• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.20 no.1
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• pp.53-62
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• 2010

일샵 종사자들의 1) 공기 중 화학물질에 대한 노출정도를 파악하고 2) 공기 중 미량으로 존재하는 아세톤 및 톨루엔과 요 중 아세톤 및 마뇨산과의 연관성을 분석하여 후자들이 아직도 생물학적인 지표로 유용한지를 알아보고자 본 연구를 실시하였다. 경인 지역소재 9개의 네일숍에 근무하는 20명의 종사자들을 노출군으로 선정하였으며 이 작업과 무관한 일반 여성 20명을 대조군 선정하였다. 작업장 공기는 한 네일숍에 3개씩 총 27개의 시료를 가능한 한 작업자의 호흡영역에서 가장 가까운 곳에서 지역시료로 채취하였다. 공기 중 유기증기 13개 물질, 포름알데히드, 요 중 아세톤, 요 중 마뇨산을 가스크로마토그래프, 자외선분광광도계 그리고 GC/MS를 이용하여 분석하였다. 유기증기 13개 물질 중 아세톤과 톨루엔은 모든 네일샵에서 검출되었다. 각 네일샵 공기 중 유기증기의 노출정도를 기하평균(GM)과 복합물질간 상가작용을 이용하여 평가를 하였을 때 노동부 노출기준의 10%, ACGIH의 13% 수준에 불과하여 네일샵 종사자들의 유기증기에 대한 직업적인 노출정도는 매우 낮은 것으로 판단되었다. 요 중 아세톤과 마뇨산은 공기 중 아세톤과 툴루엔과 약한 상관성을 보였다(아세톤의 상관 계수 r=0.49, 톨루엔의 상관계수 r=0.45). 그러나 요 중 아세톤의 농도가 노출군과 대조군 간에 통계적으로 유의하지 않았으며 마뇨산은 대조군에 비해 노출군에서 약간 높은 것으로 나타났다. 따라서 저자들은 공기 중 아세톤과 톨루엔의 농도가 낮은 작업장에서 요 중 아세톤과 마뇨산을 생물학적 지표로 삼는 것은 적절하지 못한 것으로 결론지었다.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2005.05a
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• pp.223-226
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• 2005

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 1997.05a
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• pp.51-54
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• 1997

방독마스크 수명예측을 위하여는 여러 모델식이 제안되었으며, Cohen등은 bed-residence 흡착 모델을 사용하여 정화통에서 채취한 활성탄을 carbon tube에 bed-residence time이 같게 충전시켜 습도에 따른 정화통의 수명을 예측하였다. 그리고, Mover는 Potential Jonas 모델을 적용하여 환경적 조건들과 아세톤에 대하여 유기증기 정화통의 특성을 묘사하였다. (중략)

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2007.05a
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• pp.65-68
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• 2007

수분선택흡착-VOCs흡착-압축응축식 hybrid 공정에서 수분의 선택분리가 가능한 흡착제를 선정하였다. 또한 수분흡착탑에서 미리 수분을 제거하여 VOCs의 흡착효율을 높임으로써 배출환경기준을 만족시키고 수분 혼합성 VOCs와 수분 비혼합성 VOCs 회수가 가능한 공정 운영이 가능함을 알 수 있었고, 회수된 VOCs를 곧바로 생산 공정에 재투입할 수 있는 원료물질 수준으로 회수가 가능하였다.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.411-412
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• 2002

현재 많은 산업현장에서 휘발성 유기용제를 사용하고 있다. 국내 환경부에서 규제대상 VOC로 고시하고 있는 물질(환경부고시, '98. 7.1.)은 레이드 증기압, 광화학반응성, 물질사용량, 발암성 등 유해성을 감안하여 31개를 선정하여 규제하고 있으며 앞으로 규제대상 물질을 점차로 확대하여 나갈 계획으로 있다. 이에 한정된 자원의 고갈을 방지하고 환경의 보존을 위해 공정상에서 유기용제의 사용을 대체하는 것이 가장 이상적이나, 현재의 여건으로는 맡은 시간이 소요되므로 효율적인 휘발성 유기용제 처리공정 개발이 시급한 실정이다. (중략)

• 보존과학연구
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• s.32
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• pp.61-74
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• 2011

This study examines the removal effects of solvents which were applied on three adhesives and three filling materials for ceramics. The chosen materials are Cemedine C, Loctite$^{(R)}$ 401$^{TM}$, Araldite Rapid Type, plaster of paris, CDKI 520A+B, Araldit$^{(R)}$ SV427-2+HV427-1. For the first examination, each different materials were soaked into different solvents, and then the soften level were compared by compressive pressure. The result of the first exam showed that Cemedine C was dissolved easily in acetone. Furthermore Araldite, CDK and SV427 were soften efficiently by Dichloromethan, Tetrahydrofuran and DMX(Dichloromethan+Methanol+Xylene). However, Loctite and plaster were not able to make sample for the first test. Therefore, the second test carried on only. The second examination, chosen effective solvents from the first test were applied with two different methods; soaking and saturated atmosphere. Almost every sample could removed by soaking method in ten minutes, and saturated atmosphere method needs 24 hours for the safety.

• Korean journal of applied entomology
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• v.31 no.2
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• pp.182-189
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• 1992

The influnces of 9 kinds of solvents on the toxicities against several insect species, phytotoxicity and solubility of compounds were evaluated by means of leaf dipping and spray methods. In case of the spray application, density and vapor pressure seemed to be a contributing factor to lethal toxicity against brown planthopper and diamond-back moth, respectively; the bigger the property of density and the smaller the vapor pressure gave the stronger toxicity. It appeared that the toxicity of solvents was not correlated with anyone of physical properties such as boiling point, dipole moment, dielectric constant, surface tension and viscosity. Spray treatment gave more toxicity to insects than leaf dipping treatment. Although dielectric constant and dipole moment seemed to be contributing factors to phytotoxic damage to rice seedling and bean plants, respectively, no general correlation between phytoxicity and the other physical properties was found. Leaf dipping application caused stronger phytotoxicity than spray application. It is concluded that 5% acetone solution may be most suitable to test chemicals because of its favorable solubility of compounds, lower toxicity to insects, and lower phytotoxicity.

• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.237-242
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• 2022

In this study, a drying method that can effectively remove residual solvent from (+)-dihydromyricetin was developed. Residual acetone concentration was efficiently removed below ICH-specified value (5,000 ppm) by simple rotary evaporation with ethanol pretreatment. In addition, the residual ethanol met the ICH-specified value (5,000 ppm) by simple rotary evaporation through the addition of water, and the residual moisture also met the specified value (<4%) for active pharmaceutical ingredients. At all the drying temperature (35, 45, and 55 ℃), a large amount of the residual solvent was initially removed during the drying, and the drying efficiency increased when increasing the drying temperature. Removal of residual solvent by ethanol pretreatment was shown to be related to high vapor pressure of acetone-ethanol mixture and hydrogen bonding between acetone and ethanol.

• Journal of Environmental Science International
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• v.21 no.10
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• pp.1195-1202
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• 2012

The purpose of this work is to study the adsorption and desorption characteristics of acetone vapor and toluene vapor from adsorption tower in the VOCs recovery device. The six kinds of activated carbon with different pore structures were used and the adsorption and desorption characteristics were compared according to pore structure, desorption temperature, and adsorption method, respectively. Adsorption capacity of acetone vapor and toluene vapor by batch method was higher than that by dynamic method. Especially, activated carbon with medium-sized or large pores had more difference in adsorption capacity according to adsorption methods as a result of gradually condensation of vapors on relatively mesopore and large pores. Activated carbons with relatively large pores and relatively small saturated adsorption capacity had excellent desorption ability.

• Conservation Science in Museum
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• v.15
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• pp.56-65
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• 2014

The face of the Seated Stone Buddha ^{Korean Treasure No.84} of Sinboksa Templesite in Gangneung was contaminated with a glossy resin, spoiling its beauty. The contaminants covered the face, the forehead of the urna, to the bottom of the jaw. FT-IR analysis on a sample of the contaminants identified the substance as cyanoacrylate instant adhesive, which can normally be melted with acetone and removed with a swab. However, given that the surface of the statue was severely weathered from prolonged open-air exposure, alternative removal procedures were considered, to minimize the possibility of physical damage. After research, two removal procedures were utilized: one procedure involving poultices, which had been used to remove graffiti from the Samjeondobi Stele, and one procedure involving steam sterilization, which has been used to remove resin from pottery and porcelain. When both the poultices and steam sterilization were applied together, the resin was removed within twenty-four hours, without physical work using a swab.