• Journal of the Korea Concrete Institute
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• v.17 no.3 s.87
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• pp.427-434
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• 2005

An experimental investigation was carried out in order to verify the compressive strength, flexural strength, equivalent bending strength, rebound rate of shotcrete according to silicate accelerator, aluminate accelerator, cement mineral accelerator respectively and to especially evaluate the performance of shotcrete using cement mineral accelerator for high quality. The test result of compressive strength was showed that all accelerators were satisfied the required test value for each age, for the requirement of having the $75\%$ or higher compressive strength ratio to plain concretes at 28 days, cement mineral accelerator with $87\%$ compressive strength ratio was only satisfied. In flexural strength test, cement mineral accelerator was satisfied the flexural strength requirement in steel fiber reinforced shotcrete for each age. Aluminate type was conformed to the requirement for 28 days, but not at 1 day, silicate type was failed to satisfy standard requirement. Rebound rate was measured between $11{\~}19\%$ and cement mineral accelerator was showed comparatively lower rebound rate. Based on the test results, cement mineral accelerator exhibited excellent strength improvement and lower rebound rate compared to the conventional accelerator, its result is showed the possibility of making high performance shotcrete.

• Resources Recycling
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• v.31 no.2
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• pp.40-48
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• 2022

In this study, the effects of solution components were investigated in the recovery of vanadium as ammonium metavanadate from vanadium-ore-salt roasting-water leaching solution. The vanadium-containing solution is strongly alkaline (pH 13), so the pH must be lowered to 9 or less to increase the ammonium metavanadate precipitation efficiency. However, in the process of adjusting the solution pH using sulfuric acid, aluminum ions are co-precipitated, which must be removed first. In this study, aluminum was precipitated in the form of an aluminum-silicate compound using sodium silicate, and the conditions for minimizing vanadium loss in this process were investigated. After aluminum removal, the silicate was precipitated and removed by adjusting the solution pH to 9 or less using sulfuric acid. In this process, the concentration and addition rate of sulfuric acid have a significant influence on the loss of vanadium, and vanadium loss was minimized as much as possible by slowly adding dilute sulfuric acid. Ammonium metavanadate was precipitated using three equivalents of ammonium chloride at room temperature from the aluminum-free, aqueous solution of vanadium following the pH adjustment process. The recovery yield of vanadium in the form of ammonium metavanadate exceeded 81%. After washing the product, vanadium pentoxide with 98.6% purity was obtained following heat treatment at 550 ℃ for 2 hours.

• Journal of Dental Rehabilitation and Applied Science
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• v.40 no.1
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• pp.1-12
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• 2024

Purpose: To histologically evaluate the effects of three calcium silicate-based sealers on rat mandible tissue. Materials and Methods: Rats were randomly divided as follows: A group that sacrificed immediately after cavity preparation, a group that sacrificed two weeks after cavity preparation, a group that sacrificed two weeks after CeraSeal (CS), AH Plus Bioceramic (AHB), or One-Fil (OF) sealer injection, respectively. After tissue processing for all groups, the bone tissue area (%) and the number of osteoclasts in and around the cavity were measured under a microscope. The results of each group were compared and statistical analysis was performed using one-way ANOVA and Tukey's test. Results: The formation of bone tissue and the presence of osteoclasts in the cavity were observed in the group that sacrificed two weeks after cavity preparation and the group sacrificed two weeks after AHB sealer injection, and these groups showed significantly higher average bone tissue area (%) than the other groups. In the other groups, no inflammation or foreign body reaction occurred in the cavity, and no osteoclasts were observed. Conclusion: All calcium silicate-based sealers used in this study showed a favorable bone tissue response when injected into the rat mandible. In particular, higher bone formation in the cavity was observed in AHB.

• 한국문화재보존과학회:학술대회논문집
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• 2006.11a
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• pp.139-144
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• 2006

• Proceedings of the Korean Ceranic Society Conference
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• 2000.04a
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• pp.20.1-20.1
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• 2000

• Journal of the Korean Ceramic Society
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• v.33 no.6
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• pp.679-685
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• 1996

• Resources Recycling
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• v.24 no.1
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• pp.3-11
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• 2015

Soluble silica generated from acid leaching process is very difficult to filter and deceases the purity of products, and thus becomes one of hot issues in hydrometallurgy. This paper reviewed the dissolution and reactivities of silicates in acid solution, and the methods for treatment of soluble silica. Removal of silica with alkaline pre-treatment, crystallization to $SiO_2$ and precipitation behaviour of silica with coagulation under acid conditions were briefly described.

• Proceedings of the KIEE Conference
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• 2008.10a
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• pp.157-158
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• 2008

친환경적인 분산기법으로 강력초음파 분산기법이 최근에 여러연구자들에 의해 적용되어 그 성과를 나타내고 있다. 에폭시-층상실리케이트 제조기법 중 가장 중요한 물성향상이 동반 상승되는 경우 분산처리를 통한 나노콤포지트 제조에 있다. 분산능력의 최적상태를 찾기 위해 초음파 적용시간을 4가지 적용시간을 달리하여 제조된 나노콤포지트 기계적, 전기적강도를 측정하여 와이블 확률분포 통계처리를 한 결과 전기적 절연파괴강도와 기계적 굴곡강도에서 최적의 분산상태를 얻을 수 있었다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.82-82
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• 2010

에폭시메트릭스 내에서 초음파 및 균질기를 이용하여 층상실리케이트 마이크로 입자의 균질분산을 위하여 사용하였다. 초음파와 균질기를 동시에 사용하여 최적의 적용시간과 충진나노입자 충진함량과의 관계를 연구하기위하여 구조적 특성으로 X-RD, 열적특성으로 DSC, 열적 기계적 특성으로 DMA를 사용하여 특성을 평가하였다. 충진함량 변화에 대해서 층상실리케이트의 층간사이 간격의 변화는 반비례하는 특성을 나타내었고, 충진함량이 증가됨에따라 자체만으로는 크게 응집된 입자의 분산이 미약한 결과로 볼 수 있다. 그러나 Homogenizer와 동시에 분산할 때는 충진함량이 크게 증가하여도 균질한 분산이 이루어졌다.

• Applied Chemistry for Engineering
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• v.10 no.4
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• pp.615-619
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• 1999

Polyether-clay nanocomposite was not polymerized with stearyltrimethylammonium ion exchanged montmorillonite, but it was self-polymerizable when heated with both stearyltrimethylammpmoim and m-phenylenediammonium ions intercalated montmorillonite to form polyether-clay nanocomposites. Molcular disperion of montmorillonite within the crosslinked epoxy matrix verified using X-ray diffraction and transmission electron microscopy found that the final product contains a uniform dispersion of exfoliated $10{\AA}$ thin clay layers seperated by $250{\sim}500{\AA}$of polyether polymer, thus verifying the nanocomposite structure.