• Title/Summary/Keyword: 스티렌 부타디엔 고무 폴리머

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A Study on the Compatibilization of Blends Based on Poly(phenylene ether) and Polyamide (Poly(phenylene ether)/Polyamide 블렌드의 상용화에 관한 연구)

  • 김형수;임종철
    • Polymer(Korea)
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    • v.25 no.3
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    • pp.441-449
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    • 2001
  • Compatibilization of blends based on poly(phenylene ether) (PPE) and polyamide (PA) has been practiced with the incorporation of a copolymer formed by grafting polystyrene onto polybutadiene latex (g-BS) which is further functionalized with maleic anhydride (MAH) (g-BS*) to impart reactivity with amine groups of PA. The major focus has been placed on the effect of the various structural factors in g-BS8 on the phase morphology and mechanical performance of the blends. For the balance of impact strength and heat resistance, it was important to locate g-BS n particles inside of the PPE phase, which was accomplished by the proper control of the molecular weight and amount of PS in g-BS*. For g-BS*'s having constant molecular weight and amount of PS, the reduction of MAH content or increase of rubber particle size in g-BS* resulted in the increase of domain size and consequently loss in mechanical properties. Based on the comparison made with the conventional PPE/PA blend comprising MAH grafted PPE as a compatibilizer, it was confirmed that the comparable level of mechanical performance can be achieved by an appropriate g-BS* type material with improved whiteness index.

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A Study on the Fundamental Properties of Cement Mortar Using Polymer Coated Crumb Rubber (폴리머 코팅 폐타이어 분말을 혼입한 시멘트 모르터의 기초적 성질)

  • Song, Hun;Jo, Young-Kug;Soh, Yang-Seob
    • Magazine of the Korea Concrete Institute
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    • v.8 no.6
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    • pp.163-172
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    • 1996
  • Recently, the disposal of used vehicle tires is a big social problem because the amount of used vehicle tires has been increased with development of' automobile industry. Many researches have been made on the recycling of used vehicle tires in the various fields of industry as well as construction industry. When the crumb rubber made of vehicle tires is mixed in cement concrete and mortar, it is indicated that the adhesive strength of interface between the crumb rubber and cement hydrates is very low. The purpose of this study is to improve the fundamental properties by increasing of the adhesion strength of styrene-butadiene rubber(SF3R) latex coated crumb rubber in ; cement mortar. SBR-modified mortar using crumb rubber is also tested as the same method. From the test results, the cement mortar using SBR latex coated crumb rubber have a good fundamental properties compared with that using uncoated crumb rubber. The mechanical properties of SBR-modified mortar using crumb rubber with polymer-cement ratios of 10% are also improved.

Vibration Damping Ratio Performance Evaluation According to the Polymer Mixing Rate of SBR-based Polymer Modified Mortar through Ultrasonic Pulse Analysis (초음파 펄스 분석을 통한 SBR계 폴리머 혼입 모르타르의 폴리머 혼입률에 따른 진 동감쇠비 성능 평가)

  • Jeong, Min-Goo;Jang, Jong-Min;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.6
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    • pp.543-551
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    • 2022
  • The mechanical performance and vibration damping ratio performance of a specimen according to the polymer mixing rate were evaluated for polymer modified mortar. As a polymer, Styrene Butadiene Rubber(SBR) liquid polymer with a solid content of about 49~51% was used, and the polymer content was increased by liquid 5%. The specimen was 40*40*160(mm), and after curing, compressive strength, flexural strength, and vibration damping ratio were measured using the ultrasonic pulse method. As a result, it was found that the compressive strength decreased as the polymer was mixed, but the flexural strength was increased. The vibration damping ratio increased by 11% at 5% polymer, 28% at 10% polymer, 33% at 15% polymer, and 72 at 20% polymer. I was found that the incorporation of the polymer was very effective to reduce the vibration of the mortar. In addition, through SEM and SEM-EDS analysis, it is determined that the cause of vibration reduction due to polymer mixing is that the polymer film formed in the transition zone of aggregate and internal voids buffered the vibration of the mortar inside. Taken together, in the scope of this study, the appropriate polymer mixing ratio for reducing the vibration of mortar is judged to be about 7.5%.