• Title/Summary/Keyword: 알칼리암

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Geology and Mineralization of East Africa Rift System (동아프리카 열곡대의 지질 및 광화작용)

  • Koh, Sang-Mo;Lee, Gilljae;Kim, Eui-Jun;Ryoo, Chung-Ryul
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.4
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    • pp.331-342
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    • 2013
  • 동아프리카 열곡대는 아라비아반도와 아프리카 북동부의 경계에서 부채꼴 형태로 남쪽으로 뻗은 대단층 함몰지구대이다. 아프리카 판 내부에 발달한 열곡대의 폭은 35~60 km이며 연장은 약 4,000km로 알려져 있다. 열곡대는 에티오피아에서 남서방향으로 발달하다 에티오피아 남부에서 동, 서 및 남서 열곡대로 나누어진다. 이 열곡대는 제3기초 올리고세(30~35 Ma)부터 에티오피아 북부 아파르 침강대를 중심으로 주 에티오피아 열곡대가 형성되고, 남쪽으로 확장되면서 마이오세에 활성화된다. 서부 열곡대는 동아프리카대지의 가장자리와 빅토리아 호의 서편을 따라 발달하며, 고각의 정단층에 의해 특징되는 전형적인 반지구대이다. 동부 열곡대(주 에티오피아 열곡대와 케냐 열곡대)는 30 Ma 전 화산활동과 지구조활동이 시작되었으나, 서부 열곡대는 Albert 호 북부에서 12 Ma 전에, Tanganyika 열곡에서는 7 Ma 전부터 시작되었다. 서부 열곡대의 남서 방향으로 분기된 남서 열곡대는 DR-콩고 남부와 잠비아의 Tanganyika 호에서부터 남서 방향으로 확장되어 보츠와나 Okavango 열곡대와 연결된다. 주 에티오피아 열곡대(MER)의 화산암류와 관련 퇴적암류는 지열, 소다회, 포타쉬(K), 천열수 금, 벤토나이트, 유황 및 부석자원으로 중요한 관련암으로 역할을 한다. 열곡관련 대표적인 광상으로는 Afar 열곡대에 분포하는 Danakhil K-광상과 Megenta 및 Blackrock 천열수 금광상이다. Danakhil K-광상은 제4기 화산활동과 높은 지열류에 의해 열곡대 내 분포하던 소금 선상지(salt fan)에서 증발작용에 의해 형성된 증발형 K-광상으로서 총 자원량은 약 12.6억톤으로 평가되었다. 이 광상에서는 4종의 K-광물인 실바이트, 카날라이트, 포리하라이트, 카이나이트가 산출한다. 아파르 침강대 내 분포하는 대표적인 천열수 금광상은 텐다호 지구대에 위치하는 Megenta 및 Blackrock 광상이다. 제4기에 EMR에서 산성의 과알칼리 화산활동에 의해 열수활동이 초래되어 현재까지도 활동하여 지열대가 형성되고, 저유황형금 광상들이 형성되었다. Megenta 저유황형 금 광상은 2009년 발견되었으며, 현재 영국의 Startex International사에 의해 탐사가 진행 중이다. 지금까지의 탐사 결과 옥수질 규화 변질암 분포지에서 5개의 광체가 분포하며, 그중 Hyena 광체에서는 규화 변질된 열수각력암에서 최고 16.75 g/t의 금 품위가 보고되었다. 동아프리카 열곡대의 서편인 부룬디에 분포하는 Gakara REE 광상은 카보너타이트 유형의 REE 광상이다. 이 광상은 $400km^2$ 면적 내 수 cm부터 수 m까지의 폭을 가지는 맥상 또는 망상세맥상의 광체를 형성한다. 주로 조립의 바스트너사이트와 모나자이트로 구성된다. 바스트너사이트의 형성시기는 $587{\pm}4Ma$인 신원생대로 알려져 있으며, 이 지역에 분포하는 카보너타이트와 알칼리암들이 신원생대에서 신생대까지의 광범위한 연대를 보이는 것은 동일한 구조선을 따라서 일어나는 반복되는 열곡활동으로 해석된다. 또한 REE, U, 인회석 자원의 관련암체로 생각되는 알카리 조면암(네펠린-조면암 포함)과 카보너타이트는 동아프리카 열곡대의 남동부 끝자락인 말라위와 모잠비크에 우세하게 분포한다.

Petrologic Evolution of the Songaksan Monogenetic Volcano, Jeju Island, Korea (제주도 송악산 단성화산의 암석학적 진화)

  • 황상구;원종관;이문원;윤성효;이인우;김성규
    • The Journal of the Petrological Society of Korea
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    • v.10 no.1
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    • pp.13-26
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    • 2001
  • Songaksan volcano, which occurs as a monogenetic volcano on the southwestern promontory of Hallasan shield volcano, is composed of tuff ring, cinder cone, lava pond and cinder conelet complex on wide basalt plateau. Except for an influx of external quartz xenocrysts in the tuff ring. Totally the volcano ranges from trachyandesite to trachybasalt in petrography and chemical compositions, which confirm the continuum between the evolved and primitive compositions widely occurring in the Jeju volcanic system. Chemical data for the volcano show quantitative compositional variation from the lower to the upper part of the volcanic sequences. The continuous compositional variations generally define a compositionally zoned magma storage. The chemical data suggest that the compositiona1 donations might have resulted from the fractional crystallization of a parental alkali magma. As result, the Songaksan volcano initially tapped the lop of the zoned magma storage and subsequently erupted successively more primitive magma.

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Mineralchemie der Klinopyroxen vom tephritischen Gesteine im Kaiserstuhl, BRD (카이져슈튤에서 산출되는 테프라이트질 화산암내의 단사휘석에 관한 광물화학적 고찰)

  • Kim, Jin-Seop;Keller, Jorg
    • Journal of the Mineralogical Society of Korea
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    • v.2 no.2
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    • pp.100-106
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    • 1989
  • Die Titan-Augite sind die dominierenden Einsprenglings- und Grundmassephasen in allen tephritischen Gesteinen im Kaiserstuhl. Mg-Werte ($Mg/Mg+Fe^{2+}+Mn$) der Pyroxene schwanken von 60-85. Der FATS- und TITS-Anteil nimmt von phonolithischem Basanit und -Tephrit zum fraktionierten phonolithischen Tephrit hin ab. Die Kpx der einzelnen Gesteinsgruppen zeigen auch einen Fraktionier-ungstrend, der durch Abnahme von Si und Zunahme von Al vom phonolithischen Basanit und -Tephrit zum fraktionierten phonolithischen Tephrit gekennzeichnet ist. Der in Alkaligesteinen gewohnlich auftretende $gr{\ddot{u}}ne$ Kern der Px ist Fe-reicher und $Ti-{\ddot{a}}rmer$ als der $hellbra{\ddot{u}}nliche$-farblose Rand. Die $gr{\ddot{u}}nen$ Kerne weisen $gegen{\ddot{u}}ber$ den $hellbr{\ddot{a}}unlichen$ Randern $h{\ddot{o}}here$ $Na/Fe^{+3}$-Verhaltnisse auf.

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Petrology of host granites and enclaves from the Bohyeonsan area, Euiseong Basin (의성분지 보현산 일대 화강암류와 포획암에 대한 암석학적 연구)

  • 좌용주;김건기
    • The Journal of the Petrological Society of Korea
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    • v.9 no.3
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    • pp.187-203
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    • 2000
  • Mafic microgranular enclaves (MME) occur in the granites from the Bohyunsan area. The host granites are generally of granodioritic and granitic compositions. The MME can be divided into magic mineral clusters, quartz diorite and diorite according to their occurrence. Halter variation diagrams show linear trends between the MME and the host granites. Though the rim compositions of plagioclase in the host granites and the MME are similar the core compositions of plagioclase in some host granites show abnormally high An content. The Mg/(Mg+Fe) ratio of hornblende in the host granites gradually increase from the core to the rim. The chemical composition of minerals in the host granites had been affected by more marc magma composition. The modelling of major elements of the MME and hybrid host granites also indicate that they result from simple mingling/mixing between a dioritic magma and the host granite magma. The MME are thus interpreted to be globules of a more mafic magma which intruded the granite magma. Partial equilibration has been achieved between the MME and the host granites after they were commingled with each other.

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Mineralogical Characteristics of Hydrothermal Laumontite and Adularia in the Breccia Zone of a Fault, Yangbuk-myeon, Gyeongju and Implications for Fault Activity (경주시 양북면 단층각력대에서 산출하는 로몬타이트와 아듈라리아의 광물학적 특징과 후기 단층활동)

  • Choo, Chang-Oh;Jang, Yun-Deuk;Chang, Chun-Joong
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.1
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    • pp.23-36
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    • 2012
  • Morphological and mineralogical characteristics of laumontite and adularia in the breccia zone in a fault, Yangbuk-myeon, Gyeongju, Korea suggest that they formed by reaction with hydrothermal alteration related to fault activity. Laumontite commonly occurring in the breccia zone is related to the presence of hydrothermal fluids bearing alkaline elements in the zone. Laumonite is characterized by elongated columnar form with aspect ratio varying 5~10. Laumontite and adularia whose characteristic euhedral forms are indicative of the latest product formed as rapid precipitation from fluids or replacements of Ca-plagioclase. Hydrothermal fluids reacted with intensively fractured granite, typical with high permeability, leached alkaline elements such as Ca, K, allowing laumontite and adularia to be precipitated under neutral to weak alkaline conditions. It is noteworthy that the formation process and genesis of low temperature minerals such as laumontite and adularia are very similar to those formed by wallrock alteration or hydrothermal alteration that occurred in epithermal deposits. Taking into account its characteristic morphology and chemistry, authigenic K-feldspar that commonly forms at low temperature in many fault zones must be adularia.

Geochemical and Geochronological Studies on Metaigneous Rocks in the Gyemyeongsan Formation, Northwestern Okcheon Metamorphic Belt and their Tectonic Implication (옥천변성대 북서부 계명산층 내 변성화성암류의 지구화학 및 지구연대학적 연구와 그 지구조적 의의)

  • 박종길;김성원;오창환;김형식
    • The Journal of the Petrological Society of Korea
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    • v.12 no.4
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    • pp.155-169
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    • 2003
  • In the northwest Okcheon metamorphic belt, the metaigneous rocks in the Gyemyeongsan Formation have wider chemical ranges for major, trace and REE elements compared with metaigneous rocks in the Munjuri Formation and do not represent bimodal igneous activity which is characteristic for a continental rifting. The metaigneous rocks in the Munjuri Formation are regarded as products of single magmatic evolution, whereas those in the Gyemyeongsan Formation may be formed through multiple magmatic episodes. The felsic metavolcanic rocks in the Gyemyeongsan Formation show weaker Eu negative anomalies compared with those in the Munjuri Formation but those in both formations show similar degrees of enrichment from LREE to HREE. The metabasites in the Munjuri Formation do not show Eu anomalies but those in the Gyemyeongsan Formation show both positive and negative Eu anomalies(0.59

CHIME Zircon Age of the Gamaksan Alkaline Meta-Granitoid in the Northwestern Margin of the Gyeonggi Massif, Korea, and its Tectonic Implications (경기육괴 북서 연변부 감악산 알칼리 변성화강질암의 CHIME 저어콘 연대와 지체구조적 의의)

  • Cho, Deung-Lyong;Lee, Seung-Ryeol;Suzuki, Kazuhiro
    • The Journal of the Petrological Society of Korea
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    • v.16 no.3
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    • pp.180-188
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    • 2007
  • We carried on CHIME zircon age dating for the Gamaksan alkaline meta-granitoid (GAM) from the northwestern margin of the Gyeonggi massif, and obtained a timing of regional metamorphism at $247{\pm}14Ma$ (n=103, MSWD=0.92). The age is compatible with Permo-Triassic regional metamorphic ages from the Imjingang Belt which has been regarded as possible eastward extension of Triassic collisional belt in China. Considering an extensional ductile shearing of the Gyeonggi (Kyonggi) Shear Zone which deformed GAM occurred at 226 Ma with temperature condition about $500^{\circ}C$ (Kim et al., 2000), and the Late Triassic to Early Jurassic Daedong Group unconformably overlies on top of the ductile shear zone, cooling rate of GAM over the period can be estimated as $18{\sim}10^{\circ}C/Ma$. Since new zircon begin to pow at temperature higher than upper-amphibolite facies condition (${\sim}700^{\circ}C$), cooling rate of GAM from peak metamorphism (247 Ma) to deposition of the Daedong G.oup (${\sim}$Early Jurassic) would be higher than $10^{\circ}C/Ma$. Such rapid cooling rate is compatible with that reported from exhumation stage of the Dabie-Sulu Belt, and supports an idea that the Gyeonngi massif is a part of Permo-Triassic orogenic belt in East Asia.

Rb-Sr Whole-rock Isochron Age and Petrology of the Mt. Geumjeong Granite, Busan (부산 금정산화강암체의 암석학 및 Rb-Sr 전암 등시선 연대)

  • Yun Sung-Hyo;Koh Jeong-Seon;Park Kwang-Sun;Ahn Hyo-Chan;Kim Young-Il;Yoo Sung-Hyeon;Lee Dong-Han;Yun Gi-Young
    • The Journal of the Petrological Society of Korea
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    • v.14 no.1
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    • pp.61-72
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    • 2005
  • The granitoids in the Mt. Geumjeong, Busan can be divided into granodiorite, hornblende granite, adamellite, tonalite, biotite granite and micrographic granite. The geochemical characteristics of the Mt. Geumjeong granites indicate that they were crystallized from a calc-alkaline series and that they belong to Ⅰ-type granitic rocks which evolved from granodioritic magma into hornblende granite, adamellite, biotitie granite, and finally micrographic granite through fractional crystallization of plagioclase. The crystallization pressures and temperatures of the minimum melt compositions of the granitic rocks were estimated to about 1∼5 kbar and 720∼700℃. The trace element composition and REE patterns, characterized by a high LILE/HFSE ratio and enrichments in LREE, indicate typical continental margin arc calc-alkaline rocks produced in the subduction environment. The Rb-Sr isotopic data for the Mt. Geumjeong granites define a well-defined isochron yielding as age of 69.6±1.9 Ma with an initial Sr isotopic ratio of 0.70503.

Cabboic Xenoliths in Alkaline Basalts from Jeju Island (제주도 알칼리 현무암에 포획된 반려암질 포획암)

  • Eom, Young-Bo;Nam, Bok-Hyun;Hwang, Byoung-Hoon;Kim, Jin-Seop;Yang, Kyung-Hee
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.2 s.52
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    • pp.103-114
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    • 2007
  • Gabbroic xenoliths in poikilitic and equigrnular textures and plagioclase megacrysts, up to 15 cm in size, are trapped in alkaline basalts from Sinsanri and Sangeumburi, Jeju island. Gabbroic xenoliths are gabbro norite in composition. Plagioclase is the most dominantly present $(42{\sim}94vol%)$, while olivine crystals are absent. Pokilitic xenoliths, interpreted as cumulates, include euhedral opx+cpx in oikocryst plagioclase. Equigranular xenoliths include subhedral to anhedral opx+cpx+pl. Based on the textural and geochemical natures, occurrence mode at the outcrops, poikiltic and equigranular xenoliths and plagioclase megacrysts were from rigid zone, mushy zone and crystal-suspended zone of the magma chamber, respectively. The gabbroic xenoliths in alkaline basalts of the Juju island represent crystallization products of relatively evolved basaltic magma at the Jeju magma reservoir beneath the Jeju Island. They are gabbro fragments that represent crystallization-isolation-capture processes associated with magma batches temporarily occupying reservoirs.

Petrology and Geochemical Characteristics of A-type Granite with Particular Reference to the Namsan Granite, Kyeongju (경주 남산일대의 A-형 화강암의 암석학 및 지화학적 특성)

  • 고정선;윤성효;이상원
    • The Journal of the Petrological Society of Korea
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    • v.5 no.2
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    • pp.142-160
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    • 1996
  • Petrological and geochemical characteristics of A-type granite were studied from the Namsan and Tohamsan granites in the vicinity of Kyeongju city, southeastern Korea. The Namsan granite consists of hypersolvus alkali-feldspar granite in the northern part and subsolvus alkali-feldspar to biotite granite in the southern part. This hypersolvus granite usually has miarolitic cavities and is characteristically composed of quartz, single homogeneous one-feldspar (alkali feldspar) forming tabular microperthite crystals, or micrographic intergrowth with quartz, and interstitial biotite (Fe-rich annite), alkali amphibole (riebeckitic arfvedsonite) and fluorite. Petrographic and petrochemical characteristics indicate that the hypersolvus granite and subsolvus granite from the Namsan belogn to the A-type and I-type granitoid, respectively. The A-type granite is petrochemically distinguished from the I-type Bulgugsa granites of Late Cretaceous in South Korea, by higher abundance of $SiO_2$, $Na_2O$, $Na_2O+K_2O$, large highly charged cations such as Rb, Nb, Y, Zr, Ga, Th, Ce. U the REEs and Ga/Al ratio, and lower abundance of $TiO_2$, $Al_2O_3$, CaO, $P_2O_5$, MnO, MgO, Ba, Sr, Eu. The total abundance of REEs is 293 ppm to 466 ppm, showing extensively fractionated granitic compositon, and REEs/chondrite normalized pattern shows flat form with strong Eu '-' anomaly ($Eu/Eu^{\ast}$=0.03-0.05). A-type granite from the Namsan area is thought to have been generated late in the magmatic/orogenic cycle after the production of I-type granite and by direct, high-temperature partial melting of melt-depleted, relatively dry tonalitic/granulitic lower crustal material with underplating by mantle-derived basaltic magmas associated with subduction.

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