• Title/Summary/Keyword: 시멘트 분말도

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Purity of γ-Dicalcium Silicate with Synthetic and Raw Materials Conditions (합성 및 원료 조건에 따른 γ-C2S의 순도)

  • Lee, Seok-Hee;Cho, Hyeong-Kyu
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.2
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    • pp.123-128
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    • 2020
  • γ-dicalcium silicate(γ-C2S) is known as a polymorphism of belite. Due to its high CO2 fixing capacity and the production process with low CO2 emission, γ-C2S has attracted more attention of researchers. For the further development of γ-C2S applications in construction industry, this study aims to investigate the method for synthesizing high purity of γ-C2S. The influence of raw materials and calcination temperatures on the purity of γ-C2S was evaluated. Several Ca bearing materials were selected as the calcium source, the materials which's main component is SiO2 were used as the silicon source. Raw materials were mixed and calcined under different temperatures. The results revealed that the highest purity could be obtained using Ca(OH)2 and SiO2 powder as raw materials. In addition, a relatively economic synthesis method using natural mineral materials-limestone and silica sand as raw materials were developed for the practical application. The purity of synthetic γ-C2S was recorded up to 77.6%.

Influence of Mixtures and Curing Conditions on Strength and Microstructure of Reactive Powder Concrete Using Ternary Pozzolanic Materials (배합 및 양생조건이 3성분계 포졸란재를 이용한 RPC의 강도발현 특성에 미치는 영향)

  • Janchivdorj, Khulgadai;Choi, Seung-Hoon;So, Hyoung-Seok;Seo, Ki-Seog;So, Seung-Young
    • Journal of the Korea Concrete Institute
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    • v.25 no.4
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    • pp.457-465
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    • 2013
  • This study discussed the influence of mixtures and curing conditions on the development of strength and microstructure of RPC using ternary pozzolanic materials. Through pilot experiment, various RPC was manufactured by adding single or mixed ternary pozzolanic materials such as silica fume, blast furnace slag and fly ash by mass of cement, up to 0~65%, and cured by using 4 types of method which are water and air-dried curing at $20^{\circ}C$, steam and hot-water curing at $90^{\circ}C$. The results show that the use of ternary pozzolanic materials and a suitable curing method are an effective method for improving development of strength and microstructure of RPC. The unit volume of cement was greatly reduced in RPC with ternary pozzolanic materials and unlike hydration reaction in cement, the pozzolanic reaction noticeably contributes to a reduction in hydration heat and dry shrinkage. A considerable improvement was found in the flexural strength of RPC using ternary pozzolanic materials, and then the utilization of a structural member subjected to bending was expected. The X-ray diffractometer (XRD) analysis and Scanning Electronic Microscope (SEM) revealed that the microstructure of RPC was denser by using the ternary pozzolanic materials than the original RPC containing silica fume only.

An Experimental Study for Improving the Durability of Concrete Bridge Decks (교량 바닥판 콘크리트의 내구성 증진을 위한 실험적 연구)

  • Suh, Jin-Won;Rhee, Ji-Young;Ku, Bon-Sung;Shin, Do-Chul
    • Journal of the Korea Concrete Institute
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    • v.19 no.4
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    • pp.393-399
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    • 2007
  • Concrete bridge decks are directly exposed to the severe environmental conditions such as rain water and deicing chemicals resulting in the freeze-thaw action and the rebar corrosion during their service lift. These deteriorations of bridge decks shorten the service lift and consequently they are the major concerns of the maintenance. The high performance concrete (HPC) deck is proposed as the alternative to minimize the deterioration problems. To develop more durable concrete deck, the performance characteristic tests of HPC mixtures were carried out. In this study, 4 different concrete mixtures were used varying the mineral admixtures as the cement replacement; ordinary portland cement (OPC), 20% fly ash (FA),20% fly ash with 4% silica fume (FS), and 40% ground granulated blast-furnace slag (BS). The design compressive strengths of HPC specimens were 27 MPa and 35 MPa, respectively. The results showed that the compressive strength of concrete did not much affect the durability of concrete. HPC with fly ash and silica lune (FS) were turned out to have the good durability and crack resistance.

Mechanical Properties of Alkali-Activated Slag-Based Concrete Using Lightweight Aggregates (경량골재를 사용한 알칼리 활성 슬래그 콘크리트의 역학적 특성)

  • Yang, Keun-Hyeok;Oh, Seung-Jin;Song, Jin-Gyu
    • Journal of the Korea Concrete Institute
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    • v.20 no.3
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    • pp.405-412
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    • 2008
  • Six alkali-activated (AA) concrete mixes were tested to explore the significance and limitations of developing an environmental friendly concrete. Ground granulated blast-furnace slag and powder typed sodium silicate were selected as source material and an alkaline activator, respectively. The main parameter investigated was the replacement level of lightweight fine aggregate to the natural sand. Workability and mechanical properties of lightweight AA concrete were measured: the variation of slump with time, the rate of compressive strength development, the splitting tensile strength, the moduli of rupture and elasticity, the stress-strain relationship, the bond resistance and shrinkage strain. Test results showed that the compressive strength of lightweight AA concrete sharply decreased when the replacement level of lightweight fine aggregate exceeded 30%. In particular, the increase in the discontinuous grading of lightweight aggregate resulted in the deterioration of the mechanical properties of concrete tested. The measured properties of lightweight AA concrete were also compared, wherever possible, with the results obtained from the design equations specified in ACI 318-05 or EC 2, depending on the relevance, and the results predicted from the empirical equations proposed by Slate et al. for lightweight ordinary Portland cement concrete. The stress-strain curves of different concrete were compared with predictions obtained from the mathematical model proposed by Tasnimi. The measured mechanical properties of lightweight AA concrete generally showed little agreement with the predictions obtained from these equations.

A Study on Fabrication and Characterization of Inorganic Insulation Material by Hydrothermal Synthesis Method (2) (수열합성법을 이용한 무기계 단열소재 제조방법 및 특성에 관한 연구 (2))

  • Seo, Sung-Kwan;Chu, Yong-Sik;Lee, Jong-Kyu;Song, Hun;Park, Jae-Wan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.3
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    • pp.225-232
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    • 2013
  • The inorganic insulating material was fabricated with quartzite, ordinary portland cement(OPC), lime, anhydrous gypsum and foaming agent by hydrothermal reaction. The inorganic insulating material was fabricated by using autoclave chamber under high-temperature and high-pressure. The inorganic insulating material is a porous lightweight concrete. Because of its porous structure, properties of inorganic insulating material were light-weight and high-heat insulation property. Properties of fabricated inorganic insulating material were $0.26g/cm^3$ in specific gravity, 0.4MPa in compressive strength and 0.064W/mK in thermal conductivity. In this study, the inorganic insulating material was fabricated and analyzed at different size of quartzite/OPC, various foaming reagent and functional additives to improve the properties. Consequently, polydimethylsiloxane can improve density and thermal conductivity. Especially, polydimethylsiloxane showed excellent improvement in compressive strength.

Analysis of breaching behavior of levee according to coating thickness of new substance (신소재의 피복두께에 따른 제방의 붕괴 거동 분석)

  • Ko, Dong Woo;Kim, Sung Joong;Kang, Joon Gu
    • Proceedings of the Korea Water Resources Association Conference
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    • 2018.05a
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    • pp.480-480
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    • 2018
  • 전 세계적으로 자연 친화, 하천생태계 보전, 친수하천 등을 조성하기 위한 대대적인 하천 정비사업이 활발히 진행 중에 있다. 최근 홍수로 인한 제방 붕괴에 대응하기 위한 제방의 안정화 및 개선을 위한 방법으로 기존의 시멘트와 같은 혼합물질을 사용하지 않고 환경 친화적이고 지속 가능한 대안에 대한 수요가 증가되고 있는 추세이며 현재 노후화 된 불안정 제방에 대한 보강대책을 수립해나가는 과정으로써 친환경 신소재를 활용하여 제방을 보호하는 연구가 수행되고 있다. 제방사면에 적용되는 신소재는 바이오폴리머를 활용한 재료로써 공동연구기관 카이스트에서 개발된 환경 친화적인 물질로 미생물에 의해 유도된 고인장 및 인체 무해성 등의 특성을 갖고 있으며 경제적 타당성인 측면에서 시멘트와 비교 분석 되어야 하고 실제 현장에서의 적용 가능성, 신뢰성 및 내구성 검토 등 성능을 보장하기 위한 지속적인 연구가 필요한 상황이다. 이에 본 안동하천실험센터에서는 중규모 제방을 직접 제작하여 수리모형실험을 통한 친환경 신소재 활용 제방의 안정성 및 성능 평가를 실시하였다. 수리실험 조건은 카이스트에서 제시된 레시피를 기반으로 먼저 분말형태의 바이이폴리머를 물과 희석하여 만들어진 바이오폴리머 용액을 흙과 혼합한 뒤 제방표면에 직접 미장작업을 수행하여 실험조건에 따라 일정한 두께(1cm, 3cm, 5cm)로 피복하였다. 이후 월류 붕괴 실험이 가능한 3 - 5일 정도의 양생기간을 거쳐 실험을 진행하였다. 실험결과는 다수의 고프로(GoPro) 및 비디오 카메라 등 다양한 영상장치를 이용하여 픽셀기반의 영상분석기법을 활용한 시간 흐름에 따른 제방 사면에서의 붕괴규모를 산정하여 신소재의 피복 두께에 따른 제체의 붕괴 거동 및 안정성을 평가하였으며, 또한 제방 파괴부에서의 흐름 상황 및 유속이 붕괴 발달에 미치는 영향을 분석하기 위하여 PIV 분석을 실시하였다. 이번 연구의 최종목표는 지속적인 예비실험을 수행하여 월류 및 침투, 파이핑 등 파괴 인자 별 신소재의 성능 개선 및 개발된 새로운 공법에 대한 효과 검토를 통한 최적안을 도출함으로써 향후 실규모 실험실증을 통한 신소재 시공 및 공법에 대한 현장적용 가능성 검증을 거쳐 최종적으로 신소재 제방 공법 설계 기술, 신소재 및 공법 표준안, 제방공법 안정성 평가 가이드라인 등을 제시하고자 하며, 이러한 실험데이터를 축적함으로써 실제 제방 붕괴 시 비상대처계획 수립에 필요한 기초자료로 활용이 가능할 것으로 사료된다.

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Granulation of Artificial Zeolite for the Simultaneous Removal of Nitrogen and Phosphorous from the Wastewater (질소, 인 동시 제거용 입상 인공제올라이트 제조)

  • Lee, Deog-Bae;Lee, Kyeong-Bo;Han, Sang-Soo;Henmi, Teruo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.1
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    • pp.67-71
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    • 1998
  • This study was carried out to granulate artificial zeolite powder that remove ammonium nitrogen and phosphorous simultaneously in wastewater treatment. Optimum water content was required for 30 percent volume to granulate artificial zeolite with 1.7mm diameter and 1~2cm length using granulator. Portland cement could remove much $NH_4{^+}$ and $PO_4{^{3-}}$ from the wastewater than other binding materials. Mixed 33, 25. 20. 16 percent of portland cement to artificial zeolite powder(v/v), cation exchange capacity of the granulars were 66.5, 81.4, 126.8, $151.2cmol^+kg^{-1}$ and hardness of that were 176.1, 24.4, 4.1, $0.4kg\;cm^{-2}$, respectively. Content of portland cement in the granular were related with removal of $PO_4{^{3-}}$ positively and that of $NH_4{^+}$ negatively. Shaked 1g of the granulars that made of portland cement 33 percent with 40ml synthetic wastewater containing $NH_4{^+}$ $1545mgl^{-1}$ and $PO_4{^{3-}}$ $417mgl^{-1}$, 99.4 percent of $NH_4{^+}$ and 90.3 percent of $PO_4{^{3-}}$ were removed simultaneously after 48 hours shaking. The longer shaking, the more $NH_4{^+}$ and $PO_4{^{3-}}$were removed. The artificial zeolite granular had both micropore and macropore that could be useful in the wastewater purification.

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Development of Reinforcement Grout Materials Using Blast Furnace Slag Powder and Aramid Fiber (고로슬래그 미분말과 아라미드 섬유를 이용한 보강그라우트재 개발)

  • Seo, Hyeok;Park, Kyung-Ho;Kim, Chan-Jung;Kim, Ho-Chul;Kim, Daehyeon
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.1
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    • pp.67-77
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    • 2019
  • The grouting method is utilized to reinforce and waterproof poor grounds, enhance the bearing capacity of structures damaged resulting from settlement due to elevation and vibration or differential settlement, and for cutoff. The purpose of this research is to enhance the compressive strength of grout materials by using aramid fiber and develop a high-strength ground improvement method by using blast furnace slag powder. In this regard, this study has conducted a uniaxial compression test after checking the high charge (higher than 50%) of the ratio of blast furnace slag powder and cement at 100:0, 70:30 and 40:60%, adding the aramid mixture based on 0, 0.5 and 1.0% of the cement and furnace slag powder weight and creating sand gels based on surface oiling rate of 0.7 and 1.2%. For the environmental review evaluation, a heavy metal exudation test and a pH test measurement have been conducted. The experiment results showed that 1% increase of aramid fiber led to 1.3 times greater uniaxial compression intensity. As for the hexavalent chrome, a 30% increase in blast furnace slag powder led to approximately 50% decrease in heavy metal exudation. However, the pH test revealed that a 30% increase in blast furnace slag powder resulted in approximately 0.5 increase in pH. Further research on the pH part is needed in the future.

Evaluation Method of Healing Performance of Self-Healing Materials Based on Equivalent Crack Width (등가균열폭에 기반한 자기치유 재료의 치유성능 평가 방법)

  • Lee, Woong-Jong;Kim, Hyung-Suk;Choi, Sung;Park, Byung-Sun;Lee, Kwang-Myong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.383-388
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    • 2021
  • In this study, constant head water permeability test was adopted to evaluate self-healing performance of mortars containing inorganic healing materials which consist of blast furnace slag, sodium sulfate and anhydrite. Clinker powder and sand replaced for a part of cement and fine aggregates. On constant head water permeability test for self-healing mortars, unit water flow rate of mortar specimens were measured according to crack width and healing period. As a result of evaluating the healing performance of self-healing mortar, it was confirmed that with the initial crack width of 0.3mm, the healing rate at healing period of 28 days increased by more than 30%p compared to plain mortar, greatly improving the healing performance. Furthermore, the coefficient(α) which was estimated from the relationship between crack width and unit water flow rate was used for calculating equivalent crack width. By analyzing the correlation of healing rate and equivalent crack width, the time and initial crack width attaining healing target crack width were predicted.

Eco-Friendly Backfill Materials with Bottom Ash (바톰애시를 이용한 환경친화적 뒤채움재)

  • Lee, Kwan-Ho;Kim, Seong-Kyum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.3
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    • pp.1385-1390
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    • 2012
  • Couple of laboratory for controlled low strength materials with bottom ash and recycled in-situ soil have been carried out. The optimum mix ratios for 4 cases with flowability and unconfined compressive strength were determined. The optimim mixing ratios were 25 to 45% of insitu soil, 30% of bottom ash, 10 to 20% of fly ash, 0 to 3% of crumb rubber, 3% of cement and 22% of water. Each mixture was satisfied the standard specification, minimum 20cm of flowability and 127 kPa of unconfined compressive strength. Two different curling methods, at room temperature and wet condition, were adopted. The average secant modulus(E50) was 0.07 to 0.08 * $q_u$. The compressive strength at wet condition showed 10% larger than at room temperature. The range of internal friction angle and cohesion for mixtures were 36.5o to 46.6o and 49.1 to 180 kPa, respectively. The mixture with crumb rubber(case 4) showed higher choesion and lower internal friction angle than the others. The pH of all the mixtures was over 12 which is strong alkine.