• Composites Research
• /
• v.32 no.1
• /
• pp.78-84
• /
• 2019

This study focused on the prediction of the long-term performance of carbon fiber/epoxy composites using Dynamic Mechanical Analysis (DMA) and Time-Temperature Superposition (TTS). Single-frequency test, multi-frequency test, and creep TTS test were performed. A sinusoidal load of $20{\mu}m$ amplitude was applied while increasing the temperature from $-30^{\circ}C$ to $240^{\circ}C$ at $2^{\circ}C/min$ for the single-frequency test and the multi-frequency test. The frequencies applied to the multi-frequency test were 0.316, 1, 3.16, 10 and 31.6 Hz. In the creep TTS test, a stress of 15 MPa was applied for 10 minutes at every $10^{\circ}C$ from $-30^{\circ}C$ to $230^{\circ}C$. The glass transition temperature was determined by single-frequency test. The activation energy and the storage modulus curve for each temperature were obtained from glass transition temperature for each frequency by the multi-frequency test. The master curve for the reference temperature was obtained by applying the shift factor using the Arrhenius equation. Also, TTS test was used to obtain the creep compliance curves for each temperature and the master curve for the reference temperature by applying the shift factors using the manual shift technique. The master curve obtained through this process can be applied to predict the long-term performance of carbon fiber/epoxy composites for a given environmental condition.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.10 no.7
• /
• pp.1661-1667
• /
• 2009

Post-cure characteristics of a silicone rubber material which is widely used for a LCD lamp holder were investigated using thermogravimetric analysis (TGA). Research was especially focussed on searching for the optimum post-cure conditions in relation to the practical operation environments. The results showed that incipient volatile temperature(Ti) during the process was considered as the most important factor and, thereby, post-curing for 2hrs at $250^{\circ}C$seemed to be a reasonable condition in the practical view-point. Arrhenius plot of shift factors which were empirically determined from the time-temperature-superposition-principle showed good linearity, exhibiting the post-cure mechanism might be proceeded through single mechanism with activation energy of 108.25kJ/mol.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.23 no.1
• /
• pp.46-51
• /
• 2019

Intermittent CSR testing was used to investigate the degradation of a NBR O-ring, and also the prediction of its life-time. An intermittent CSR jig was designed taking into consideration the O-ring's environment under use. Degradation of O-rings by thermal aging was observed between $40^{\circ}C$ and $120^{\circ}C$. O-rings showed non-linear degradation behavior under $80^{\circ}C$. At 20% of failure condition, predicted life-times were 32.5 years by Arrhenius plot and 22.6 years by WLF plot.

• Journal of Drive and Control
• /
• v.18 no.2
• /
• pp.32-37
• /
• 2021

The piston reservoir is mainly used in hydraulic blow-down system for aerospace engineering. The reservoir is heavy due to both hydraulic cylinder and piston in pressurization. The positive expulsion tank with rubber diaphragm has been mostly applied propellant and fuel tank at low pressure to satellites. To reduce weight, the reservoir that can be used at high pressure with rubber diaphragm was developed. In this research, the prediction of life-time for the rubber diaphragm was implemented through an accelerated life test, as a part of development of new reservoir. Also, the diaphragm was stored in an temperature chamber at the same condition as and operation with hydraulic oil. As a result, the life-time for a rubber diaphragm was successfully evaluated via Arrhenius law and Time-Temperature Superposition based on failure times over temperatures in the accelerated test.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.02a
• /
• pp.332-332
• /
• 2012

분자선 에피탁시(molecular beam epitaxy)를 이용하여 GaAs 기판에 성장한 InAs 양자점(QDs: quantum dots)은 성장 온도, 압력, As/In의 공급비 등의 성장 조건에 따라 다른 변수(parameter)를 갖는다. 따라서 성장변수에 따라 양자점의 모양과 크기, 밀도가 달라져 균일한 양자점 형성에 어려움이 있어 많은 연구가 진행되고 있다. 예를 들면 In-interruption 법으로 성장한 양자점의 특성이 S-K mode (Stranski-Krastanov mode)로 성장한 양자점에 비해 광학적 특성이 향상되었다. 본 연구에서는 In pre-deposition (IPD) 법으로 성장한 InAs/GaAs 양자점의 광학적 특성을 PL(photoluminescence)와 TRPL (time-resolved PL)을 이용하여 분석하였다. InAs QDs 시료들은 In과 As 공급시간을 각각 1초와 19초 (QD1), 2초와 18초 (QD2), 3초와 17초 (QD3)로 조절하여 성장하였으며, In이 공급되는 시간 동안 As shutter를 차단하여 As 공급을 중단하였다. In과 As의 차단 없이 S-K mode로 성장한 시료를 기준시료로 사용하였다 (QD0). AFM (atomic force microscope) 측정결과, In 공급시간이 1초에서 2초로 증가할 때, 양자점의 밀도와 종횡비(aspect ratio)가 증가하였고, 양자점의 균일도가 증가하였다. 그러나 QD3 시료는 QD1 시료에 비해 밀도와 종횡비, 균일도가 감소하였다. 10 K에서 PL 피크는 In 공급 시간이 증가할 때, 970 nm에서 1020 nm로 적색편이 하였고 반치폭 (FWHM: full width at half maximum)은 75 meV에서 85 meV로 증가하였다. QD2 시료의 PL 피크 에너지가 가장 낮았고, 가장 강한 PL 세기를 보였다. IPD 시간이 증가함에 따라 PL 피크에서 측정한 PL 소멸은 점차 빨라졌다. IPD 기법으로 성장한 양자점의 빠른 PL 소멸은 양자점 밀도와 종횡비 향상에 의한 파동함수 중첩의 증가와 구속 에너지 증가에 의한 것으로 설명된다.

• Elastomers and Composites
• /
• v.45 no.4
• /
• pp.263-271
• /
• 2010

Intermittent CSR testing was used to investigate the degradation of an FKM O-ring, also the prediction of its life-time. An intermittent CSR jig was designed taking into consideration the O-ring's environment under use. The testing allowed observation of the effects of friction, heat loss, and stress relaxation by the Mullins effect. Degradation of O-rings by thermal aging was observed between 60 and $160^{\circ}C$. In the high temperature of range ($100-160^{\circ}C$) O-rings showed linear degradation behavior and satisfied the Arrhenius relationship. The activation energy was about 60.2 kJ/mol. From Arrhenius plots, predicted life-times were 43.3 years and 69.9 years for 50% and 40% failure conditions, respectively. Based on TTS (time-temperature superposition) principle, degradation was observed at $60^{\circ}C$, and could save testing time. Between 60 and $100^{\circ}C$ the activation energy decreased to 48.3 kJ/mol. WLF(William-Landel-Ferry) plot confirmed that O-rings show non-linear degradation behavior under $80^{\circ}C$. The life-time of O-rings predicted by TTS principle was 19.1 years and 25.2 years for each failure condition. The life-time predicted by TTS principle is more conservative than that from the Arrhenius relationship.

• Journal of the Society of Disaster Information
• /
• v.14 no.1
• /
• pp.79-88
• /
• 2018

In this study, the changes of the expansion and strength according to the temperature of the emergency repairing expansion material were examined by cup foaming test and uniaxial compressive strength test, and the accelerated compression creep test was carried out to confirm the long term stability. Ramp & Hold test and accelerated compressive creep test were performed to evaluate the creep performance. The short - term creep test was used to determine the initial creep strain of the expanding material. The isothermal method using time - To evaluate the long - term compressive creep performance.

• The Journal of the Acoustical Society of Korea
• /
• v.17 no.8
• /
• pp.58-63
• /
• 1998

저주파 영역의 음파의 투과속도 측정에 기존의 펄스에코방법이나 투과법 (transmission method)가 이용되는 경우, 탐촉자 및 시편의 크기, 시편과 탐촉자 사이의 거 리가 사용하는 음파의 주파수가 작아질수록 대형화되어 측정에 어려움을 나타내게 된다. 따 라서 본 연구에서는 고분자 재료의 음향특성을 평가할 수 있는 간단한 방법으로써 고분자 재료의 주파수에 따른 동적 탄성률(dynamic modulus)을 시간-온도 중첩의 원리를 이용하여 측정하고, 고분자 내에서 저주파 영역의 음파의 전달 속도와 주파수에 따른 탄성율(elastic modulus), 전단 탄성률(shear modulus) 그리고 밀도의 관계식으로부터 음속을 측정하였다. 실험결과 주파수가 증가함에 따라 고분자 재료의 동적 탄성률이 증가하였으며, 음속도 주파 수에 따라 증가하였다. 본 연구에서 사용한 폴리우레탄 재료의 음속은 100Hz∼10kHz영역에 서 약1500m/sec에서 3000m/sec를 나타내었다.

• Journal of the Korean Geosynthetics Society
• /
• v.9 no.4
• /
• pp.75-84
• /
• 2010

In this study, the long-term performance tests, which have extensibility, creep deformation, installation resistance and durability characteristic, is conducted to apply geosynthetic strip in field. The strength reduction factors using the test results are evaluated in order to calculate long-term design tensile strength. First, the creep deformation was evaluated by both the stepped isothermal method(SIM) and the time-temperature superposition(TTS) method. The creep reduction factor is reasonable to apply 1.6. Second, the result of installation damage test had little damage of yarn, which affected strength of reinforcement. Therefore, it can be analyzed that the installation damage of geosynthetic strip has little effect of long-term design tensile strength. Finally, the durability reduction factor considering chemical, biological and outdoor exposure resistance is reasonable to apply 1.1, which is considered the stability and economic efficiency of reinforced earth wall using geosynthetic strip.

• Composites Research
• /
• v.32 no.6
• /
• pp.382-387
• /
• 2019

A single frequency strain mode test, a stress relaxation mode test, and a creep test using RH-DMA were performed to investigate the effects of relative humidity and temperature on the viscous properties of PET film. The relative humidity was 10%, 30%, 50%, 70%, and 90%. The temperature was considered to be 30~95℃ for single frequency strain mode tests, 30℃ and 70℃ for stress relaxation mode test, and 5~95℃ for creep test. According to the results, higher relative humidity results in lower storage modulus and loss modulus, but the maximum value of the loss modulus is not significantly affected by changes in relative humidity and is almost constant. Relaxation modulus decreases rapidly at the beginning and becomes constant, and as the temperature increases, it is susceptible to changes in relative humidity. Strain recovery also increases rapidly at the beginning and is susceptible to changes in relative humidity as the temperature increases. In addition, as the temperature increases, the degree of increase in creep compliance increases, and as the temperature rises above the glass transfer temperature, the degree of increase becomes very large. The master curve determined by the time-temperature superposition provides the information to predict the long-term performance under operating conditions such as relative humidity and temperature.