• Solar Energy
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• v.17 no.1
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• pp.67-77
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• 1997

To develop chemical heat pump of higher energy density and efficiency heat-release characteristics accompanied by exothermic hydration reaction in packed bed, $Ca(OH)_2/CaO$ reactor, are examined in a lab-scale unit. We have studied the enhancement effect of inserted fins in cylindical packed bed reactor. The results obtained by numerical analysis about profiles of temperature, completion time of reaction and exothermic heat amount released from the reactor read the insertion of fins in reactor can reduce the reaction completion time by half and the rate of thermochemical reaction depends on the temperature and concentration, and it is also governed by the boundary conditions and the rate of heat transfer in the particle packed bed.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.6
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• pp.189-196
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• 2020

When concrete member become large like in high rise buildings, hydration heat makes temperature difference inside and outside and cause cracks. The method of using latent heat material as heat reducer could be more accessible, usable and efficient than other methods. Therefore, many studies using PCM as heat reducer are being conducted. Since heat reducer have different reacting temperature, they may be affected by environmental factors like ambient and concrete mixing temperature but studies issuing this are insignificant. Therefore, this paper attempt to evaluate the hydration heat characteristics and quality of concrete using strontium-based PCM under hot weather conditions. As a result, when the strontium-based hydration heat reducer was mixed 3wt.% and 5wt.% in hot weather condition, hydration heat speed and heating rate could be reduced by 8%, 21%, and 75, 85 minutes compared to OPC, respectively. This is considered to be the phase change reaction is relatively promoted when the temperature is high and cause improve performance than room condition result. Later, comparing the efficiency of other types of P.C.M in hot weather condition, and conduct detailed reviews on the strength development in long-term age.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.6
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• pp.9-17
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• 2019

Cement hydrates and the related characteristics change with ages, and the behaviors are much related with chloride diffusion. In this work, 30% replacement ratio with FA(Fly Ash) and GGBFS(Ground Granulated Blast Furnace Slag) are considered for concrete with three levels of W/B (Water to Binder ratio) and 2 years of curing period. Chloride diffusion coefficients from accelerated condition are obtained at 5 measurement period (28days, 56days, 180days, 365days, and 730days), and the results are compared with porosity, binding capacity, and permeability from program-DUCOM. The similar changing pattern between chloride diffusion and permeability is observed since permeability is proportional to the square of porosity. Curing period is grouped into 4 periods and the changing ratios are investigated. Cement hydrate characteristics such as porosity, permeability, and diffusion coefficient are dominantly changed at the early ages (28~56 days), and diffusion coefficient in OPC concrete with low W/B continuously changes to 180days.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.489-497
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• 2022

In this study, the fluidity, mechanical properties and microstructure of cement pastes with carbon nanotube (CNT) were experimentally investigated. The 6 types of cement paste mixes with different PCE:CNT and w/b had been manufactured, and several tests including flow, compressive strength, absorption and water porosity were performed on cement pastes with or without CNT.Additionally, microstructural observations such as x-ray diffraction (XRD) and scanning electron microscopy (SEM) were carried out to examine hydrates formed in cement paste with CNT. As a result, it was found that the performance of cement pastes with CNT was better compared to that of control cement paste (OPC) due to both of hydration acceleration effect and filling effect. Furthermore, the SEM images clearly showed that CNT can bridge cracks formed in cement matrix. Conclusively, it is believed that the CNT, if mixed appropriately, could be an option as nono-materials to improve performance of concrete structures.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.2
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• pp.153-160
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• 2023

In this study, nano-sized C-S-H crystals were synthesized using the liquid phase reaction method and their properties were investigated. The synthesized C-S-H crystals were added to the cement composite in suspension form to determine their effect on the hydration properties of the cement. The amount of chemical admixture was varied to obtain nano-sized C-S-H crystals with optimal agglomerated morphology, and SEM photographs were analyzed. A cleaning process was added to remove harmful substances other than the synthesiz ed C-S-H crystals. It was found that the concentration of harmful substances was reduced in the case of C-S-H crystals subjected to the cleaning process. The synthesized C-S-H suspensions were prepared with and without the cleaning process, and cement composites were prepared with the cement weight content as the main variable. The effect of C-S-H crystals on the initial hydration properties of the cement was confirmed by microhydration heat analysis. In addition, mortar specimens were prepared to measure the compressive strength over time. The test results showed that the nano-sized C-S-H crystals act as nucleation sites in the cement paste to promote the early hydration of the cement and increase the early compressive strength.

• Journal of the Korea Institute of Building Construction
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• v.15 no.3
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• pp.265-271
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• 2015

This study is intended to produce a PC (Precast Concrete) member without a steam curing process in developing the high early strength concrete satisfying the condition of 10MPa in compressive strength at the age of 6 hours, and is intended to ensure economic feasibility by increasing the turnover rate of concrete form. Hence, high early strength cement with high $C_3S$ content and the hardening accelerator of powder type accelerating the hydration of $C_3S$ was used. And the properties of concrete were evaluated according to the hardening accelerator mixing ratio (0, 1.2, 1.6, 2.0). No big difference was found from the tests of both slump and air content. When 1.6 % or higher amounts of the hardening accelerator were mixed, the compressive strength of 10MPa was achieved at the age of 6 hours. From the test results of autogenous (drying) shrinkage and plastic shrinkage, it can be seen that there was a difference according to hydration reaction rate due to the addition of the hardening accelerator. However, it was shown that no problem arose with crack and durability. And it was shown that resistance to freezing-thawing, carbonation, and penetration were excellent.

• Journal of the Korean Ceramic Society
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• v.39 no.10
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• pp.943-947
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• 2002

In order to examine the possibility of incineration of inderstrial by-product and wastes which contains a large percentage of chlorine by the cement kiln, measured heat of hydration, setting time, flow, change of length, compressive strength of OPC by the amount of KCl. The result was that a shorter setting time, a lower flow, a increasing the degree of initial shrinkage, a increasing of compressive strength before 3 days and decrease after 7 days by the induction period is shorter as promote the hydration with KCl.

• Journal of the Korea Concrete Institute
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• v.27 no.2
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• pp.115-125
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• 2015

This study investigated the fluidity, heat of hydration, setting time, strength development, and characteristics of hydration and pozzolanic reactions of high-strength high-volume ground granulated blast-furnace slag(GGBFS) blended cement pasts with the water-to-binder ratio of 20% by experiments, and analyzed the effects of the replacement ratio and fineness of GGBFS on the hydration and pozzolanic reaction. The results show that, in the high-strength mixtures with low water-to-binder ratio, the initial hydration is accelerated due to the "dilution effect" which means that the free water to react with cement increases by the replacement of cement by GGBFS, and thus, strengths at from 3 to 28 days were higher than those of plain mixtures with ordinary Portland cement only. Whereas it was found that the long term strength development is limited because the hydration reaction rates rapidly decreases with ages and the degree of pozzolanic reaction is lowered due to insufficient supply of calcium hydroxide according to large replacement of cement by GGBFS. Also, the GGBFS with higher fineness absorbs more free water, and thus it decreases the fluidity, the degree of hydration, and strength. These results are different with those of normal strength concrete, and therefore, should be verified for concrete mixtures. Also, to develop the high-strength concrete with high-volume of GGBFS, the future research to enhance the long-term strength development is needed.

• Journal of the Korea Concrete Institute
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• v.27 no.2
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• pp.127-136
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• 2015

To evaluate the effects of limestone powder and silica fume on the properties of high-strength high-volume ground granulated blast-furnace slag (GGBFS) blended cement concrete, this study investigated the rheology, strength development, hydration and pozzolanic reaction characteristics, porosity and pore size distribution of high-strength mortars with the water-to-binder ratio of 20, 50 to 80% GGBFS, up to 20% limestone powder, and up to 10% silica fume. According to test results, compared with the Portland cement mixture, the high-volume GGBFS mixture had much higher flow due to the low surface friction of GGBFS particles and higher strength in the early age due to the accelerated cement hydration by increase of free water; however, because of too low water-to-binder ratio and cement content, and lack of calcium hydroxide content, the pozzolanic reactio cannot be activated and the long-term strength development was limited. Limestone powder did not affect the flowability, and also accelerate the early cement hydration. However, because its effect on the acceleration of cement hydration is not greater than that of GGBFS, and it does not have hydraulic reactivity unlikely to GGBFS, compressive strength was reduced proportional to the replacement ratio of limestone powder. Also, silica fume and very fine GGBFS lowered flow and strength by absorbing more free water required for cement hydration. Capillary porosities of GGBFS blended mortars were smaller than that of OPC mortar, but the effect of limestone powder on porosity was not noticeable, and silica fume increased porosity due to low degree of hydration. Nevertheless, it is confirmed that the addition of GGBFS and silica fume increases fine pores.

• Applied Chemistry for Engineering
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• v.3 no.1
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• pp.148-155
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• 1992

For the enhancement of the concrete durability, we developed high - durable portland cement (ACTPC) by physical treatment of ordinary portland cement with asphalt and carbon black. In this research, the hydration reaction characteristics of ACTPC were studied by using SEM, X-Ray, Conduction Micro Calolimeter etc. When the ACTPC is mixed with water, it is believed the asphalt films on cement particles suppress the early stage of hydration reactions of cements, because the films hinder the contact with water and the elusion of soluble ions from particles. But the carbon blacks on the cement particles accelerated the hydration reactions of cement after a while, because the micro particles can be used as seed crystals in $CaO-SiO_2-H_2O$ gel formation.