• Title/Summary/Keyword: 쌍극자

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Miscibility Improvement in PP and EPDM Blends via Introducing Specific Interaction (특정상호작용에 의한 폴리프로필렌/EPDM 블렌드의 상용성 향상)

  • Cho, Young-Wook;Go, Jin-Hwan;Lee, Won-Ki;Lee, Jin-Kook;Cho, Won-Jei;Ha, Chang-Sik
    • Elastomers and Composites
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    • v.35 no.1
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    • pp.46-52
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    • 2000
  • Miscibility improvement between polypropylene(PP) and ethylene-propylene-diene-terpolymer (EPDM) was studied by introducing specific interaction into both polymers. PP was modified by grafting maleic anhydride(MAH) onto backbone, leading to MAH-grafted PP(PP-g-MAH). Sulfonated EPDM ionomer neutralized with bivalent zinc cation(ZnSEPDM) was used as one component. The blends of PP-g-MAH and ZnSEPDM were prepared at $200^{\circ}C$ in Brabender Roller Mixer. Fourier transform-infrared(FT-IR) spectroscopic and dynamic mechanical studies have been performed to investigate the miscibility. FT-IR spectral peak corresponding to carbonyl group in PP-g-MAH and that to sulfonate group in ZnSEPDM were shifted to lower and higher frequency with increasing ZnSEPDM content, respectively, in the blends. Glass transition temperature of ZnSEPDM was increased up to 70wt.% of ZnSEPDM, and again decreased above 70wt.%. It can be concluded from the shift of FT-IR characteristic peaks and the changes of glass transition temperatures that the miscibility between PP and EPDM was improved via introducing specific interaction, i.e., dipole-ion interaction.

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Magnetic Characteristics of TA19-1 and TA19-2 Seamounts in the Lau Basin, the South Western Pacific (남서태평양 라우분지 TA19-1 해산과 TA19-2 해산의 지자기 특성 연구)

  • Kim, Chang Hwan
    • Economic and Environmental Geology
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    • v.47 no.4
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    • pp.395-404
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    • 2014
  • We conducted the geophysical survey of possible hydrothermal vent sites at 2009, in the Lau Basin, the south western Pacific and analyzed the magnetic characteristics of TA19-1 and TA19-2 seamounts. TA19-1 is a cone-shaped seamount with a caldera summit. TA19-2 seamount is bigger and shows more complicated topography than TA19-1 seamount. TA19-2 has a large caldera, a summit in the west side of the caldera and several crests. Simple dipole anomalies with a high over the north and a low over the south occur in TA19-1 seamount. High magnetic anomalies are located in the northern flank and the summit of TA19-2 seamount and low anomalies around the summit and the caldera. The results of bathymetry and magnetic data suggest that TA19-2 seamount might have more complicated magmatic process than TA19-1. Low magnetization zones are located over the summit, the calderas and the caldera rims. The magnetization lows indicate that submarine hydrothermal vents, along faults and fracture zones, could have caused an alteration of magnetic minerals. The magnetization highs over the summit and the calderas might have been related with later magmatisms like volcanic sills, intrusions.

Synthesis of CaZrO3 : Eu3+ phosphor by skull melting method (스컬용융법에 의한 CaZrO3 : Eu3+ 형광체 합성)

  • Choi, Hyunmin;Kim, Youngchool;Seok, Jeongwon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.4
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    • pp.131-135
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    • 2020
  • Single crystal phased CaZrO3 : Eu3+ phosphor have been synthesized by skull melting method. The crystal structure, morphology and optical properties of synthesized phosphor were investigated XRD (X-ray diffraction), SEM (scanning electron microscopy), UV (ultraviolet) fluorescence reaction and PL (photo luminescence). The starting materials having chemical composition of CaO: ZrO2 : Eu2O3= 0.962 : 1.013 : 0.025 mol% were charged into a cold crucible. The cold crucible was 120 mm in inner diameter and 150 mm in inner height, and 3 kg of mixed powder (CaO, ZrO2 and Eu2O3) was completely melted within 1 hour at an oscillation frequency of 3.4 MHz, maintained in the molten state for 2 hours, and finally air-cooled. The XRD results show that synthesized phosphor is stabilized in orthorhombic perovskite structure without any impurity phases. The synthesized phosphor could be excited by UV light (254 or 365 nm) and the emission spectra results indicated that bright red luminescence of CaZrO3 : Eu3+ due to magnetic dipole transition 5D07F2 at 615 nm was dominant.

Detection of Groundwater Table Changes in Alluvium Using Electrical Resistivity Monitoring Method (전기비저항 모니터링 방법을 이용한 충적층 지하수위 변동 감지)

  • 김형수
    • The Journal of Engineering Geology
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    • v.7 no.2
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    • pp.139-149
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    • 1997
  • Electrical resistivity monitoring methods were adopted to detect groundwater table change in alluvium. Numerical modelling test using finite element method(FEM) and field resisfivity monitoring were conducted in the study. The field monitoring data were acquired in the alluvium deposit site in Jeong-Dong Ri, Geum River where pumping test had been conducted continuously for 20 days to make artificial changes of groundwater table. The unit distance of the electrode array was 4m and 21 fixed electrodes were applied in numerical calculation and field data acquisition. "Modified Wenner" and dipole-dipole array configurations were used in the study. The models used in two-dimensional numerical test were designed on the basis of the simplifving geological model of the alluvium in Jeong Dong Ri, Geum River. Numerical test results show that the apparent resistivity pseudosections were changed in the vicinity of the pootion where groundwater table was changed. Furthermore, there are some apparent resistivity changes in the boundary between aquifer and crystalline basement rock which overlays the aquifer. The field monitoring data also give similar results which were observed in numerical tests. From the numerical test using FEM and field resistivity monitoring observations in alluvium site of Geum River, the electrical monitoring method is proved to be a useful tool for detecting groundwater behavior including groundwater table change. There are some limitations, however, in the application of the resistivity method only because the change of groundwater table does not give enough variations in the apparent resistivity pseudosections to estimate the amount of groundwater table change. For the improved detection of groundwater table changes, it is desirable to combine the resistivity method with other geophysical methods that reveal the underground image such as high-resolution seismic and/or ground penetrating radar surveys.

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Range of physicochemical parameters for active ingredients of herbicides (제초제의 활성 성분에 대한 물리-화학 파라미터의 범위)

  • Sung, Nack-Do;Song, Seon-Seob
    • The Korean Journal of Pesticide Science
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    • v.7 no.1
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    • pp.58-65
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    • 2003
  • Various physicochemical parameters for the active ingredients of 245 herbicides were calculated to develope a diagnosis and estimation system for utility as herbicide. The range of physico-chemical parameters for each inhibitors of photo system II (H1), acetolactate synthase (ALS) (H2) and herbicides were confirmed. The distribution ranges of 85% dependence for each physicochemical parameters were Obs.logP :$-0.90\sim4.50$, dipol moment: $1.80\sim12.22$ (debye), molecular refractivity: $53.0\sim104.0(cm^3/mol)$, polarizability: $19.0\sim37.0(\AA^3)$, HOMO energy: $-9.98\sim-7.34$ (eV), LUMO energy:$-2.76\sim0.40$ (eV), Van der Waals molecular volumes: $558.0\sim995.0(cm^3)$, molecular weight: $202.0\sim430.0$ (amu) and surface areas (Grids): $194.0\sim356.0(\AA^2)$, hydration energy: $-10.16\sim114.7$ Kcal/mol, respectively. It is suggested that MR and polarizability constants will be able to distinguish between herbicides and medicinal drugs. Results revealed that various compounds based on the range of physicochemical parameters of herbicides could be diagnosed and estimated.

A Study on THz Generation and Detection Characteristics of InGaAs Semiconductor Epilayers (InGaAs 반도체 박막의 테라헤르쯔(THz) 발생 및 검출 특성 연구)

  • Park, D.W.;Kim, J.S.;Noh, S.K.;Ji, Young-Bin;Jeon, T.I.
    • Journal of the Korean Vacuum Society
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    • v.21 no.5
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    • pp.264-272
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    • 2012
  • In this paper, we report THz generation and detection characteristics investigated by InGaAs semiconductor epilayers, as results of a basic study obtained from the InGaAs-based THz transmitter/receiver (Tx/Rx). High-temperature and low-temperature (LT) grown InGaAs epilayers were prepared by the molecular beam epitaxy technique for the characterization of THz generation and detection, respectively, and the surface emission based on the photo-Dember effect was tried for THz generation. THz wave was generated by irradiation of a Ti:Sapphire fs pulse laser (60 ps/83 MHz), and a LT-GaAs Rx was used for the THz detection. The frequency band shown in the spectral amplitudes Fourier-transformed from the measured current signals was ranging in 0.5~2 THz, and the signal currents were exponentially increased with the Tx beam power. The THz detection characteristics of LT-InGaAs were investigated by using an Rx with dipole (5/20 ${\mu}m$) antenna, and the cutoff frequency was ~2 THz.

A Study on a Teacher's and Students' Perceptions of Learning Difficulties of the Chemical Bond Unit of the Chemistry II (화학II 화학결합 단원의 학습 어려움에 대한 학생과 교사의 인식 연구)

  • Ko, Ki-Hwan;Lee, Sun-Kyung;Kang, Kyung-Hee
    • Journal of the Korean Chemical Society
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    • v.51 no.5
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    • pp.447-458
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    • 2007
  • The purpose of this study was to explore high school teacher's and students' perceptions of learning difficulties of the ‘chemical bond' unit of the Chemistry II in the 7th national curriculum. The participants in this study were consisted of a teacher and his students(85) from the Chemistry II classrooms: they all answered to the questionnaire, and then some students and the teacher were interviewed individually. The results showed that there were big differences between the teacher's and his students' perceptions of 1) the most difficult unit for understanding; 2) concepts they learned; and 3) the most difficult concept for understanding in the classroom. Students thought that electro-negativity unit was the most difficult to understand while teacher thought molecular structure unit was the hardest unit to teach. And teacher taught all 32 subjects of chemical bond unit to students, but some students could not remember they learned all of them. Most difficult parts for students to understand were ‘Coulomb force' and ‘dipole moment', while the most difficult part for the teacher to teach was ‘the conceptual difference between atomic bond and intermolecular force'. The reasons caused the students' learning difficulties were analyzed and discussed based on the interview data, and then further study was presented.

Solvation in Mixed Solvent (III). Solvatochromic Analysis for the Solvent Effect of Binary Mixed Solvent (혼합용매에서의 용매화 (제3보). 이성분 혼합용매 중에서 용매효과에 대한 분광용매화 분석)

  • Lee, Ik-Choon;La, Sang-Mu;Lee, Bon-Su;Sohn, Se-Chul
    • Journal of the Korean Chemical Society
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    • v.28 no.4
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    • pp.210-216
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    • 1984
  • Solvatochromic comparison methods were applied to determine Taft's solvent parameters, ${\pi}^{\ast}$(solvent polarity-polarizability), ${\alpha}$(solvent hydrogen bond donor acidity) and ${\beta}$ (solvent hydrogen bond acceptor basicity) for MeOH-MeCN solvent mixtures. Swain's solvent parameters A(anion solvation scale) and B(cation solvation scale) were also determined by least square fitting of kinetic data in the same binary solvent mixtures. It was found that: (i)${\beta}$ depends on the basicity of the solvent and increases with the MeOH content owing to the increase in polymeric structure of methanol; (ii) ${\pi}^{\ast}$depends on the dipole moment of the solvent and increases with the MeCN content of the solvent; (iii) ${\alpha}$ increases rapidly with the MeOH content as the hydrogen bond donor acidity of the solvent mixtures increases. Taft's reaction constants a and s and Swain's reaction constants a and b were determined for the reactions reported from our laboratory previously using solvent parameters determined in this work. No meaningful inter-relationship was found between the two set of reaction parameters, but a good linear correlation was found between the ratios a/s and a/b. Solvent effect on the reaction mechanism, substituent effect and leaving group ability were examined in the light of these reaction constants ratios.

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Characteristics of ITO with surface treatment by N2, O2, Ar Plasma and UV (질소, 산소, 아르곤 플라즈마와 자외선에 의하여 표면 처리한 ITO의 특성)

  • Bae, Gyeong-Tae;Jeong, Seon-Yeong;Gang, Seong-Ho;Kim, Hyeon-Gi;Kim, Byeong-Jin;Ju, Seong-Hu
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.90-90
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    • 2018
  • 디스플레이는 다수의 가로 전극과 세로 전극으로 구성되고, 전극에 신호를 주어 동작하도록 하는 원리이다. 이 디스플레이에는 전기가 통하고 투명한 전극이 필수적으로 사용되고 있고, 대표적인 투명 전극으로 ITO (Indium Tin Oxide)가 있다. ITO 박막은 $In_2O_3$에 Sn을 첨가하여 $Sn^{4+}$ 이온이 $In^{3+}$ 이온을 치환하고 이 과정에서 잉여 전자가 전기전도에 기여하는 구조이다. ITO 박막은 표면 처리 방법에 따라 표면 상태가 크게 변화한다. 플라즈마를 이용한 표면 처리는 환경오염이 적으며 강도, 탄성률 등과 같은 재료의 기계적 특성을 변화시키지 않으면서 표면 특성만을 변화시킬 수 있는 방법으로 알려져 있다[1]. UV (Ultraviolet)를 조사한 표면처리는 ITO 표면의 탄소를 제거하고, 표면 쌍극자를 형성하며, 표면의 조성을 변화시킬 수 있으며, 페르미 에너지 준위를 이동시킬 수 있어 ITO의 일함수를 증가시킬 수 있다[2]. ITO에 대한 다양한 연구가 수행되었음에도 불구하고 보다 다양한 관점에서의 연구가 지속될 필요가 있다. 따라서 본 연구에서는 다양한 조건으로 표면 처리한 ITO 표면의 일함수, 면저항, 표면 형상, 평탄도, 접촉각 등에 대해 알아보고자 한다. 세정한 ITO, 세정 후 UV 처리한 ITO (UV 처리 시간 2분, 4분 6분, 8분), 세정 후 $N_2$, $O_2$, Ar의 공정 가스를 사용하여 Plasma 처리한 ITO로 표면 처리 조건을 변화하였다. 표면 처리한 ITO의 특성은 Kelvin Probe를 이용한 일함수, 물방울 형상의 각도를 측정한 접촉각, AFM (Atomic Force Microscope)을 이용한 평탄도, 가시광선 (380~780 nm) 파장에 대한 투과도와 면저항을 측정하였다. 접촉각은 세정한 ITO의 경우 $45.5^{\circ}$에서 세정 후 UV를 조사한 ITO의 경우 UV 8분 조사 시 $27.86^{\circ}$로 감소하였고, $N_2$, $O_2$, Ar 가스를 사용하여 Plasma 처리한 ITO는 모두 $10^{\circ}$ 미만을 나타내었다. 플라즈마 처리에 의하여 접촉각이 현저하게 개선되었다. ITO의 면저항은 표면 처리 조건에 따라 $9.620{\sim}9.903{\Omega}/{\square}$로 그 차이가 매우 적어 표면처리에 의하여 면저항의 변화는 없는 것으로 판단된다. 가시광선 영역에서의 투과도는 공정 조건에 따라 87.59 ~ 89.39%로 그 차이가 적어 표면처리에 의한 변화를 나타내지는 않은 것으로 판단된다. 표면 처리 조건에 따른 평탄도 $R_{rms}$는 세정한 ITO의 경우 4.501 nm로부터 UV 2, 4, 6, 8분 처리한 경우 2.797, 2.659, 2.538, 2.584 nm로 평탄도가 개선되었다. $N_2$, $O_2$, Ar 가스를 사용하여 플라즈마 처리한 ITO의 경우 평탄도 $R_{rms}$는 2.49, 4.715, 4.176 nm로 사용한 가스의 종류에 따라 다른 경향을 나타내었다. 표면 처리 조건에 따른 평탄도 Ra는 세정한 ITO의 경우 3.521 nm로부터 UV 2, 4, 6, 8분 처리한 경우 1.858, 1.967, 1.896, 1.942 nm를, $N_2$, $O_2$, Ar 가스를 사용하여 플라즈마 처리한 ITO의 경우는 1.744, 3.206, 3.251 nm로 평탄도 $R_{rms}$와 유사한 경향을 나타내었다.

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Characterization of an Animal Carcass Disposal Site using Electrical Resistivity Survey (전기비저항 탐사를 이용한 가축사체 매몰지 특성 분석)

  • Ko, Jin-Suk;Kim, Bong-Ju;Choi, Nag-Choul;Kim, Song-Bae;Park, Jeong-Ann;Park, Cheon-Young
    • The Journal of Engineering Geology
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    • v.22 no.4
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    • pp.409-416
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    • 2012
  • In this study, an electrical resistivity survey and a drilling investigation were conducted at an animal carcass disposal site. Chemical analysis of leachate collected from the site was also performed (sampling times: May 2011 and June 2012). Five lines of dipole-dipole electrical resistivity surveys were carried out, along with drilling investigations at 3 points within the disposal areas and 11 points near the disposal site. Two-dimensional inverse modeling of the collected resistivity data was performed to evaluate the properties (size, depth, and form) of the disposal site. Leachate analysis showed that pH of leachate decreased from 7.4 to 6.7, while Eh changed from -358 mV to -48 mV over time. In addition, dissolved ions increased due to the progression of carcass decomposition. Results of the electrical resistivity survey indicated that low resistivity zones (minimum value, $0.64{\Omega}m$) existed at a depth of 8 m from the surface. Considering the bedrock location and carcass disposal depth, there was no evidence of bedrock contamination by leachate. The results of the electrical resistivity survey are consistent with those of the drilling investigation, which indicates that electrical resistivity effectively depicted the properties of the disposal site. This study demonstrates that electrical resistivity survey is a suitable technique for investigation of animal carcass disposal sites.