• Title/Summary/Keyword: 슬래그계

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An Experimental Study on Toxicity Evaluation of Melting Slag from MSWI Ash Using Microtox Bioassay (Microtox 생물검정을 이용한 소각재 용융슬래그의 독성평가)

  • Park, Sang-Goo;Kim, Geon-Hung;Han, Yang-Soo;Kim, Gil-Ho
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.674-677
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    • 2012
  • 본 연구에서는 기존 매립이나 지반보강재로 사용되던 소각재 용융슬래그를 고부가가치 수처리 여재로 활용하기 위하여 형광성 박테리아를 통한 Microtox 생물검정법으로 독성을 평가하였다. 소각재 용융슬래그의 독성평가 대조군으로는 기존의 수처리 여재인 입상활성탄(석탄계/야자계/목탄계), PP PE펠렛(Poly-Propylene Poly-Ethylene pallet), 표준여과사를 비교하였으며, 시료의 용출시험은 US EPA에서 제안한 TCLP 방법을 사용하였다. Microtox Acute Toxicity 평가 결과, 독성순위는 석탄계 입상 활성탄, 소각재 용융슬래그, 목탄계 입상활성탄, 야자계 입상활성탄, 표준여과사, PP PE 순으로 나타났으며, 실험에 사용된 모든 수처리 여재들은 급성독성을 고려하지 않는 무독성으로 나타났다. 따라서 소각재 용융슬래그가 수처리를 목적으로 수체에 편입시켜도 기존의 수처리 여재들과 비교할 때 수환경에 미치는 영향은 미미할 것으로 판단된다.

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An Experimental Study on the Construction Performances and Economical Evaluation of the Self-compacting Concrete by Cementitious Materials (결합재에 따른 자기충전 콘크리트의 시공성 및 경제성 평가에 관한 실험적 연구)

  • Kwon, Yeong-Ho
    • Journal of the Korea Concrete Institute
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    • v.29 no.3
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    • pp.315-322
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    • 2017
  • The purpose of this study is to investigate experimentally the construction performances and economical evaluation of the self-compacting concrete in actual site work after selecting the optimum mix proportions according to cementitious materials. Slag cement type of 46.5% slag powder and belite cement of 51.4% $C_2S$ content, lime stone powder as binders are selected for site experiment including water cement ratio. Also, test items for optimum mix proportion are as followings ; (1) Slump flow, 500 mm reaching time, V-type flowing time and U-box height (2) Setting time, bleeding, shortening depth and adiabatic temperature rising (3) Mixing time in plant (4) Concrete quantity and cost, quality control in actual concrete work. As test results, (4) Optimum water-cement ratio ; Slag cement type 41.0% and belite cement 51.0% (2) Setting time and bleeding finishing time of slag cement are faster, bleeding content of slag cement is higher, shortening depth and adiabatic temperature rising of belite cement type are lower (3) Optimum mixing time in batcher plant is 75 seconds and concrete productive capacity is about $100{\sim}110m^3/hr$. (4) Belite cement type is lower than slag cement type in material cost 14.0%, and concrete quantity in actual concreting work save 3.3% in case of belite cement type. Therefore, self-compacting concrete of belite cement type is definitely superior to that of slag cement type in various test items without compressive strength development.

Up-cycling of Air-cooled Ladle Furnace Slag : Environmental Risk Assessment and Mortar Compressive Strength Assesment of Binary and Ternary Blended Cement Using Air-cooled Ladle Furnace Slag (전기로 환원슬래그 Up-cycling : 환경위해성 평가 및 환원슬래그를 혼합하여 제조한 2성분계 및 3성분계 혼합시멘트 모르타르 압축강도 평가)

  • Cho, Han Sang;Mun, Young Bum;Moon, Won Sik;Park, Dae Cheol;Kim, Hyeong Cheol;Choi, Hyun Kook
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.3
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    • pp.159-164
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    • 2015
  • This study investigated the environmental risk for up-cycling of air-cooled ladle furnace slag (LFS) and evaluated the mortar compressive strength of binary and ternary blended cements using LFS of 3, 5, 10 wt%. Based on the Soil Environment Conservation Act standard, there was no environmental risk of the up-cycling of LFS. Results of mortar compressive strength assesment showed that the compressive strength of two blended cements using LFS of lower than 5 wt% was about 1.1 times superior to that of un-substituted cement (ordinary portland cement, OPC); however the compressive strength of those with LFS of 10 wt% decreased with 10% compared with that of OPC.

An Experimental Study on Ternary System Concrete Using Blast-furnace Slag and Fly-ash (고로(高爐)슬래그 미분말(微粉末)과 플라이애쉬를 이용(利用)한 3성분계(性分系) 콘크리트의 기초물성(基礎物性)에 관한 실험적(實驗的) 연구(硏究))

  • Lee, Hwa-Joong;Hong, Chang-Woo;Kim, Kyeong-Jin
    • Resources Recycling
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    • v.18 no.4
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    • pp.31-37
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    • 2009
  • The purpose of this study was to evaluate the effects of fly-ash and blast-furnace slag on strength development and durability of ternary blended concrete (TBC) and ordinary portland cement concrete as fly ash and slag contents. Main experimental variables were performed fly ash contents (0%, 10%) and slag contents (0%, 10%, 20%, 30%). The compressive and flexural strengths, chloride-ion rapid permeability and chemical attacks resistance were measured to analyze the characteristic of the developed TBC on hardened concrete. The test results showed that compressive and flexural strength of TBC increased as the slag contents increased from 0% to 30% at the long term of curing. It considers blast furnace slag used when fly ash content was up to 10%. The permeability resistance of TBC(fly ash 10%, blast 30%) was extremely good at the curing time 90 days. Also, the effects of added blast furnace slag on OPC and TBC were increased on the permeability and chemical attacks resistance.

초임계 이산화탄소를 응용한 개질 제강 슬래그의 Cs 및 Co 이온의 제거 특성

  • 김민길;원휘준;현재혁;김계남;오원진;정종헌
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.122-123
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    • 2004
  • 산업체에서 폐기물로 발생되는 제강 슬래그를 사용전 초임계 이산화탄소를 이용해 고온 고압에서 전처리를 통해 얻어진 제강 슬래그를 이용하여 토양 제염 후 발생하는 방사성 폐액 중에 포함되어 있는 성분 가운데 방사성이 높은 성분인 Cs 이온과 Co 이온을 제거하는데 활용함으로서 폐기물의 재활용에 의한 방사성 이온 제거 방안을 모색해 보고자 하였으며 이에 대한 연구는 환경보호 차원뿐만 아니라 폐기물 자원 회수라는 측면에서도 그 중요성이 크다고 할 수 있다.(중략)

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A Study on the Hydration Characteristics and Fundamental Properties of Ternary Blended Cement Using Ferronickel Slag (페로니켈슬래그 및 고로슬래그 미분말을 결합재로 사용한 삼성분계 시멘트의 수화 특성 및 기초물성에 관한 연구)

  • Cho, Won-Jung;Kim, Han-Sol;Ann, Ki-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.39-48
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    • 2020
  • The present study investigates the chemical reaction and performance of ternary blended binders by mixing ferronickel slag. Cement was replaced using ground granulated blast furnace slag and ferronickel slag, combined up to 50% of the replacement rate. The blended cements were tested by setting times, length change, compressive strength at 1, 3, 7, 28 days. X-ray diffraction and scanning electron microscope were conducted for detecting hydration products while the MIP and microhydation heat were used for examining morphological characteristics. The results showed that by adding ferronickel slag, Pozzolanic reaction occurred, forming a dense pore structure and the effect of reducing hydration heat and dry shrinkage was also found. The compressive strength at 28 days was lower than that of 100% OPC control specimen (OSP0), but ternary blended cements showed no significant difference compared to binary blended (OSP50). If the optimal mix is derived later and used for the purpose, the potential for use as a cement binder is expected.

Properties for Solidification of Sewage Sludge by Steelmaking Slag with $CaO-Al_{2}O_{3}-SiO_{2}$ system ($CaO-Al_{2}O_{3}-SiO_{2}$계 제강슬래그를 이용한 하수슬러지 고화체 물성연구)

  • Lee, Hoon-Ha;Sohn, Jin-Gun;Lee, Park-Seok;Cho, Gyu-Yong
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2006.05a
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    • pp.150-155
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    • 2006
  • 제강공정에서 발생되는 $CaO-Al_{2}O_{3}-SiO_{2}$계 조성을 갖는 2 차 정련슬래그 (래들 슬래그)를 이용하여 하수슬러지용 고화재개발 및 하수슬러지 고화체의 물성에 관한 연구를 수행하였다. 래들슬래그는 냉각과정에서 분화되는 성질이 있어 냉각후 분말상의 슬래그가 만들어진다. 분말상 슬래그의 주 결정상은 $12CaO{\cdot}7Al_{2}O_{3}$$2CaO{\cdot}SiO_{2}$로 구성되어 있다. $12CaO{\cdot}7Al_{2}O_{3}$ 상은 속경성 시멘트의 특징이 있다. 또한 $CaSO_{4}$와 혼합사용시 ettringite 상을 형성시켜 하수슬러지의 함수율 저감효과 및 강도발현 효과가 우수한 결과를 얻었다. $Cl^{-}$ 이온의 고정화면에서는 고화재중 래들슬래그의 혼합비가 높을수록 고화체 구조내에 $Cl^{-}$ 이온이 고정화되어 용출량은 감소하였다. 고화재로서 제강부산물을 사용하기 때문에 경제성이 있으며, $Cl^{-}$ 이온 함량이 높은 하수슬러지 고화재로서의 재활용이 기대된다.

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The Evaluation of Surface Scaling and Resistance of Concrete to Frost Deterioration with Freezing-Thawing Action by Salt Water (염화물이 함유된 동결수의 동결융해 작용에 따른 콘크리트의 내동해성과 표면열화 평가)

  • Kim, Gyu-Yong;Kim, Moo-Han;Cho, Bong-Suk;Lee, Seung-Hoon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.6
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    • pp.143-151
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    • 2007
  • This study presents the experimental results of frost durability including resistance to freezing-thawing and surface scaling of concrete. Mixing design was proportioned with the various water-binder ratio between 0.37 and 0.47 and three different binder compositions corresponding to Type I cement without any supplementary cementitious materials(OPC), Type II cement with 50% blast-furnace slag replacement(BFS50), and ternary cement with Type III cement, 15% fly ash, and 35% slag replacement (BFS35%+FA15%). Test results showed that the mixing design with BFS50% and BFS35%+FA15% exhibited higher durability factor than that made with OPC only. Finally, the use of blend cement containing slag can be used effectively in terms of frost durability of the concrete exposed to severe condition under coastal environment like as flying salt, sea water spray, etc.