• Proceedings of the Korean Fiber Society Conference
• /
• 1998.04a
• /
• pp.58-62
• /
• 1998

고분자 블렌드의 열역학적 상용성은 고분자 혼합물의 혼합 엔트로피가 무시할 수 있을 정도로 작기 때문에 성분 고분자 사이의 강한 분자간 인력에 의한 음의 값의 혼합 엔탈피에 의해서 유도되어진다. 상용성 고분자 블렌드를 얻기 위하여 도입되어질 수 있는 분자간 상호인력으로는 수소결합$^1$, 쌍극자-쌍극자 상호작용$^2$, 이온-쌍극자 상호작용$^3$, 산-염기 상호작용$^4$, 전이금속 복합체 형성$^{5}$ , 전하이동 복합체 형성$^{6}$ 등이다.(중략)

• Korean Journal of Optics and Photonics
• /
• v.11 no.1
• /
• pp.1-5
• /
• 2000

We define the basic minimal coupling Hamiltonian of the atomic systems in the Coulomb guage and show that this Hamiltonian yields the correct equations of motion for the operators of interest. Using the unitary transformation and making the dipole approximation, we calculate the effect of polarization of the dipoles on the interaction Hamiltonian of the system. ystem.

• Journal of the Korean Chemical Society
• /
• v.59 no.5
• /
• pp.413-422
• /
• 2015

Proton exchange membrane (PEM), which transfers proton from the anode to the cathode, is the key component of the proton exchange membrane fuel cell (PEMFC). Nafion is widely used as PEM due to its high proton conductivity as well as excellent chemical and physical stabilities. However, its high cost and the environmental hazards limit the commercial application in PEMFCs. To overcome these disadvantages, various alternative polymer electrolytes have been investigated for fuel cell applications. We used densely sulfonated polymers to maximize the ion conductivity of the corresponding membrane. To overcome high swelling, dipole-dipole interaction was used by introducing nitrile groups into the polymer backbone. As a result, physically-crosslinked membranes showed improved swelling ratio despite of high water uptake. All the membranes with different hydrophilic-hydrophobic compositions showed higher conductivity, despite their lower IEC, than that of Nafion-117.

• Journal of the Korean Magnetics Society
• /
• v.27 no.1
• /
• pp.23-29
• /
• 2017

In this study, the influences of magnetization reversal and magnetic interaction on the coercivity of Sr-ferrite particles with different sizes were investigated through various magnetic measurements. The shape of the initial magnetization curve and the magnetic field dependence of the coercive force indicate that the magnetization reversal changes from domain nucleation to wall pinning as the particle size decreases. On the other hand, the Henkel plot, interaction field factor and ${\Delta}M(H)$ obtained from the DCD and IRM curves show that the strength of the dipolar interaction is increased with increasing the particle size. Therefore, it can be concluded that coercivity is closely related to magnetic interaction as well as magnetization reversal mechanism.

• Journal of the Korean Magnetics Society
• /
• v.23 no.6
• /
• pp.188-192
• /
• 2013

The magnetic interaction effect on the magnetic activation volume and area of electrodeposited CoPt magnetic films was investigated. The dipolar interaction was predominant interaction mechanism for all samples. And the interaction strength was increased with decreasing current density and increased with increasing sample thickness. Although the activation volumes of the samples fabricated at low current density were larger than those of the high current density samples, the sample thickness seemed to have little influence on the variation of activation volume. But it was found that the activation area was apparently affected by the magnetic interaction strength as well as the current density.

• Journal of the Korean Magnetics Society
• /
• v.21 no.5
• /
• pp.151-156
• /
• 2011

The influence of thickness on magnetic interaction and magnetic properties in electrodeposited CoPt magnetic films was investigated from the analysis of the magnetic remanence curves and the magnetic hysteresis loops. As the thickness of the CoPt film is increased, the perpendicular coercivity and the saturation magnetization are increased but the squareness is considerably decreased. The analysis results of the magnetic remanence curves and the magnetic hysteresis loops exhibited that the dipolar interaction is the main interaction mechanism for all samples, but the strength of the dipolar interaction gradually increased with increasing sample thickness.

• 한국지구과학회:학술대회논문집
• /
• 2010.04a
• /
• pp.53-53
• /
• 2010

지표위의 어떤 지점에서의 지구자기의 수평분력 방향과 진북방향 사이의 각을 편각(Declination)이라고 정의한다. 쉽게 말하면 편각은 나침반의 자침이 가러 키는 방향과 진북방향과의 사이 각을 말한다. 대부분의 사람들은 나침반의 자침이 북자기극(North magnetic pole)을 가러킨다고 잘못알고 있다. 지구 다이나모설(Geodynamo theory)에 의하면 주로 철(약 90%)로 구성된 외핵 속에서 계속 생성 유지되고 있는 복잡한 (각각 나선형(helical)의 회전축에 대체로 평행하거나 평행하지 않은) 대류(Convection currents)에 수반하는 전류가 복잡한 지구자기장을 형성한다. 지표상에서 측정한 지구자기장의 자료를 Spherical harmonic analysis 으로 분석하면 한 개의 커다란 쌍극자(Dipole) (Inclined geocentric dipole 또는 주된 자기장(Main field) 이라고 부름), 적도쌍극자(Equatorial dipole), 4극자 (Quadrupoles), 8극자(Octupoles) 등의 여러 개의 크고 작은 쌍극자들의 총합이 지구자기장의 근원인 것처럼 해석되고 있다. 어떤 지점에서의 지구자기장의 방향은 외핵에서 생성된 천체 자기장에서 Main field를 제거한 나머지 자기장과, 상부 맨틀(upper mantle), 지각 및 지표상에 존재하는 인공 물체 또는 암석 및 광석 등의 잔류자기 및 유도자기 그리고 지형 등의 영향으로 결정된다. 어떤 지점에서의 지구자기장의 방향은 태양풍(Solar wind)과 전리층 사이의 상호작용 등의 외부자장(external field)의 영향도 받는다. 비쌍극자 자장(Non-dipole field)은 지표상에서 측정되는 총자기장에서 외핵에서 생성된 주된 자기장(Main field) 즉, 지구의 회전축에서 약 11.5도 기울어진 쌍극자 자장을 제거하고 남는 자기장을 말한다. 따라서 편각은 비쌍극자자장의 영향을 가장 많이 받는다. 비쌍극자 자장은 정지한 상태의 자장(standing field) 과 매년 서쪽으로 약 0.2도 움직이는 Westward drift하는 자장으로 크게 두 가지로 구분된다. 쌍극자 자장의 방향은 매우 느리게 변하지만 그 세기는 현재 비교적으로 빠르게 약해지고 있다. 비교적으로 매우 빠르게 변하는 비쌍극자 자장의 변화를 영년변화(Secular variation) 이라고 한다.

• Journal of the Korean Chemical Society
• /
• v.34 no.3
• /
• pp.267-279
• /
• 1990

The adsorption mechanisms of phenols on XAD-2 and XAD-7 resins were studied by using the distribution coefficient(log Kd) measured in the optimum adsorption conditions. It was observed that the Langmuir adsorption isotherm, indicating a molecular size-dependent adsorption, was appropriate for characterizing the adsorption behaviors of phenols on XAD-2 and XAD-7 resins. The adsorption energies of phenols on XAD resins were calculated by Lennard-Jones potential equation. In the calculation of the adsorption energy, the molecular radii and dipole moments of the resins and phenols were calculated by their van der Waals volumes and Debye equation, respectively. The stacking factor (F) were determined from the radio of the equilibrium distance to the stacking distance of molecules. In order to explain the adsorption energy calculated from the stacking factor it was compared with the adsorption enthalpy for each of phenols which was experimentally determined by batch adsorption shake method. It was observed that the adsorption enthalpy of phenolate ions on the XAD resins was likely to be more seriously affected by dispersion interaction than by a dipole or a charge interaction.

• Nuclear Engineering and Technology
• /
• v.4 no.4
• /
• pp.294-300
• /
• 1972

CNDO/2 and INDO calculations have been carried out on varying geometries of methyl chloro-and fluoro-formates. Results show that the configuration in which halogen atom is trans to methyl group is the most stable. Atomic charges and overlap population show that the trans form is stabilized by conjugation of carbonyl double bend with the unshared pairs of the ether oxygen and by electrostatic attraction of carbonyl oxygen to methyl group. Dipole moments of the trans forms agree reasonably well with the experimental values but showed that any generalizations made with dipole moments from bond moments should be accepted with considerable reservations.

• Analytical Science and Technology
• /
• v.28 no.3
• /
• pp.187-195
• /
• 2015

The heat of sublimation (HOS) is an essential parameter used to resolve environmental problems in the transfer of organic contaminants to the atmosphere and to assess the risk of toxic chemicals. The experimental measurement of the heat of sublimation is time-consuming, expensive, and complicated. In this study, quantitative structural property relationships (QSPR) were used to develop a simple and predictive model for measuring the heat of sublimation of organic compounds. The population-based forward selection method was applied to select an informative subset of descriptors of learning algorithms, such as by using multiple linear regression (MLR) and the support vector machine (SVM) method. Each individual model and consensus model was evaluated by internal validation using the bootstrap method and y-randomization. The predictions of the performance of the external test set were improved by considering their applicability to the domain. Based on the results of the MLR model, we showed that the heat of sublimation was related to dispersion, H-bond, electrostatic forces, and the dipole-dipole interaction between inter-molecules.