• Title/Summary/Keyword: 실리콘 카바이드

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Application of Ceramic Membrane (세라믹 분리막의 응용)

  • 김은옥
    • Membrane Journal
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    • v.3 no.1
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    • pp.12-21
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    • 1993
  • 세라믹 분리막은 알루미나($Al_2O_3$), 지르코니아($ZrO_2$), Carbon, 실리콘 카바이드, 스테인레스 등의 무기재료를 이용하여 제조된 분리막이다. 압출성형공정으로 제조된 지지체는 1700$^{\circ}C$ 이상의 소결공정을 거치므로 지지체 상단에 슬러리 코팅공정으로 형성된 얇은 막에게 안정된 분리기능을 수행할 수 있도록 커다란 물리적 강도를 제공한다. 따라서, 세라믹 분리막은 다공성 세라믹 구조를 갖는 특징적인 두 개 또는 세 개의 균일한 층으로 구성된 복합막이라 할 수 있다.

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Electrochemical Characteristics of Dopamine coated Silicon/Silicon Carbide Anode Composite for Li-Ion Battery (리튬이온배터리용 도파민이 코팅된 실리콘/실리콘 카바이드 음극복합소재의 전기화학적 특성)

  • Eun Bi Kim;Jong Dae Lee
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.32-38
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    • 2023
  • In this study, the electrochemical properties of dopamine coated silicon/silicon carbide/carbon(Si/SiC/C) composite materials were investigated to improve cycle stability and rate performance of silicon-based anode active material for lithium-ion batteries. After synthesizing CTAB/SiO2 using the Stöber method, the Si/SiC composites were prepared through the magnesium thermal reduction method with NaCl as heat absorbent. Then, carbon coated Si/SiC anode materials were synthesized through polymerization of dopamine. The physical properties of the prepared Si/SiC/C anode materials were analyzed by SEM, TEM, XRD and BET. Also the electrochemical performance were investigated by cycle stability, rate performance, cyclic voltammetry and EIS test of lithium-ion batteries in 1 M LiPF6 (EC: DEC = 1:1 vol%) electrolyte. The prepared 1-Si/SiC showed a discharge capacity of 633 mAh/g and 1-Si/SiC/C had a discharge capacity of 877 mAh/g at 0.1 C after 100 cycles. Therefore, it was confirmed that cycle stability was improved through dopamine coating. In addition, the anode materials were obtain a high capacity of 576 mAh/g at 5 C and a capacity recovery of 99.9% at 0.1 C/0.1 C.

SiC MOSFET Compared to Si Power Devices during Short Circuit Test (실리콘 카바이드와 실리콘 MOSFET의 단락회로 특성비교)

  • Nguyen, Thanh That;Ashraf, Ahmed;Park, Joung Hu
    • Proceedings of the KIPE Conference
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    • 2013.11a
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    • pp.89-90
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    • 2013
  • Higher power density, higher operational temperature, lower on state resistance and higher switching frequency capabilities of Silicon Carbide (SiC) technology devices compared to Silicon (Si) devices makes it has higher promising market. One of the most developed SiC devices is the power MOSFET. This study tests the SiC MOSFET under short circuit conditions taking into account the effect of gate voltage characteristics. The results will be compared to IGBT and MOSFET Si devices with similar ratings. A tester circuit was designed to perform the short circuit operation.

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Tribological Characteristics of Sliding Contact between Deferent Combinations of Ceramics (미끄럼 접촉시 이종세라믹 간의 트라이볼로지적 특성)

  • Kim Bupmin;Kim Seock-sam;Shin Dongwoo;Yoon Sang-bo
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.296-300
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    • 2004
  • Currently. the study on structural ceramic helps to suggest the precise data of friction and wear in accordance with the various conditions in operations. Also, the study helps to predict effective operating conditions by monitoring the occurrence of wear transition. The studies in the Past were mainly concentrated in using identical materials. However, it is highly likely to have unqualified data from the differences of mechanical and chemical properties between ceramic materials. Thus, in this study, through conducting the ball-on-disk type wear testing, the different ceramic materials has been used to consider tribological characteristics between different ceramic materials. We conducted the wear test by using three kinds of specimen which are zirconia, alumina and silicon carbide against zirconia. We have changed the sliding velocity and the loading conditions in this test and found out that there is row friction coefficient and wear rate in the combination of zirconia and silicon carbide.

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Method for the Assembly of a High-density Multi-channel Deformable Mirror for High Energy Lasers (고에너지 레이저용 고밀집 다채널 실리콘-카바이드 변형거울의 정밀 조립 방법)

  • Hyug-Gyo Rhee;Sunho Cho;Sihyun Kim;Jaehyun Lee;Pilseong Kang
    • Korean Journal of Optics and Photonics
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    • v.35 no.4
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    • pp.170-174
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    • 2024
  • A laser beam propagating in free space can be negatively affected by atmospheric turbulence. To overcome this and correct the wavefront error of the laser beam itself, a deformable mirror (DM), which is a key component of adaptive optics, is widely used. In this paper, a novel precision assembling method is suggested for a multi-channel high-density DM. The material of the mirror sheet of the DM is silicon carbide (SiC), and the actuator is a stacked-type lead-magnesium-niobate (Pb(Mg1/3Nb2/3)O3; PMN). To connect the mirror sheet and each actuator, a flexure is inserted. The flexure can make the DM operate with full strokes without the failure of adhesive. A series of jigs were designed and applied in order to assemble these three parts (the mirror sheet, actuators, and flexures) precisely. After assembly, the performance of the DM was also checked.

A Study on Improvement of the Ablation Resistance of Two Types of the Carbon/Carbon Composites by HfC Coating (하프늄카바이드 코팅을 통한 2종형상의 탄소/탄소복합재의 내삭마성 향상연구)

  • Kang, Bo-Ram;Kim, Ho-Seok;Oh, Phil-Yong;Choi, Seong-Man
    • Composites Research
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    • v.33 no.4
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    • pp.205-212
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    • 2020
  • In this study, HfC was coated on two types of carbon/carbon composites coated with SiC by vacuum plasma spraying(VPS). The experiment was performed using a plasma wind tunnel with heat flux of 5.06 MW/㎡ for 120 s heat flux before and after the coating. The mass ablation rate was calculated through the mass change before and after the test, and the length change was measured by using calipers and high speed camera. The oxidation/ablation behavior were observed by FE-SEM with EDS analysis of the specimens cross section. The plasma wind tunnel test results showed that the coated specimens had low weight loss and length change, and high oxidation/ablation resistance. However, two types of the specimens tested under the same conditions were different in the ablation behavior and ablation rate, and it was evaluated that the cylindrical type had higher oxidation/ablation resistance.

Performance Evaluation of C/SiC Composites (C/SiC 복합재료의 내열성능 평가)

  • Kim, Yun-Chul
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.185-188
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    • 2007
  • The main objective of this research effort was to develope the performance of C/SiC composites manufactured by LSI (Liquid Silicon Infiltration) method for solid and liquid rocket propulsion system and ensure the performance analysis technique. The various carbon preform were manufactured by filament winding, tape rolling, involute layup and stack molding process. For the best performance of thermal and mechanical properties, many process conditions were tested and selected by varying preform, the content of SiC, temperature, impregnation resin and chemical vapour reaction. In conclusion, the high performance and reliability of C/SiC composite were proved for solid and liquid rocket propulsion system. And the performance analysis technique related to mathematical ablation model was originated.

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Defect Inspection and Physical-parameter Measurement for Silicon Carbide Large-aperture Optical Satellite Telescope Mirrors Made by the Liquid-silicon Infiltration Method (액상 실리콘 침투법으로 제작된 대구경 위성 망원경용 SiC 반사경의 결함 검사와 물성 계수 측정)

  • Bae, Jong In;Kim, Jeong Won;Lee, Haeng Bok;Kim, Myung-Whun
    • Korean Journal of Optics and Photonics
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    • v.33 no.5
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    • pp.218-229
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    • 2022
  • We have investigated reliable inspection methods for finding the defects generated during the manufacturing process of lightweight, large-aperture satellite telescope mirrors using silicon carbide, and we have measured the basic physical properties of the mirrors. We applied the advanced ceramic material (ACM) method, a combined method using liquid-silicon penetration sintering and chemical vapor deposition for the carbon molded body, to manufacture four SiC mirrors of different sizes and shapes. We have provided the defect standards for the reflectors systematically by classifying the defects according to the size and shape of the mirrors, and have suggested effective nondestructive methods for mirror surface inspection and internal defect detection. In addition, we have analyzed the measurements of 14 physical parameters (including density, modulus of elasticity, specific heat, and heat-transfer coefficient) that are required to design the mirrors and to predict the mechanical and thermal stability of the final products. In particular, we have studied the detailed measurement methods and results for the elastic modulus, thermal expansion coefficient, and flexural strength to improve the reliability of mechanical property tests.

Recovery of Silicon from Silicon Sludge by Electrolysis (실리콘 슬러지로부터 실리콘의 전해회수(電解回收))

  • Park, Jesik;Jang, Hee Dong;Lee, Churl Kyoung
    • Resources Recycling
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    • v.21 no.5
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    • pp.31-37
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    • 2012
  • As a recovery of elemental silicon from the sludge of Si wafer process, a process of mechanical separation-chlorine roasting-electrolysis has been suggested. The silicon sludge consisted of Si, SiC, machine oil, and metallic impurities. The oil and metal impurities was removed by mechanical separation. The Si-SiC mixture was converted to silicon chloride by chlorine roasting at $1000^{\circ}C$ for 1 hr and the silicon chloride was dissolved into an ionic liquid of $[Bmpy]Tf_2N$ as an electrolyte. Cyclic voltammetry results showed an wide voltage window of pure $[Bmpy]Tf_2N$ and a reduction peak of elemental Si from $[Bmpy]Tf_2N$ dissolved $SiCl_4$ on Au electrode, respectively. The silicon deposits could be prepared on the Au electrode by the potentiostatic electrolysis of -1.9 V vs. Pt-QRE. The elemental silicon uniformly electrodeposited was confirmed by various analytical techniques including XRD, FE-SEM with EDS, and XPS. Any impurity was not detected except trace oxygen contaminated during handling for analysis.

Study on the Producing SiC Based Briquette for Raised Temperature of Molten Steel using Si Sludge Induced in the Process of Si Fabrication (실리콘 제조 공정에서 발생한 실리콘 슬러지를 활용한 용강 SiC계 승온제 제조 연구)

  • Lee, Chang-Hyun;Lee, Sang-Ro;Park, Man-Bok;Koo, Yeon-Soo;Lee, Man-Seung
    • Resources Recycling
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    • v.26 no.6
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    • pp.45-49
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    • 2017
  • Most Waste slurry is produced in the process of silicon manufacturing for semiconductor industry, containing silicon (Si) and silicon carbide (SiC). Waste slurry is simply stored with solidifying by cement or buried. On the other hand, it was suggested in this study that the waste slurry should be used for heating source as supplementary material in steel making process. The waste slurry was refined and pulverized, which was recycled into SiC-based sludge briquette. Chemical composition for SiC-based sludge briquette was analyzed and the feature of heating source was observed in accordance with the injection time and input amount. As a result, SiC-based sludge briquette in terms of low cost and high efficiency had an effect on increasing liquid steel temperature in steel making plants.