• Applied Chemistry for Engineering
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• v.3 no.1
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• pp.148-155
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• 1992

For the enhancement of the concrete durability, we developed high - durable portland cement (ACTPC) by physical treatment of ordinary portland cement with asphalt and carbon black. In this research, the hydration reaction characteristics of ACTPC were studied by using SEM, X-Ray, Conduction Micro Calolimeter etc. When the ACTPC is mixed with water, it is believed the asphalt films on cement particles suppress the early stage of hydration reactions of cements, because the films hinder the contact with water and the elusion of soluble ions from particles. But the carbon blacks on the cement particles accelerated the hydration reactions of cement after a while, because the micro particles can be used as seed crystals in $CaO-SiO_2-H_2O$ gel formation.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.1
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• pp.84-92
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• 2014

The purpose of study is to analyze mechanism with early high portland cement and hardening accelerator. As the result, it was concluded that hardening accelerator makes accelerates appearance of $Ca(OH)_2$ through experiment using TG-DTA when it hydrates with cement. On the result of compressive strength, as increasing the amount of hardening accelerator used, early compressive strength was improved. Also, as a result of hydration heat, hardening accelerator accelerates hydration of $C_3S$ that is cement's component. On the result of XRD's analyzation, hydration product for each age could be check and it was shown that as increasing the amount of hardening accelerator used, peak point of hydration product was recorded high. As the result of SEM, appearance of C-S-H was shown as the amount of $Ca(OH)_2$'s appearance and each age according to additive contents of hardening accelerator. Therefore hardening accelerator used on this study is effective on getting early compressive strength.

• Applied Chemistry for Engineering
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• v.10 no.8
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• pp.1124-1128
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• 1999

In this study the effect of organic additive, triethanolamine(TEA), and temperature change of accelerator for shotcrete was studied. Then the amount of accelerator, temperature and W/C were experimentally investigated. Effects of hydration time and hydration heat of concrete on organic additive amount were analysed by DSC, SEM and XRD. We found that the hydration heat was increased and hydration time was decreased with TEA(<5 wt %). The order of hydration rate of potassium accelerator was PA < PC-3 < PC-5 < PC-8.

• Journal of the Korean Geotechnical Society
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• v.36 no.11
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• pp.97-106
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• 2020

Swelling properties and shear strength behavior of MgO-Sand mixtures with hydration procese of MgO are compared according to different MgO contents (W_MgO/W_Total=0, 30, 50, 70, 100%) in this study. The specimens are prepared by mixing with crushed MgO refractory bricks and silica sand. After hydration, the particle size and the specific gravity of MgO were decreases. Through microstructure observation and X-ray diffraction analysis, it is confirmed that MgO changes from the cubic structure of Periclase to the hexagonal cubic structure of Brucite after hydration. As the MgO content increases, both swelling rate and swelling pressure of the mixtures increase. W_MgO/W_Total=30% specimen shows relatively low swelling pressure and swelling rate because produced Mg(OH)₂ mainly fills the pores between sand particles. However, in the case of MgO more than 50%, swelling pressure and swelling rate increase significantly because Mg(OH)₂ fills the pores of sand particles at first and then either pushes out sand particles or Mg(OH)₂ particles after filling the pores. As a result of the direct shear test, before hydration, the mixtures show a dilative behavior on high MgO contents and a contractive behavior on low MgO contents. However, after hydration, the behavior of all mixtures changes to contractive behavior. The threshold fraction of fine (i.e., Mg(OH)₂) contents of the hydrated MgO-Sand mixtures reveals approximately 60% compared with normalized shear strength.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.353-354
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• 2010

The relation between polymer and cement in a polymer-modified cement waterproofing membrane was investigated by using an electron probe micro-analyzer and numerical simulation.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.761-764
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• 2008

Most of ready-mixed concrete plants have the problem of construction waste sludge, which pollutes environment and causes economic loss due to the discard and increasing the cost of concrete. Thus, a recycling of the cement sludge has been strongly desired as one of their solution. This research is to the study on the recycling of the cement sludge, especially the study on the hydration control by the sodium gluconate as a set-retarder. The set-retarder can delay the hydration of the cement included in the sludge water, so that the sludge water can be substituted with some of new cement without the property of the cement. And it invests the effect of the sodium gluconate to the hydration of the cement in suspension. The degree of hydration of cement may be controlled by adding the sodium gliconate. The hydration delay time is observed that depends on the concentration of residual sodium gloconate, not how long the cement has been hydrated before the addition of the sodium gluconate.

• Korean Journal of Food Science and Technology
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• v.35 no.4
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• pp.660-665
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• 2003

Effect of freezing on the hydration rate and growth characteristics of bean sprout of two domestic cultivars of soybean, Eunha beans and Taegwang beans, was investigated. Freezing of the soybeans at $-80^{\circ}C$ affected characteristics of the hydration and growth of soybean sprout of the beans. Hydration rate of the frozen beans depended on the hydration temperature. It decreased up to 50% at lower than $60^{\circ}C$ of hydration temperature, but it did not decrease at higher than $60^{\circ}C$. Activation energies of frozen Eunha and Taegwang beans were 39.79 and 39.25 kJ/mol, respectively. Kinetic compensation effect between activation energy values and the pre-exponential factor for the hydration of soybeans with or without freezing was observed. Germination rate and thickness of the bean sprout increased by freezing, however, yield and weight were not affected by freezing.

• Cement Symposium
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• s.33
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• pp.101-108
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• 2006

• Cement Symposium
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• no.5
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• pp.88-93
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• 1977

시멘트 입도는 수화반응 속도에 밀접한 관계가 있으며 이로 인한 강도 발현 및 제반 물리특성에 크게 기여한다. 따라서 제품관리에 Blaine 및 sieve test로서 분말도를 check하고 있는바 이 분말도가 cement 물리특성에 미치는 영향을 실험실적으로 검토하였다.

• Proceedings of the Korean Ceranic Society Conference
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• 2004.04b
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• pp.52.1-52.1
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• 2004