• Clean Technology
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• v.19 no.3
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• pp.257-263
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• 2013

The zinc phosphate-coated mica (ZP/mica) pigments were prepared using phosphoric acid, zinc nitrate and mica as starting materials, and used as anticorrosive pigments. The scanning electron microscopy (SEM) and x-ray diffraction (XRD) techniques were used to observe the morphology and crystal structure of prepared pigments. The prepared pigments were incorporated into an epoxy binder to prepare coating and the corrosion inhibition performance of the pigments was evaluated using electrochemical impedance spectroscopy (EIS). It was found that the anticorrosive performance of the ZP/mica pigment prepared at $70^{\circ}C$ was the better than that prepared at $20^{\circ}C$. The formation of ZnO, in addition to $Zn_3(PO_4)_2{\cdot}2H_2O$, was observed on ZP/mica pigment prepared at $70^{\circ}C$. The excellent anticorrosive performance of ZP/mica pigment could be ascribed to the synergistic effect with electrochemical anticorrosive mechanism from zinc compounds on mica and barrier anticorrosive mechanism from lamellar mica.

• Journal of Preventive Medicine and Public Health
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• v.32 no.1
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• pp.1-8
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• 1999

Objectives. We conducted this study to obtain basic data of urinary levels of arsenic, cadmium, and zinc in children of Ulsan industrial area and to evaluate the difference in urinary levels of these metals between industrial area and suburban area. Methods. The study subjects were composed of 348(male 182, female 166) school children residing in industrial area and 100(male 50, female 50) school children of suburban area. We analyzed urinary levels of arsenic, cadmium, and zinc using atomic absorption spectrophotometer. Results. The geometric means of urinary level of arsenic, cadmium, and zinc of study participants were 3.69, 0.99, $282.49{\mu}g/l$ respectively. The adjusted geometric means of urinary levels of arsenic, cadmium, and zinc of study participants were 3.92, 1.05, $299.92{\mu}g/g$ creatinine respectively. Conclusions. The children residing in industrial area had the higher urinary levels of arsenic and cadmium than suburban children with statistical significance(p<0.01).

• Economic and Environmental Geology
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• v.17 no.1
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• pp.17-34
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• 1984

The Ordovician limestone and dolomite was mineralized by the intrusion of quartz porphyry to form hydrothermal ore deposit along the fault shear zone, which trends $N30^{\circ}-40^{\circ}W$ dipping $60^{\circ}-70^{\circ}SW$. The primary manganese carbonates in the upper part of the deposit were oxidized to form supergene manganese ore deposits. The quartz porphyry is plotted mainly in granite region of the triangular diagram of normative composition. The granite phase contains more copper and lead, but less zinc, nickel and chromium than the granodiorite phase which occupies the northwestern part of the quartz porphyry. The content of copper, lead, zinc, nickel and chromium in the quartz porphyry is lower compared with the granitic rocks from the copper province in the Gyeongsang basin. But the granitic rocks from the lead-zinc province has lower content of copper and nickel than the quartz porphyry. The primary distribution pattern of trace elements in the country rock of limestone and dolomite has close relation with the hydrothermal mineralization, showing anomalous or high content near the fault shear zone. The secondary distribution pattern of trace elements in soils shows close relation with the solubility of the carbonates of the elements under weathering condition.

• Proceedings of the Korea Information Processing Society Conference
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• 2012.04a
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• pp.1077-1078
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• 2012

시계열 데이터는 기상데이터, 주식데이터, 센서 데이터, 네트워크 트래픽 데이터, 의료 데이터 등 다양한 분야에서 사용되고 있다. 그 중에서 서브시권스 매칭 방법은 시계열 데이터베이스 어플리케이션에서 많은 주목을 받고 있다. 기존의 서브시권스 매칭 방법은 단일 윈도우만을 비교하여 서브시권스 매칭을 수행하였으나, 착오해답을 줄이는 데에는 한계가 있었다. 따라서 다중 윈도우를 비교하여 착오해답을 줄이고 성능을 높일 수 있는 다중 윈도우를 이용한 서브시퀀스 매칭 방법을 구현하였다. 그 결과 단일 윈도우를 사용했을 때보다 약 4.8배까지 후보집합의 수가 줄어드는 것을 볼 수 있었다.

• Applied Chemistry for Engineering
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• v.17 no.3
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• pp.274-279
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• 2006

To synthesize ZnO colloidal solution by a sol-gel process, zinc acetate ($C_{4}H_{6}O_{4}Zn{\cdot}2H_{2}O{\cdot}0.2\;mol$) and lithium hydroxide ($LiOH{\cdot}H_{2}O{\cdot}0.14\;mol$) in the ethanol were added to the solution containing a dispersing agent, hydroxypropyl cellulose (HPC). The nanosize and physical shape of the synthesized ZnO particles were determined by HPC acting as the dispersing agent. Nanosized ZnO particles were also obtained by a precipitation method based on zinc-2-ethylhexagonate. The precipitates were characterized by DLS, XRD, FE-SEM, and UV-vis. As the results, the ZnO colloids tend to self-assemble into a well-ordered hexagonal close-packed structure. The ZnO nanoparticles have an average diameter of nearly 40 nm with a narrow size distribution.

• Clean Technology
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• v.16 no.4
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• pp.292-296
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• 2010

We fabricated quantum dot sensitized solar cells(QDSSC) using PbS as a sensitizer and measured the solar energy conversion efficiency. After growing ZnO nanowires on the substrate by low temperature ammonia solution reaction, PbS QDs were deposited on ZnO nanowires by SILAR(Successive ionic layer adsorption and reaction) method. The morphology and crystallinity of PbS/ZnO nanowires were studied by SEM and XRD. In this study, the maximum conversion efficiency of QDSSC using PbS was 0.075% at one sun, which was lower than that of QDSSC using other sensitizers. The reasons it showed relatively low efficiency are i) the probability of type-I band gap arrangement between ZnO and PbS, ii) disturbance of electron migration by the various-sized PbS band gap, iii) stability dip by the chemical reaction of PbS QDs with electrolyte. To solve these problems, researches about controlling the size distribution of PbS and new type electrolyte would be needed.

• Korean Journal of Soil Science and Fertilizer
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• v.22 no.3
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• pp.205-214
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• 1989

The present experiment was conducted to investigate effects of soil conditioner applied on continuous cropping fields of red pepper from 1985 to 1986 in Imsil, Chunbuk province. 1. The ratios of bacteria/fungi (B/F) and actinomycetes/fungi (A/F) in the soils of continuous cultivation were increased with application of phytotoxin decomposers such as deep tillage (De), compost (Co), magnesium lime (Mg), gypsum silicate, and De + Co + Mg. 2. Degradation of phytotoxin (p-hydrohylenyons aeid) in the continuous soils was promoted with application of De, Co, Mg, gypsum, silicate and De + Co + Mg resulting in yield increase. 3. The infection rate plant by phytophthora were decreased with deep tillage and application of compost and magnesium lime and caused the increase of yield (22%) due to the increase of fruit per hill.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.9
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• pp.636-642
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• 2013

In order to overcome drawbacks (i.e., filtration and recovery) of conventional powder type photocatalysts, nano-ZnO/Laponite/PVA (ZLP) photocatalyzed adsorption balls were developed by using in situ mixing of nanoscale ZnO as a photocatalyst, and Laponite as both adsorbent and supporting media in deionized water, followed by the poly vinyl alcohol polymerization with boric acid. The optimum mixing ratio of nano-ZnO:Laponite:PVA:deionized water was found to be 3:1:1:16 (by weight), and the mesh and film produced by PVA polymerization with boric acid might inhibit both swelling of Laponite and detachment of nanoscale ZnO from ZLP balls. Drying ZLP balls with microwave (600 watt) was found to produce ZLP balls with stable structure in water, and various sizes (55~500 ${\mu}m$) of pore were found to be distributed based on SEM and TEM results. In the initial period of reaction (i. e., 40 min), adsorption through ionic interaction between methylene blue and Laponite was the main removal mechanism. After the saturation of methylene blue to available adsorption sites for Laponite, the photocatalytic degradation of methylene blue occurred. The effective removal of methylene blue was attributed to adsorption and photocatalytic degradation. Based on the results from this study, synthesized ZLP photocatalyzed adsorption balls were expected to remove recalcitrant organic compounds effectively through both adsorption and photocatalytic degradation, and the risks of environmental receptors caused by detachment of nanoscale photocatalysts can be reduced.

• Journal of Soil and Groundwater Environment
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• v.11 no.5
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• pp.20-34
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• 2006

This study was undertaken to assess the anthropogenic impact on trace metal concentrations (Zn, Cu, Pb, Cr, Ni, and Cd) of roadside sediments (N = 70) from No.7 national road within the watershed of Hoidong Reservoir in Pusan City and to estimate the potential mobility of selected metals using sequential extraction. We generally found high concentrations of metals, especially Zn, Cu and Pb, affected by anthropogenic inputs. Compared to the trace metal concentrations of uncontaminated stream sediments, arithmetic mean concentrations of roadside sediments were about 7 times higher for Cu, 4 times higher for Zn, 3 times higher for Pb and Cr and, 2 times higher for Ni and As. Speciation data on the basis of sequential extraction indicate that most of the trace metals considered do not occur in significant quantities in the exchangeable fraction, except for Cd and Ni whose exchangeable fractions are appreciable (average 29.3 and 25.8%, respectively). Other metals such as Zn (51.4%) and Pb (45.2%) are preferentially bound to the reducible fraction, and therefore they can be potentially released by a pH decrease and/or redox change. Copper is mainly found in the organic fraction, while Cd is highest in the exchangeable fraction, and Cr and Ni in the residual fraction. Considering the proportion of metals bound to the exchangeable and carbonate fractions, the comparative mobility of metals probably decreases in the order of Cd>Ni>Pb>Zn>Cr>Cu. Although the total concentration data showed that Zn was typically present in potentially harmful concentration levels, the data on metal partitioning indicated that Cd, Ni and Pb pose the highest potential hazard for runoff water. As potential changes of redox state and pH may remobilize the metals bound to carbonates, amorphous oxides, and/or organic matter, and may release and flush them through drain networks into the watershed of Hoidong Reservoir, careful monitoring of environmental conditions appears to be very important.

• Journal of the Korean association of regional geographers
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• v.20 no.4
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• pp.379-392
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• 2014

Southeast Asian studies in Korea have been developing rapidly, thanks to strategic and collective efforts invested by the area specialists. Especially, political scientists' contribution as 'institution builders' were remarkable. Anthropologists' leadership as 'solidarity makers' between humanities and social science is now experimenting. In terms of quantity, contribution of geography to area studies is not satisfactory yet, though geography is regarded as a discipline inseparable with area studies. However, geographers as 'horizontal networkers' can contribute to area studies through conducting research in unexplored subject and connecting the human and the physical science.