace slag tand curing condition on the flowability and compressive strength of mortar in oder to develop cementless alkali-activated concrete. In view of the results, we found out that the mixture ratio of fly ash/blast furnace slag always results to be significant factors. But the influence of curing temperature in the strength development of mortar is lower than the contribution due to other factors. At the age of 28days, the mixture 50% fly ash and 50% ground granulated blast furnace slag activated with 1:1 the mass ratio of 9M NaOH and sodium silicate, develop compressive strength of about 65 MPa under $20^{\circ}C$ curing.

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Isothermal Conduction Calorimetry Analysis of Alkali Activated Slag Binder (알칼리 활성 슬래그 결합재의 미소수화열 분석)

  • Choi, Young-Cheol;Cho, Hyun-Woo;Oh, Sung-Woo;Moon, Gyu-Don
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.3
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    • pp.237-243
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    • 2015
  • In this research, isothermal conduction calorimetry analysis has been conducted to investigate the reactivity of alkali activated slag binders. In order to secure the reactivity and workability of alkali activated slag binders, experiences with various types and concentrations of alkali activators were performed. Isothermal conduction calorimetry were measured with different alkali activators and mass ratio of $SO_3$ to binders as variables, and sodium tripolyphosphate ($Na_2P_3O_{10}$) and hydrated sodium borate ($Na_2B_4O_710H_2O$) were used to control setting time. As a results, alkali activated slag binders required alkali activators with 4 to 5 percent of concentration to accelerate the formation of calcium silicate hydrate(C-S-H) by alkali-activation, and overall heat generation rate delayed as accumulated heat decreased due to the high $SO_3$ contents. Moreover, the use of hydrated sodium borate as setting retarder causes elongated setting time due to delaying heat generation, so it can be considered that setting retarder played an important role in delaying total heat generation rate.

Analysis of Internal Structure in Alkali-Activated Fire Protection Materials Using Fly ash (플라이애시를 활용한 알칼리 활성화 내화성 마감재의 내부구조 분석)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.104-112
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    • 2012
  • This study involves investigating the correlation between variation of internal structure and heating temperature of alkali-activated fire protection materials using fly ash. Dehydration and micro crack thermal expansion occur in cement hydrates of cementitious materials heated by fire. Internal structure difference due to both the dehydration of cement hydrates and pore solution causes and influences changes in the properties of materials. Also, this study is concerned with change in microstructure and dehydration of the alkali-activated fire protection materials at high temperatures. The testing methods of alkali-activated fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. The study results show that the alkali-activated fire resistant finishing material composed of potassium hydroxide, sodium silicate and fly ash has the high temperature thermal stability. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction.

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The Estimation of Optimal Mixing Ratio of CLSM Mixed with Red Mud and Paper Sludge Ash (Red mud와 제지회를 혼합한 CLSM의 적정 혼합비 산정)

  • Roh, Seongoh;Kim, Taeyeon;Lee, Bongjik
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.4
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    • pp.21-27
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    • 2022
  • Recently, numerous studies are being performed to examine alkali-activated cement which uses industrial by-products, such as GGBS and fly ash, as well as alkali activators. Alkali-activated cement is a type of binder that exerts the same strength as cement without using cement by mixing industrial by-products with alkali activators. Alkali activators, which are used mainly for carbon-reducing technologies and alkali activation, are expensive and difficult to apply in the field due to risks related to strong alkalinity. Therefore, this study intends to explore methods to use red mud as a substitute for an alkali activator. To that end, this study has evaluated engineering properties, such as flow and strength, of CLSM that uses red mud and paper sludge ash as binders and its possibility to cause soil pollution. This study also aims to present the appropriate mixing ratios of red mud and paper sludge ash to produce CLSM.

Strength Development Properties of Alkali-Activated Slag Mortar by Curing Conditions (양생조건에 따른 알칼리활성슬래그 모르타르의 강도발현 특성)

  • Song, Jin-Gyu;Kim, Byeong-Jo;Oh, Myeong-hyeon
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2015.07a
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    • pp.216-217
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    • 2015
  • This study consist of research on the strength development properties of alkali activated slag(AAS) by differential combination of activators, initial protecting and curing conditions. 3 type of binders cured in the atmosphere, underwater and sealed were estimated compressive strength of 3, 7 and 28 days. Test results showed that strength development properties of binders varied with initial protecting and curing conditions because of ionized anions in pore water.

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The Mechanics Characteristics of Alkali-Activated Mortar by Brain of Blast Furnace Slag (고로슬래그 분말도에 따른 알칼리 활성 모르타르의 역학적 특성)

  • Kang, Hyun-Jin;Ko, Kyung-Taek;Ryu, Gum-Sung;Kang, Su-Tae;An, Gi-Hong;Lee, Jang-Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.393-394
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    • 2009
  • Recently, various researchers have studied alkali-activated concrete that do cementless as the binder. This study analyzed the effect on alkali-activated mortar by fineness of blast slag as the binder with no use of cement, by observing workability and compressive strength.

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