• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.6
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• pp.182-188
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• 2018

Recently, various researches on the utilization of carbon nanotube(CNT) with superior electrical conductivity and large surface areas into concrete have been actively conducted. Thus, mechanical and thermal properties of cement-flyash composites were evaluated concerning the CNT replacements. Based on the low binder-to-water ratio, the cement composites were produced with 0.2 % and 0.5 % of CNT solids. The compressive strengths with various ages, isothermal calorimetry measurement, SEM analysis, thermal conductivity of cement composites and thermal gravimetry analysis were implemented. As the amount of CNT addition was increased, the thermal conductivity of cement composites were also increased. Also, there was no significant mechanical property differences between mixtures with and without CNTs.

• The Science & Technology
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• v.32 no.10 s.365
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• pp.18-20
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• 1999

21세기에는 하늘과 땅, 그리고 바다 밑에서 무한의 新에너지자원을 개발하여 에너지 걱정은 안해도 된다. 태양광발전 위성에서 전기를 얻고 해저의 메탄수화물을 개발하고 태양과 별들 속에서 일어나는 핵융합을 재현하면 충분히 공급할 수 있다는 것이다. 또 현재 개발할 수 있는 석유의 매장량은 1조배럴로 세계 소비수준으로 40년 분량이며 메탄수화물, 천연가스, 타르 샌드 등을 개발하면 앞으로 3세기는 충분히 공급할 수 있다는데.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.7
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• pp.95-104
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• 2018

The structures and energies of the anhydrate and hydrate (hydrate rate: h of 1) states of L-alanine (LA) and glycine (G) were calculated by quantum chemical calculations (QCCs) using B3LYP/6-31G(d,p) for four types of conformers (${\beta}$-extended: ${\Phi}/{\Psi}=t-/t+$, $PP_{II}$: g-/t+, $PP_{II}$-like: g-/g+, and ${\alpha}$-helix: g-/g-). In LA and G, which have an imino proton (NH), three conformation types of ${\beta}$-extended, $PP_{II}$-like, and ${\alpha}$-helix were obtained, and water molecules were inserted mainly between the intra-molecular hydrogen bond of $CO{\cdots}HN$ in $PP_{II}$-like and ${\alpha}$-helix, and attached to the CO group in ${\beta}$-extended. In LA and G, $PP_{II}$-like conformers were most stable in the anhydrate and hydrate states, and the result for LA was different from some experimental and theoretical results from other studies reporting that the main stable conformation of alanine oligopeptide was $PP_{II}$. The formation pattern and stability of the conformation of the oligopeptide was strongly dominated by the presence/absence of intra-molecular hydrogen bonding of $CO{\cdots}HN$, or the presence/absence of an $NH_2$ group in the starting amino acid.

• Journal of the Korea Concrete Institute
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• v.26 no.3
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• pp.287-297
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• 2014

Heat of hydration of mass concrete is one of the most important factors that significantly affect structural quality and construction period. Therefore, appropriate methods to control heat of hydration are essential technologies for mass concrete construction. In this study, probability of thermal cracking was checked by thermal analysis prior to the construction of a turbine foundation in a domestic power plant. Subsequently, changes of concrete mix proportion and an effective curing method were proposed to control heat of hydration of mass concrete structures. Concrete manufactured by slag cement was proposed instead of concrete produced by ordinary Portland cement, and an automated curing method was proposed to improve the curing method using typical moist curing with blanket. The automated curing method maintains the temperature difference between center and surface of concrete below a setting value by temperature monitoring. Concrete with slag cement was used for actual construction. One of two identical turbine foundations was cured by an insulated curing method, and the other was cured by the automated curing method to compare the curing methods. And then, the effects of control of heat of hydration were evaluated based on temperature/strain monitoring and crack investigations.

• Applied Biological Chemistry
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• v.18 no.3
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• pp.145-166
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• 1975

The calcium balance study was carried out to determine the availability of calcium in different sources for chicks and laying hens. The sources of calcium were calcium carbonate (CC), dicalcium phosphate-dihydrate (DCPH), and dicalcium phosphate-anhydride (DCPA) for chicks and calcium carbonate (CC) and oyster shell (OS) for laying hens. The radioisotope dilution method was employed to measure the endogenous excreta calcium during the period of balance study following preliminary feeding. A. Experimental results with chicks: No significant difference was found among feed consumption of chicks fed diets containing different sources of calcium. Body weight gain of chicks was dependent upon the source of calcium. The gain decreased in the order of DCPH, DCPA and CC (P<0.01). The feed conversion efficiency in chicks fed DCPH was better than those in chicks fed CC or DCPA. The average tibia ash contents for chicks fed different sources of calcium were similar. The DCPH was superior to CC or DCPA regarding the calcium content in tibia ash. There were no significant differences among the average calcium contents in plasma trichloracetic acid filtrate in chicks irrespective of calcium sources. The mean apparent retention of calcium by chicks fed DCPH, CC and DCPA were 65.9, 64.0 and 59.9% respectively. The calcium to phosphorus ratios in tibia ash and plasma trichloracetic acid filtrate for chicks fed different sources of calcium were similar. The chicks fed DCPH showed the partition of endogenous excreta calcium in total excreta calcium as 35.6% which was higher than 31.0 or 31.4% for chicks fed CC or DCPA. The endogenous excreta calcium per day per chick in group fed DCPH, DCPA or CC were 17.2, 16.1 and 14.6mg respectively. The true retained calcium per day per chick in group fed DCPH were 109.9 mg which was higher than those observed with CC or DCPA group (P<0.01). The true retention of calcium by the birds fed diets containing DCPH, CC or DCPA were 78.1, 75.1 or 72.6% respectively. B. Experimental results with laying hens: The feed consumption, egg production and feed converion efficiency of laying hens fed diets containing different sources of calcium were similar. Calcium concentration in plasma trichloracetic acid filtrate in laying birds fed CC was equivalent to the value obtained by feeding OS. The apparent calcium retention by laying birds fed CC was 61.6% and it was significantly more than that of hens fed OS of 51.6% (P<0.05). The partition of endogenous excreta calcium in total excreta calcium of laying hens fed CC was 23.5% and this was higher than that of birds fed OS of 15.6%. The laying hens fed CC showed 310 mg of endogenous excreta calcium per day per bird while birds fed OS showed 261mg. The true retention of calcium by layers fed CC was 70.7% against 59.2% for birds fed OS (P<0.05).

• Journal of the Korean Ceramic Society
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• v.38 no.8
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• pp.732-739
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• 2001

산업부산자원으로부터 유입되는 중금속이 시멘트 수화반응에 미치는 영향에 대하여 연구하였다. 출발물질은 순수시약을 사용하여 $C_3$S와 $C_2$S 조성으로 배합하고 여기에 Zn, Cu, Cr의 중금속 산화물을 1000ppm, 2000ppm, 3000ppm 첨가하여 150$0^{\circ}C$에서 1시간 소결하여 중금속의 고용분배, 결정구조, 용출상태 그리고 수화열을 관찰하였다. 중금속중 Zn는 $C_3$S와 간극질에 집중 고용되고 Cu는 간극물질에 집중 고용되며 Cr은 $C_3$S와 $C_2$S에 집중 고용되었다. 광학현미경 및 XRD 관찰결과 중금속 함량별로 $C_3$S와 $C_2$S의 결정상에는 큰 영향이 없는 것으로 나타났다. 그리고 7일간 수화시 Zn는 40~50%, Cu와 Cr은 전량 용출되었다. Conduction calorimeter 분석결과 중금속 함량별 변화에도 $C_3$S와 $C_2$S 수화열에는 차이가 없었다.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.385-386
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• 2009

The temperature crack of concrete structure is caused by the phenomenon which the concrete volume is restricted in the inside or outside part due th the temperature variations induced by the hydration heat of cement. And mass concrete structures are weak in temperature crack. This study performed the hydration heat analysis of Seongdeok dam to analyze the hydration heat according to different interval of placement.

• Journal of the Korean Society of Hazard Mitigation
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• v.10 no.5
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• pp.17-25
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• 2010

We studied on the watertightness improvement of cementitious material for durability enhancement of concrete. For improvement of watertightness of OPC and OPC with fly ash, we used various materials with watertightness properties to OPC and OPC with fly ash. The performance of watertightness improvement of cementitious materials closely related to formation of CSH by pozzolanic reaction and to reducing of size of contact angle in cement pore by using organic fatty acid. And volume of CSH formation at early hydration have an influence of watertightness improvement and reduction of long-term water absorption rate. In using of fly ash, improvement of workability by using the spherical fly ash caused to densify on the structures of cement material and CSH formation by pozzolanic reaction and cement using fly ash also caused watertightness improvement of cementitious materials. For improvement of concrete durability by watertightness, cementitious materials need using watertightness materials and at using fly ash, also it have to the effect of improvement of watertightness of cementitious materials by pozzolanic reaction.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.488-495
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• 2017

In this study, we conducted the kinetic hydration modeling of OPC and the final product according to the substitution ratio of GGBS by using the geochemical code, GEMS, in order to calculate the thermodynamic equilibrium. The thermodynamic data was used by GEMS's 3rd party database, Cemdata18, and the cement hydration model, the Parrot & Killoh model was applied to simulate the hydration process. In OPC modeling, ion concentration of pore solution and hydration products by mass and volume were observed according to time. In the GGBS modeling, as the substitution rate increases, the amount of C-S-H, which contributes the long-term strength, increases, but the amount of Portlandite decreases, which leads to carbonation and steel corrosion. Therefore, it is necessary to establish prevention of some deterioration.

• Journal of the Korean Society of Hazard Mitigation
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• v.6 no.2 s.21
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• pp.1-7
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• 2006

Recently, the massive concrete structures have been increasingly built in Korea. Many reinforced concrete structures have been reported to suffer from cracking in construction stages due to heat of hydration arising from mass concrete. This cracking may cause some serious durability problems and thus reduces the safety and service life of the structures. In this study, the stresses, strains, and temperatures were measured and the crack widths and crack Patterns were also observed in the footing and abutment structures. And the causes and mechanism in thermal cracking in the footing and abutment structures are thoroughly analysed. The comparisons of test results with analysis have been made. Efficient crack control techniques were developed form the experimental and analytical studies.