• Tunnel and Underground Space
• /
• v.28 no.4
• /
• pp.358-371
• /
• 2018

The stability of openings in the underground mine is major concern in the operation of mines that must ensure productivity and safety. Among many rock conditions affecting cavities stability, the width and height of the opening is an important design factor. In this paper, we consider to determine the maximum unsupported span of a opening in a limestone mine by using the Q system among several rock classification schemes. In order to determine the span of the unsupported opening in the limestone mine, rock mass classifications were carried out at over 200 sites in the underground limestone mines. The relationships by using the Q system and the stability graph proposed by Mathews to determine the maximum span of the unsupported opening were derived and compared. We propose a new classification method that combines GSI and RMR rock classification systems to make it easy to use in a field.

• The Korean Journal of Applied Statistics
• /
• v.24 no.5
• /
• pp.931-939
• /
• 2011

In practice, thresholds are determined by the two subjective assessment methods in a generalized pareto distribution of mean extreme function(MEF-graph) or Hill-graph. To remedy the problem of subjectiveness of these methods, we propose an alternative method to determine the threshold based on the robust statistics. We compared the MEF-graph, Hill-graph and our method through VaRs on the Korean stock market data from January 5, 1987 to August 3, 2009. As a result, the VaR based on the proposed method is not much different from the existing methods, and the standard deviation of VaR for our method was the smallest. The results show that our method can be a promising alternative to determine thresholds of the generalized pareto distributions.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.33 no.4
• /
• pp.27-34
• /
• 2005

The paper discussed on the stability of cantilevered pipe conveying fluid subjected to distributed follower force. Governing equations of motion are derived by extended Hamilton's principle, and the numerical scheme using finite element method is applied to obtain the discretized equations. The critical flow velocity as a function of the distributed follower force for the various mass ratio is determined. The flutter configurations of the pipes at the critical flow velocities are drawn graphically at every twelfth period to define the order of quasi-mode of flutter configuration The critical mass ratios, at which the transference of the eigenvalue branches related to flutter take place, are definitely determined. Also, the effect of damping on the stability of the system is considered.

• Journal of the Korean Chemical Society
• /
• v.20 no.1
• /
• pp.15-18
• /
• 1976

The preferred conformation of benzenesulfenyl chloride was determined by EHMO calculation. It was found that the stability was dictated by the n-${\pi}$ conjugation of S atom with the benzene ring. The ethanolysis reaction of benzenesulfenyl chlorides has been studied. The rate constants obtained have been discussed in terms of substituent effects and d-orbital participation of sulfur atom. From a non-linear Hammett plot, bipyramid type of intermediate has been suggested.

• Analytical Science and Technology
• /
• v.27 no.6
• /
• pp.357-363
• /
• 2014

Isoprene is a one of the biogenic volatile organic compounds (BVOCs) and it is known as a source of the tropospheric ozone and formaldehyde. In addition, isoprene is a trace component of the exhaled breath and it is a potential biomarker for the diagnosis of diseases such as lung cancer. In these regards, isoprene gas standards are required for the accurate measurement of isoprene in air samples. To establish a standard for isoprene gas, gravimetric preparation and characterization of primary gas standards were studied. The primary gas standards were produced independently in 4 aluminum cylinders and concentrations were examined by GC-FID. As a result, the uncertainty of the gravimetric preparations including purity of the raw material was 0.01% and reproducibility of the preparation of independent 4 cylinders was 0.08%. The primary gas standards for isoprene showed 14 months of long-term stability. The relative expended uncertainty of 2.8% (95% of confidence level, k=1.96) was assigned to the certified value of 10 ${\mu}mol$/mol level of isoprene based on the quantitative evaluation of the purity, weighing, reproducibility, adsorption and long-term stability.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2009.05a
• /
• pp.997-1001
• /
• 2009

GIS 기반의 HEC-HMS를 이용하여 유량자료가 있는 소하천인 정자천 유역을 대상으로 장기 강우 유출 분석을 하였다. 일반적으로 홍수량 산정은 단기해석으로 분석하나 평 갈수기와 홍수기 때의 하천 유황이 다르기 때문에 매개변수가 불일치할 것이라 생각되고, 이에 대한 보정이 필요한지 판단이 필요하다. 이를 위해 장기 연속모의를 통하여 매개변수의 보정 필요성을 검토하였다. 연구는 수치지도를 조합하여 ARC-VIEW로부터 Map파일 및 Basin파일을 생성하였고, 토지이용도와 토양도를 ARC-VIEW를 이용하여 CN value를 추출하였다. 계산조건중 손실량 산정방법은 SCS Curve Number법으로 하였고, 단위도 방법은 Clark UH법, 하도추적방법은 Muskingum방법, 기저유량산정방법은 Constant monthly로 설정하였다. 유역면적, 도달시간자료, 저류상수 값 등의 추출은 GIS기법을 이용하여 추출하였다. HEC-HMS의 장기 연속모의(Continuous Simulation)로 얻어진 Element Graph를 보면 대략적인 형태가 일치하나 2006년도에 대한 모의에서는 홍수기의 결과만 일치하는 것으로 보이고, 2007년도에 대한 모의에서는 평 갈수기와 홍수기의 그래프 형태가 유사하게 나타났다. 실측 유량보다 유량 값이 약간 크게 산출되어 홍수량 산정에서 볼 때 안정성에 무리가 없다고 판단되지만, 평 갈수기 기간에서 볼 때 연마다 하천의 매개변수가 일치하지 않는다고 생각되며, 홍수 후 유역의 변화로 매개변수가 변화한 것이라 생각된다. 향후 정자천유역의 보다 많은 강우사상과 실측유량을 통해 HEC-HMS의 유출량을 비교 분석하면 보다 더 정확한 해석이 가능할 것이며, 홍수가 빈번한 지역의 경우 유수지의 검토와 저수지의 시간당 방류량을 알 수 있다면 오차의 범위를 줄일 수 있다고 생각된다. 더 나아가 우리나라에 적합한 매개변수와 GIS 프로그램이 개발된다면 보다 쉽고 정확한 해석이 가능할 것이라고 생각된다.

• Analytical Science and Technology
• /
• v.26 no.5
• /
• pp.326-332
• /
• 2013

Geosmin and 2-methylisoborneol (2-MIB) are volatile organic compounds responsible for the majority of unpleasant taste and odor events in drinking water. Geosmin and 2-MIB are byproducts of blue-green algae (cyanobacteria) with musty and earthy odors. These compounds have odor threshold concentration at ng/L levels. It is needed to develop a sensitive method for determination of geosmin and 2-MIB to control the quality of drinking water. In this study, geosmin and 2-MIB in water samples were determined by gas chromatography-mass spectrometry (GC-MS) with headspace-solid phase microextraction (HS-SMPE). The detection limits of this method were 1.072 ng/L and 1.021 ng/L for geosmin and 2-MIB, respectively. Good accuracy and precision was also obtained by this method. Concentrations of the two compounds were measured in raw waters from Nakdong River in the cyanobacterial blooming season. Water bloom formed by cyanobacteria has been occurred currently in Nakdong River. It is needed to investigate the concentrations of geosmin and 2-MIB to control the quality of drinking water from Nakdong River. Both geosmin and 2-MIB were detected in raw waters from Nakdong River at concentrations ranging from 4 to 24 ng/L and 6 to 16 ng/L, respectively.

• Korean Journal of Food Science and Technology
• /
• v.25 no.4
• /
• pp.373-378
• /
• 1993

A rapid gas chromatographic profiling method for the simultaneous analysis of free fatty and other acids was applied to vegetable oils. Oil samples were dissolved in dichloromethane and the free acids were extracted with saturated $NaHCO_3$ solution. The aqueous extract was acidified and then loaded onto the Chromosorb P column for the extraction. The acids were eluted with diethyl ether selectively from Chromosorb P column and were treated with triethylamine to prevent the losses of volatile acids. Several long chain fatty acids were detected from soybean oil, rice-bran oil, sesame oil and perilla oil. Various organic acids including odd number fatty acids were detected in crude oil, especially sesame oil. Arachidic acid from perilla oil and vanillic acid from sesame oil, which were not reported before were detected. The content ratio of free linoleic acid to oleic acid was $1.02{\sim}1.18$, which was similar to the reported data. When the GC profile of organic acids were simplified to their corresponding retention index spectra of bar graphical forms, they presented characteristic pattern of each vegetable oil that can be quickly recognized.

• Journal of Food Hygiene and Safety
• /
• v.39 no.2
• /
• pp.61-71
• /
• 2024

In this study, we analyzed chlorogenic acid indicator components in preparation for the additional listing of green coffee bean extract in the Health Functional Food Code and optimized caffeine for simultaneous analysis. We extracted chlorogenic acid and caffeine using 30% methanol, phosphoric acid solution, and acetonitrile-containing phosphoric acid and analyzed them at 330 and 280 nm, respectively, using liquid chromatography. Our analysis validation results yielded a correlation coefficient (R²) revealing a significance level of at least 0.999 within the linear quantitative range. The chlorogenic acid and caffeine detection and quantification limits were 0.5 and 0.2 ㎍/mL and 1.4, and 0.4 ㎍/mL, respectively. We confirmed that the precision and accuracy results were suitable using the AOAC validation guidelines. Finally, we developed a simultaneous chlorogenic acid and caffeine analysis approach. In addition, we confirmed that our analysis approach could simultaneously quantify chlorogenic acid and caffeine by examining the applicability of each formulation through prototypes and distribution products. In conclusion, the results of this study demonstrated that the standardized analysis would expectably increase chlorogenic acidcontaining health functional food quality control reliability.