• Title/Summary/Keyword: 아레니우스

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Arrhenius Kinetic Constants Analysis of BKNO3 under Accelerated Aging (가속노화에 따른 BKNO3의 아레니우스 동역학 상수 분석)

  • Jang, Seung-gyo;Kim, Jun-hyung;Ryu, Byung-tae;Hwang, Jung-min
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.4
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    • pp.34-39
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    • 2016
  • Arrhenius kinetic constants, the activation energy and the pre-exponential factor, of energetic material $BKNO_3$ are estimated using Differential Scanning Calorimetry (DSC). Different from the conventional way, the activation energy was estimated more precisely through DSC aging trial, and the consumed fraction by heat was calculated by comparing the integration of heat flow. We suggested the condition of accelerated aging test for the energetic material $BKNO_3$ and reconsidered the meaning of the thermal accelerated aging.

Accelerated Life Prediction of Ethylene-Propylene Diene Monomer Rubber Subjected to Combined Degradation (복합노화를 받는 EPDM 고무의 가속수명예측)

  • Han, Seung Wook;Kwak, Seung Bum;Choi, Nak Sam
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.5
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    • pp.505-511
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    • 2014
  • The EPDM(ethylene-propylene diene monomer) rubbers used for manufacturing engine radiator hoses can be degraded by locally generated electrical stress in addition to thermal and mechanical stresses. This study presents an accelerated life prediction of the EPDM rubber under electrochemical stresses using the Arrhenius formula under various aging temperatures($60^{\circ}C$, $80^{\circ}C$, and $100^{\circ}C$). The modified life prediction formula considers the relationship between the gradient($E_a/R$) and the Arrhenius constant(C). The effects of tensile strain(5%, 10%) on the life of these rubbers were investigated. The aging temperature influences EPDM rubber life, and tensile strain was predicted. It was confirmed that the modified life prediction was within the data deviation level of the test.

A three-dimensional patent evaluation model that considers the factors for calculating the internal and external value of a patent: Arrhenius chemical reaction kinetics-based patent lifespan prediction (특허의 내적.외적 가치산정요인을 고려한 입체적 특허평가모델: 아레니우스 화학반응속도론 기반의 특허수명예측)

  • Choi, Yong Muk;LEE, JAEWON;Cho, Daemyeong
    • Journal of Digital Convergence
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    • v.19 no.6
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    • pp.113-132
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    • 2021
  • This study is a new evaluation using the Arrhenius equation, which is known as the chemical reaction rate estimation equation, to evaluate the intrinsic and extrinsic value elements of patents as a model. The performance of the evaluation model was superior to the SVM, Logistic reg. and ANN models that were used as patent evaluation models in prior studies. In addition, there was a strong correlation between the predicted lifespan of the patent and the actual lifespan of the patent. These evaluation models may be used for evaluation purposes only, or if an evaluation is required, including a commercialization entity or technical characteristics.

Fracture Mechanics Applied to Fatigue Crack Growth Behavior at Elevated Temperatures (고온 피로균열 성장거동에 관한 파괴역학의 응용에 관한 연구)

  • 서창민;김영호
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.6
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    • pp.1552-1560
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    • 1990
  • A general form of the mathematical function in the fatigue crack growth rate law for CT specimens was determined by means of the dimensional analysis at elevated temperatures. The experimental results can be rigorously described by the combination of rate theory and fracture mechanics. The rate theory approach extends the scope of fracture mechanics through the consideration of the temperature. The fatigue crack growth rates are represented by the Arrhenius type equation. This equation explains fairly well the experimental data for Cr-Mo-V rotor steel and A517-F steel in the comparatively wide temperature regions as affected with the temperature and the stress intensity factor range interaction.

Prediction of Useful Life by Heat Aging of Motor Fan Isolating Rubber (모터팬 방진고무부품의 노화수명 예측)

  • Kim, W.S.;Woo, C.S.;Cho, S.J.;Kim, W.D.
    • Elastomers and Composites
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    • v.37 no.2
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    • pp.107-114
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    • 2002
  • This paper discusses the accelerated heat aging tests were carried out to predict the useful life of EPDM isolating rubber components of ventilation fan motor for clean room. 20% compression set results changes as the threshold are used for assessment of the useful life and the time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. The useful life at variable temperatures and activation energy are obtained from the Arrhenius relationship. An accelerated test program to assess useful life can be represented an appreciable investment in time was designed. We also considered the effect of antioxidant agents.

Conditional Confidence Intervals for Accelerated Life Testing in Modified Arrhenius Model (수정 아레니우스 모형에서 가족수명시험에 대한 조건부 신뢰구간)

  • 박병구
    • Journal of Korean Society for Quality Management
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    • v.25 no.3
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    • pp.1-10
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    • 1997
  • In the context of accelerated life tests, procedures are given for estimating the parameters in the modified Arrhenius model and for estimating mean life at a given future stress level. The conditional confidence intervals are obtained by conditioning on ancillary statistics and pivotal quantity. Using the data of Tobias and Trindada(1986), we illustrate conditional confidence interval for parameters under use condition in the modified Arrhenius model.

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Reliability Analysis of Gas Sensor Based on ALT (가속시험을 이용한 가스 센서 신뢰성)

  • 김종걸;채수근;강규섭
    • Proceedings of the Korean Reliability Society Conference
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    • 2000.11a
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    • pp.235-241
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    • 2000
  • 가스기기 안전장치 및 조리기구에 중요한 안전장치인 Gas Sensor를 가속시험을 이용하여 신뢰성을 분석하였다. 시험을 실시한 결과 GAS SENSOR의 Heater는 인가전압에 따른 특성 변화가 아레니우스 모델과 어링모델이 잘 일치함을 보여주었다. 즉, Heater선의 전압은 발열온도에 비례하고 있음을 알 수 있었다. 이번 실험을 통하여 STRESS에 비례적으로 특성이 변하는 제품은 설계단계에서 수명에 영향을 주는 잠재적 취약부를 단시간에 효과적으로 끌어내어 개선할 수 있는 기술임을 입증하였으나 다양한 STRESS의 복합적인 인자에 의하여 변화되는 특성을 분석하여 실질적으로 현장실무에 활용을 위해서는 많은 기술적 보안이 필요할 것으로 판단된다.

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Accelerated Life Test for 1.25Gbps Transceiver (광통신용 1.25Gbps Transceiver 가속수명시험)

  • Yun, Gwang-Su;Yu, Chong-Hee;Heo, Young-Soon
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1391-1393
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    • 2008
  • In this paper, the long-term reliability for 1.25G transceiver in use of high speed optical access network is investigated. High temperature storage tests and accelerated life tests are used to long-term reliability. Accelerated aging test have been during 3,000 hour of the three accelerated aging conditions by caused high temperature stress. Mean life is assumed to follow the Arrhenius relationship and analysis from the failure data obtained in the accelerated aging conditions.

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Effect of conductor temperature rise generated by load current on the cable life (운전전류에 의한 도체온도 상승이 케이블 수명에 미치는 영향)

  • Yun, Jea-Hun;Lim, Seong-Ho
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1445-1447
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    • 2003
  • 산업공장에서 저압케이블이 지중에 집중 매설되어 있는 경우 운전전류에 의한 케이블 도체온도가 도체허용온도를 초과할 수 있다. 또한 절연재질의 활성화 에너지와 환경온도로 표현되는 아레니우스 모델의 환경온도 대신 운전전류에 의해 계산된 도체온도를 사용하여 케이블의 수명을 예측하여 보았다.

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