• Title/Summary/Keyword: 아세트알데히드

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Odor Modeling of acetaldehyde in Gumi National Industrial Complex (구미국가산업단지의 아세트알데히드 악취모델링)

  • Lee, Eun Ju;Akhtar, Muhammad Saeed;Lim, Kwang-Hee
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.22-35
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    • 2016
  • In this study CALPUFF modeling was performed to establish a correlation between regions of frequent civil odor complaints near Gumi national industrial complex and odor-emission facilities of synthetic fiber manufacturers in the same area as main acetaldehyde-emission point sources. As a result of the CALPUFF modeling, the maximum concentration of acetaldehyde in Gumi national industrial complex was reduced from O ($10^{-5}g/m^3$) to O ($10^{-6}g/m^3$) upon improving emission facilities of T company so that the maximum concentrations of acetaldehyde frequently appeared in complex 3. In addition, the predicted range of the maximum acetaldehyde concentration in Gumi national industrial complex was also improved in comparison with that prior to improving emission facilities of T company. These maximum concentrations of acetaldehyde obtained to estimate the expected contribution of total acetaldehyde point source by CALPUFF modeling showed the similar values to those measured in 'HAPs investigation in the region of Gumi-Daegu' and were consistent to the trend of civil odor complaints. Therefore, the expected contribution of total acetaldehyde point source was validated. The relative contribution of T company upon improving its emission facilities was predicted to be lowered by more than factor of two, compared to that prior to improving its emission facilities. To the contrary, the relative contribution of W company upon improving emission facilities of T company was predicted to be increased by more than factor of two, compared to that prior to improving emission facilities of T company. This indicates that the contribution of aldehyde point sources of W company was relatively increased upon improving emission facilities of T company.

Characteristics of Acetaldehyde Decomposition over Heat Treated Cobalt Phthalocyanine Catalysts (열처리 조건에 따른 코발트 프탈로시아닌 촉매상에서 아세트알데히드 분해 특성)

  • 서성규;윤형선;김대중
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.489-490
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    • 2003
  • 아세트알데히드는 석유화학관련시설에서 많이 배출되는 것으로 알려져 있으며, 환경부 고시(제2001-36호)에 이를 포함한 37개 VOC 규제제품 및 물질로 명시되어 있다. 또한, 현재의 8개 악취물질에도 포함되어 있어 강력히 규제하고 있는 물질이다. 아세트알데히드의 주요 특성으로서 최소감지농도는 0.21ppm, LEL(Lower Explosive Limit)은 4%로 반응성이 매우 크며, 액상 및 증기상에서 가연성이 매우 큰 물질이다. 이러한 물질을 처리하기 위해 직접연소법과 촉매연소법을 이용하여 처리하고 있으나, 직접연소법을 이용하는 소각로의 경우 산업폐기물을 소각하는 과정에서 아세트알데히드가 배출되고 있어 아세트알데히드의 주 배출원 이며 고온처리로 인한 비용부담의 단점이 있다. (중략)

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Photocatalytic Degradation and Application of Gaseous Acetaldehyde (기상 아세트알데히드의 광촉매 분해 및 적용)

  • 박상은;주현규;김종순;이태규;강준원
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.413-414
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    • 2000
  • Dibble과 Raupp에 의하여 TiO$_2$와 UV를 이용한 기상 TCE 분해 연구가 수행된 이후 대기오염정화를 위해 TiO$_2$/UV 시스템의 다양한 연구가 집중되어 오고 있는데 (Alberici, 1997), 휘발성유기화합물과 악취성분들의 제거가 주요 목적이 되고 있다. 아세트알데히드는 자극적인 과일 썩는 냄새가 나는 대표적 악취 물질임과 동시에 높은 증기압(740mmHg @2$0^{\circ}C$)으로 휘발성유기화합물로 규제되고 있으며, 요즘현대인들에게 "Sick Building Syndrome"이라는 사회적 문제를 일으키는 물질이다(T. Noguche. 1998). (중략)

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A Study on the Removal of Complex Odor including Acetaldehyde and Ozone Over Manganese-based Catalysts (아세트알데히드와 오존 복합악취 저감을 위한 망간기반 촉매 성능 연구)

  • Seo, inhye;Lee, Minseok;Lee, Sooyoung;Cho, Sungsu;Uhm, Sunghyun
    • Applied Chemistry for Engineering
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    • v.28 no.2
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    • pp.193-197
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    • 2017
  • In this study, we report on the catalyst process installed in conjunction with a wet plasma electrostatic precipitator to remove the oil mist and fine dust emitted from large-size grill restaurants. The multi-stage catalyst module reduced odor through catalytic reaction of acetaldehyde on catalysts even at an ambient temperature with ozone as an oxidant readily produced in a wet plasma electrostatic precipitator. Two types of manganese-based catalysts, $Mn_2O_3$ and $CuMnO_x$ were fabricated by extrusion molding for structured catalysts in practical applications, and the optimum conditions for high removal efficiencies of acetaldehyde and ozone were determined. When two optimized catalysts were applied in a two-stage catalyst module, the removal efficiency of acetaldehyde and ozone were ${\geq}85%$ and 100% respectively at the space velocity of $10,000h^{-1}$ and the reaction temperature of $100^{\circ}C$.

Analysis of Waste Water and Isolation of Strains Assimilation Waste Water from Acetaldehyde Plant (아세트 알데히드(특수산업) 공장폐수의 성분과 이용균주의 분리)

  • 정기택;서승교;송형익;박임동;방광웅
    • Korean Journal of Microbiology
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    • v.25 no.4
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    • pp.328-332
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    • 1987
  • As a research for treatment of waste water from acetaldehyde plant by biological method, we investigated general characteristics of the waste water, and isolated and identified some useful bacteria which effectively treated its waste water. Among the total number of 53 strains which were grown in waste water from an acetaldehyde plant, the strains AW-6, AW-22, AW-38 and AW-41 were found to be useful for COD removal of waste water. $COD_{Mn}$ and $BOD_{5}$ of the waste water were 5260 ppm and 6452 ppm, respectively, and pH was 1.85. And the main organic component in waste water was acetic acid which was contained 6.76%. By the taxonomical characteristics, the strains AW-6, AW-22, AW-38 and AW-41 were identified as Micrococcus roseus, Micrococcus luteus, Microbacterium lacticum and Microbacterium laevanifromans or similar strain, respectively.

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Practical Application of Mn-Cu Metal Catalyst for the Removal of Acetaldehyde (아세트알데히드 제거를 위한 Mn-Cu 금속촉매 실용화에 관한 연구)

  • Jung, Sung-Chul;Lee, Seung-Hwan
    • Journal of Digital Convergence
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    • v.10 no.8
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    • pp.201-210
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    • 2012
  • Because sensing odor varies depending on each person, even if the odor is released in line with the legal emission permission concentration levels, it can still become a social issue if a civil complaint is made. The purpose of this research is to study the possibility of putting Mn-Cu metallic oxide catalysts into practical use to economically eliminate acetaldehyde which produces a odor in the industrial process. An optimal operating parameter to eliminate acetaldehyde was deduced through a performance evaluation in the research laboratory and the performance was verified by applying the parameter into an actual facility as an on-the-site experiment through a Scale-up of pilot size. The operating temperature of the metallic oxide catalysts researched so far was at the minimum close to $220^{\circ}C$, and the $220^{\circ}C$ elimination efficiency was 50% or below. However, having experimented by using a Mn-Cu metallic oxide catalyst in this research, optimum elimination efficiency showed when space velocity (GHSV) was equal to or below 6,000 $hr^{-1}$. The average elimination efficiency was 61.2% when the catalyst controlling temperature was $120^{\circ}C$, 93.3% when the catalyst controlling temperature was $160^{\circ}C$, and 94.9% when catalyst controlling temperature was $180^{\circ}C$, thereby reflecting high elimination efficiency. The specific surface area of the catalyst was $200m^2/g$ before use, however, was reduced to $47.162m^2/g$ after 24 months and therefore showed that despite the decrease in specific surface area as time passed, there was no significant influence on the performance. Having operated Mn-Cu metallic oxide catalyst systems for at least two years on a site where there was no inflow of toxins like sulfur compounds and acidic gases, we were able to confirm that elimination efficiency of at least 90% was maintained.

Effects of Paecilomyces tenuipes Water Extract on the Alcohol Metabolism of Rats (눈꽃동충하초 물추출물이 흰쥐의 알코올대사에 미치는 영향)

  • Kim, Ji-Myung;Park, Jae-Hwan;Kim, Mi-Kyung;Chun, Hyang-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.3
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    • pp.396-400
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    • 2008
  • The effect of Paecilomyces tenuipes water extract (PTWE) on the alcohol metabolism was examined on rats. PTWE of 0, 30, 100 mg/kg body weight was administrated orally to the rats 30 min before oral treatment of 3 g/kg body weight of alcohol. Blood alcohol and acetaldehyde concentrations were measured 0.5, 1, 3, 6, 9 hr after alcohol treatment. Hepatic alcohol dehydrogenase (ADH), aldehyde dehydrogenase (ADH), microsomal ethanol oxidizing system (MEOS) activities were measured 9 hr after alcohol treatment. There were no differences in blood alcohol concentrations and area under the curve (AUC) of alcohol. PTWE decreased acetaldehyde concentration and there were significant differences after 6 hr in 30 mg/kg PTWE and after 3 and 9 hr in 100 mg/kg PTWE, respectively. In particular, 100 mg/kg PTWE decreased AUC of acetaldehyde by 44%. However, there were no changes in the hepatic ADH, ALDH, and MEOS activities.

Effect of New Remedies Mainly Comprised of Hovenia dulcis Thunb on Alcohol Degradation and Liver Protection in Sprague Dawley Male Rats (헛개나무 열매를 주성분으로 제조한 새로운 처방이 알코올 분해 및 간 손상에 미치는 영향)

  • Ko, Byoung-Seob;Jang, Jin-Sun;Hong, Sang-Mee;Kim, Dong-Wha;Sung, So-Ra;Park, Hae-Rae;Lee, Ji-Eun;Jeon, Won-Kyung;Park, Sun-Min
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.7
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    • pp.828-834
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    • 2006
  • We investigated whether two-kinds of mixture (NHDT-1 and NHDT-2) mainly composed of Hovenia dulcis Thunb had beneficial actions for alcohol and acetaldehyde degradation in acute alcohol treatment and liver protection from fatty liver induced by chronic alcohol administration. In acute alcohol degradation experiment, serum alcohol and acetaldehyde concentrations exhibited lower 1, 3 and 5 hours after taking 3 g ethanol per kg body weight in NHDT-1 treated rats, but not NHDT-2 including ginseng. On the contrast to the acute effect on alcohol degradation, the long-term alcohol administration revealed that NHDT-2, not NHDT-1, protected the increase in serum concentration of aspartate aminotransferase, alanine aminotrasferase and ${\gamma}-triglyceride$ metabolism similar to the rats not consuming alcohol, leading to decreased triglyceride accumulation in blood and liver. In liver morphological study, NHDT-1 preserved the regular hepatocyte morphology, decreased fat accumulation and reduced sinusoidal leukocyte infiltration in hepatocytes. In conclusion, NHDT-1 plays an important role in alcohol and acetaldehyde degradation without protecting liver damage while NHDT-2 works as hepatocyte protector from alcohol mediated damage.

Studies on the effect of the intermolecular hydrogen bonding on the vibrational frequencies of the acetonitrile under matrix isolation conditions at liquid-$N_2$ temperature (액체질소온도에서 매트릭스에 의해 격리된 아세토니트릴 분자의 진동주파수에 미치는 분자간 수소결합의 영향에 관한 연구)

  • Ma, Keum Ja;Jeong, Jong Hak;Jeong, Gi Ho
    • Analytical Science and Technology
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    • v.7 no.1
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    • pp.79-89
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    • 1994
  • Interactions between the acetonitrile and other organic molecules such as furan, pyrrole, pyrrolidine, thiophene, tetrahydrothiophene and acetaldehyde was studied with the infrared absorption spectroscopy under matrix isolation conditions. Xe was used as a major matrix material. Acetonitrile showed strong interactions with pyrrole and thiophene, and little interactions with pyrrolidine and acetaldehyde.

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