• Title/Summary/Keyword: 알칼리제

Search Result 427, Processing Time 0.024 seconds

The effects of some additives on Methane Fermentation of Paper Mill Sludge treated with Alkali (알칼리 처리된 제지슬러지의 메탄발효에 미치는 몇몇 첨가제의 효과)

  • Choi, Jong-Woo;Lee, Kyu-Seung;Park, Seung-Heui
    • Korean Journal of Agricultural Science
    • /
    • v.22 no.2
    • /
    • pp.134-142
    • /
    • 1995
  • In order to elevate the efficiency of methane fermentation using the paper mill sludge, this experiment was conducted at two temperature conditions($35^{\circ}C$ and $60^{\circ}C$), and overlooked the addition effects of ethyl acetate as a substrate, nickel as a constituent of $F_430$, and sulfur as a cell growth factor and reductant. The cellulose of paper mill sludge was degraded to lower molecular materials by heating at $60^{\circ}C$ and NaOH treatment. Methane forming rates were 4.8% from NaOH-treated paper mill sludge added with ethyl acetate, 16.5% with sodium sulfide, 19.8% with nickel trioxide, 31.9% with mixture, and 9.6% with control at $60^{\circ}C$, but 0.21% with ethyl acetate, 2.14% with nickel acetate, 3.02% with nickel sulfate, 3.34% with nickel trioxide and 0.62% with control at $35^{\circ}C$. Therefore, methane yield was increased by approximately 10-fold at $60^{\circ}C$ than $35^{\circ}C$, and fermentation liquid added with mixture(nickel trioxide+ethyl acetate+sodium sulfide) at $60^{\circ}C$ showed the medium pH(7.0), higher COD value and lower nitrogen content.

  • PDF

Deterioration Assessment and Structural‐Reinforcement of Stone Lantern of the Four Guardian Kings in Beopjusa Temple, Boeun (보은 법주사 사천왕석등의 비파괴 훼손도 평가 및 구조보강)

  • Choie, Myoungju;Lee, Myeong Seong;Jun, Yu Gun;Lee, Mi Hye;Kim, Yuri;Ha, Jun Kyeong
    • Journal of Conservation Science
    • /
    • v.33 no.1
    • /
    • pp.25-33
    • /
    • 2017
  • The stone lantern of the four guardian kings in the Beopjusa temple at Boeun was mainly made of biotite granodiorite consisting of porphyritic-textured potassium feldspar and included in ilmenite series. A base stone made of alkali granite was buried, after founded its place during an earlier restoration process. Cracking and break out are noticeable on this object. In addition, discoloration, salt crusting, and epiphytes were observed. The lantern was vulnerable in terms of physical and structural stability caused by cracking in the front and back of the light chamber and in the non-horizontal direction. According to the conservational condition of the stone lantern, structural reinforcement was carried out based on calculations, including those on the position, size, and anchor length of the titanium stiffener. Chemical and biological pollutants were washed off without damage to the surface of the stone material. Oxygenated iron pieces were replaced with titanium. Ethyl silicate was applied to the surface of the lantern for consolidation and smooth drainage.

Late Quaternary Deposition of Ice-Rafted Detritus in the Mid-Latitude North Atlantic: Paleoceanographic Evidence on Climatic Instability over the Past 150 Kyr (북대서양 중위도 해역의 신생대 제4기발 빙하쇄설퇴적층: 15만년 전 이후의 기후변동에 대한 고해양학적 증거)

  • 박명호;류병재
    • Economic and Environmental Geology
    • /
    • v.34 no.2
    • /
    • pp.217-226
    • /
    • 2001
  • Stable isotope, paleoceanographic and sedimentological analyses were carried out along the core Ml5612 from the Mid-Atlantic Ridge. Distinct negative ${\delta}^{18}O anomalies punctuate the planktonic isotope records and correlate with the Heinrich-IRD cvents. The IRD layer in the corc contains varying amounts of quartz, K-feldspar, plagioclase, calcite, dolomite and mica, in which detrital carbonate contributes between I and 13% (except H3 and H6). Anomalies are strongest in the N. pachydenna (sin.) isotope record. Systematic changes in the ${\delta}^{18}O offset of G. hul/aides and G. inJlata signify variations in mid-latitude thermocline structure. In conjunction with negative benthic ${\delta}^{13}C anomalies, the data document a stronger contribution of a ${\delta}^{13}C depleted, nutrient-rich water mass during the IRD events. The ${\delta}^{13}C amplitude of > 1 $\textperthousand$ between 25 and 57 ka indicates changes between northern source (NADW) and southern source (AABW) water masses at this site. The IRD layers in the core Ml56l2 are correlative with those from the core S075-26KL and DSDP 609. The IRD layers from the Portuguese margin arc coeval with HI, H2 and H4 of the open North Atlantic. This similarity (and/or synchronicity in both regions may have been resulted from common changes in a North Atlantic thermohaline switch.

  • PDF

Nitrogen and Phosphorus Removal in Membrane Bio-Reactor (MBR) Using Simultaneous Nitrification and Denitrification (SND) (동시 질산화-탈질(SND) 반응을 적용한 MBR 반응조에서 질소 및 인 제거 특성)

  • Tian, Dong-Jie;Lim, Hyun-Suk;An, Chan-Hyun;Lee, Bong-Gyu;Jun, Hang-Bae;Park, Chan-Il
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.35 no.10
    • /
    • pp.724-729
    • /
    • 2013
  • Simultaneous nitrification and denitrification (SND) occurs concurrently in the same reactor under micro dissolved oxygen (DO) conditions. Anaerobic zone was applied for phosphorus release prior to an aerated membrane bio-reactor (MBR), and anoxic zone was installed by placing a baffle in the MBR for enhancing denitrification even in high DO concentration in the MBR. Phosphorus removal was tested by alum coagulation in the anaerobic reactor preceding to MBR. DO concentration were 2.0, 1.5, 1.0, 0.75 mg/L in the MBR at different operating stages for finding optimum DO concentration in MBR for nitrogen removal by SND. pH was maintained at 7.0~8.0 without addition of alkaline solution even with alum addition due to high alkalinity in the raw sewage. Both TCODcr and $NH_4^+$-N removal efficiency were over 90% at all DO concentration. TN removal efficiencies were 50, 51, 54, 66% at DO concentration of 2.0, 1.5, 1.0, 0.75 mg/L, respectively. At DO concentration of 0.75 mg/L with addition of alum, TN removal efficiency decreased to 54%. TP removal efficiency increased from 29% to 95% by adding alum to anaerobic reactor. The period of chemical backwashing of the membrane module increased from 15~20 days to 40~50 days after addition of alum.

A Study on the Strength Property of Recycled Fine Aggregate (Wet Type) Mortar with Blast Furnace Slag (고로슬래그를 사용한 습식 순환 잔골재 모르타르의 강도 특성에 관한 연구)

  • Shim, Jong-Woo
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.14 no.5
    • /
    • pp.153-160
    • /
    • 2010
  • This study aims to obtain technical data for improvement of utilization of Blast Furnace Slag(BFS), recycled aggregate in the future by complementing fundamental problems of BFS such as manifestation of initial strength and excessive alkali quantity as well as weakness of recycled fine aggregate through manufacturing of recycled fine aggregate mortar using BFS. The recycled aggregate includes the cement paste hardened as the surface and the type of the aggregate, which contains plenty of calcium hydroxide($Ca(OH)_2$) as well as the unhydrated cement. Accordingly, the objectives of this study are to inspect the manufacturing the recycled fine aggregate mortar used with blast furnace slag, to consider the effects of the recycled aggregate on the strength development of ground granulated blast furnace slag, and then to acquire the technical data to take into consideration the further usages of the recycled aggregate and blast furnace slag. In eluted ions from recycled aggregate, it showed that there were natrium($Na^+$) and kalium($K^+$), expected to be flown out of unhydrated cement, as well as calcium hydroxide($Ca(OH)_2$). Application of this water to mix cement mortar with ground granulated blast furnace slag was observed to expedite hydration as calcium hydroxide($Ca(OH)_2$) and unhydrated cement component were expressed to give stimuli effects on ground granulated blast furnace slag. The results of the experiment show that the recycled aggregate mixed with blast furnace slag has comparatively higher hydration activity in 7 day than the mortar not mixed with one in 3 day mortar does, causing the calcium hydroxide in the recycled fine aggregate to work on as a stimulus to the hydration of ground granulated blast furnace slag.

Esophageal Reconstruction by Hypopharyngointestinal Anastomosis in Corrosive Upper Esophageal Stricture (부식성 상부식도 협착증에서 하인두-장 문합에 의한 식도재건술)

  • Park, Jae-Kil;Lee, Sun-Hee;Chang, Yun-Hee;Jin, Ung;Kwack, Moon-Sub;Kim, Se-Wha;Chun, Sung-Won
    • Journal of Chest Surgery
    • /
    • v.31 no.9
    • /
    • pp.893-898
    • /
    • 1998
  • Material and Method: Esophageal reconstruction by the hypopharyngointestinal anastomosis was done in 7 patients of corrosive upper esophageal stricture at St. Mary's Hospital from August 1995 to January 1997. Result: There were one male and six female patients ranging from 20 to 63 years of age. The causative agents were acid in 6 patients and alkali in 1 patient. The esophageal reconstruction was made by hypopharyngcolojejunostomy in 4 patients and hypopharyngocologastrostomy in 3 patients. There were no operative mortalities. One patient developed anastomotic stenosis but others were free from dysphagia. All gained 4 kg to 13 kg of body weight during the follow-up period. Conclusion: In this experience right colon and terminal ileum including ileocecal valve was revealed as a good substitute for the esophagus and the esophageal reconstruction by hypopharyngocologastro (jejuno)stomy seems to be a satisfactory method with acceptable morbidity and mortality in corrosive upper esophageal stricture patient.

  • PDF

Effect of NaOCl and Gold Plating Additive on the Gold Recovery in Cyclone Electrolytic Cell from Solution for Stripping Gold of PCB by Cyanide (시안을 이용한 PCB 금 박리용액으로부터 사이클론 전해조에서의 금 회수거동에 미치는 차아염소산나트륨과 금 도금첨가제의 영향)

  • Jo, Hyeonji;Yoo, Kyoungkeun;Bae, Mooki;Sohn, Jeongsoo;Yang, Donghyo;Kim, Sookyung
    • Resources Recycling
    • /
    • v.26 no.4
    • /
    • pp.88-94
    • /
    • 2017
  • The recovery of gold in cyclone type electrolytic cell was conducted from solution for stripping gold of PCB by cyanide. The electrolytic recovery behaviors of gold was investigated by reaction time and addition of electrolytic sodium hypochlorite (NaOCl) and gold plating additive (KG-120). Because the electrolysis generated NaOCl reacted with the cyanide in the leachate by alkaline chlorination, more than 99% of the cyanide was removed at a $NaOCl(g)/CN^-(g)$ ratio of 1.0. When NaOCl was added during the recovery of the gold from cyanide leachate in the cyclone electrolytic cell, the recovery of gold was 98% at the ratio of $NaOCl(g)/CN^-(g)$ from 0.5 to 2.5 in 480 minutes and decreased rapidly over the ratio of 3.0. Gold was recovered more than 99% by adding 1.5 and 4.5%(v/v) of KG-120 with NaOCl in 480 minutes. In particular, when the concentration of KG-120 was 3.5 and 4.5%(v/v), more than 96% of gold was recovered within 240 minutes and the initial recovery rate was relatively faster. The optimum concentration of KG-120 is 3.5%(v/v) considering the economic feasibility and efficiency.

Composition and Evolution of Lithosphere Beneath the Jeju Island Region (I): A Review (제주도 암석권의 성분과 진화(I): 리뷰)

  • Yang, Kyounghee
    • The Journal of the Petrological Society of Korea
    • /
    • v.25 no.3
    • /
    • pp.261-281
    • /
    • 2016
  • Our knowledge of the lithosphere beneath the Korean Peninsula has been improved through petrologic and geochemical studies of upper mantle xenoliths hosted by Quaternary intraplate alkali basalts from Jeju Island. The xenoliths are mostly spinel lherzolites, accompanied by subordinate harzburgite and pyroxenites. The mantle xenoliths represent residual mantle material showing textural and geochemical evidence for at least a three-stage evolution, fractional partial melting, recrystallization, and metasomatism. Their composition primarily controlled by early fractional melt extraction and porphyroclastic and mylonitic fabrics formed in a shear-dominated environment, which was subsequently modified by residual slab-derived fluids (or melts). Modal metasomatic products occur as both anhydrous phase(orthopyroxene) and hydrous phase (phlogopite). Late-stage orthopyroxene is more common than phlogopite. However, chemical equilibrium is evident between the primary and secondary orthopyroxene, implying that the duration of post-metasomatic high temperatures enabled complete resetting/reequilibration of the mineral compositions. The metasomatic enrichment pre-dates the host Jeju Quaternary magmatism, and a genetic relationship with the host magmas is considered unlikely. Following enrichment in the peridotite protolith in the mantle wedge, the upper mantle beneath proto-Jeju Island was transformed from a subarc environment to an intraplate environment. The Jeju peridotites, representing old subarc fragments, were subsequently transported to the surface, incorporated into ascending Quaternary intraplate alkali basalt. The result of this study implies that long term material transfer in the transformation of geotectonic setting from a subarc to intraplate may have played a significant role in the evolution of lithospheric mantle, resulting in the enriched mantle domains, such as EM I or EM II in the lithospheric mantle beneath East Asia.

Study on Material Characteristics and Conservation Methods for Tracksite of Cretaceous Dinosaurs and Pterosaurs of Jeongchon area in Jinju, Korea (진주 정촌면 백악기 공룡·익룡발자국 화석산지의 재질특성 및 보존 방안 연구)

  • Ji Hyun Yoo;Yu Bin Ahn;Myoung Nam Kim;Myeong Seong Lee
    • Economic and Environmental Geology
    • /
    • v.56 no.6
    • /
    • pp.697-714
    • /
    • 2023
  • The Tracksite of Cretaceous Dinosaurs and Pterosaurs in Jeongchon, Jinju was discovered in late 2017 during the construction of the Ppuri industry complex. This site is a natural heritage site with a high paleontological value, as it preserves fossils of various types of dinosaurs, pterosaurs, and animal traces at a dense concentration. In this study, we surveyed that physical weathering such as joint, crack, scaling, exfoliation, and fragmentation occurred through field research in the fossil site, and conducted basic research on conservation science to reduce the damage. To this end, among the eight levels identified after excavation, the rocks of Level 3, which yielded a large number of theropod footprint fossils, and Level 4, which yielded pterosaur footprint fossils, were analyzed for material characteristics and evaluation of the effectiveness of consolidation and adhesion. This results showed that the rocks in the Level 3 stratum were dark gray siltstone and the rocks in the Level 4 stratum were dark gray shale, which contained a large amount of calcite and were composed of quartz, plagioclase, mica, alkali feldspar, and other clay minerals, which are likely to be damaged by rainfall under external conditions. As a result of conducting an artificial weathering experiment by dividing the probationary sample into four groups: untreated, consolidation treatment, anti-swelling treatment, and adhesive treatment, the consolidation and the swelling inhibitor showed an effect immediately after treatment, but did not show a blocking effect under a freezing-thawing environment. The adhesive showed that the adhesive effect was maintained even under freezing-thawing conditions. In order to preserve the fossil sites at Jeongchon in the future, in addition to temporary measures to block the inflow of moisture, practical measures such as the construction of protective facilities should be prepared.

An Experimental Study on the Hydration Heat of Concrete Using Phosphate based Inorganic Salt (인산계 무기염을 이용한 콘크리트의 수화 발열 특성에 관한 실험적 연구)

  • Jeong, Seok-Man;Kim, Se-Hwan;Yang, Wan-Hee;Kim, Young-Sun;Ki, Jun-Do;Lee, Gun-Cheol
    • Journal of the Korea Institute of Building Construction
    • /
    • v.20 no.6
    • /
    • pp.489-495
    • /
    • 2020
  • Whereas the control of the hydration heat in mass concrete has been important as the concrete structures enlarge, many conventional strategies show some limitations in their effectiveness and practicality. Therefore, In this study, as a solution of controling the heat of hydration of mass concrete, a method to reduce the heat of hydration by controlling the hardening of cement was examined. The reduction of the hydration heat by the developed Phosphate Inorganic Salt was basically verified in the insulated boxes filled with binder paste or concrete mixture. That is, the effects of the Phosphate Inorganic Salt on the hydration heat, flow or slump, and compressive strength were analyzed in binary and ternary blended cement which is generally used for low heat. As a result, the internal maximum temperature rise induced by the hydration heat was decreased by 9.5~10.6% and 10.1~11.7% for binder paste and concrete mixed with the Phosphate Inorganic Salt, respectively. Besides, the delay of the time corresponding to the peak temperature was apparently observed, which is beneficial to the emission of the internal hydration heat in real structures. The Phosphate Inorganic Salt that was developed and verified by a series of the aforementioned experiments showed better performance than the existing ones in terms of the control of the hydration heat and other performance. It can be used for the purpose of hydration heat of mass concrete in the future.