• Title/Summary/Keyword: 수질 변화

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Physico-Chemical Characteristics of Sediment in Sedimentation Tank of Infiltration Trench and Filtration System (비점오염저감시설인 침투도랑과 여과형 시설내 침강지 퇴적의 물리화학적 특성 분석)

  • Lee, Soyoung;Lee, Eun-Ju;Kim, Chulmin;Maniquiz, M.C.;Son, Youngkyu;Khim, Jeehyeong;Kim, Lee-Hyung
    • Journal of Wetlands Research
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    • v.9 no.3
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    • pp.35-42
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    • 2007
  • The paved areas such as parking lots and roads are stormwater intensive landuses since they are impervious and have high pollutant mass emissions from vehicular activity. Vehicle emissions include different pollutants such as heavy metals, oil and grease, particulates from sources such as fuels, brake pad wear and tire wear. Especially, the released heavy metals can be easily absorbed on the surface area of small particulate materials because of its ionic strength. Therefore, by constructing the sedimental tank in structural BMPs as a pre-treatment facility, the particles and heavy metals both can be removed from the runoff at an instant. To understand the physico-chemical characteristics of sediments from sedimentation tank, one-year study at an infiltration trench and filtration system was conducted to quantify the metal mass absorbed on sediments with various particle sizes. The structural BMPs for this study are located in Yongin City, Kyunggido. The research results show that Cu, Zn and Pb are dominant metal compounds in the sediments. Also the metal concentrations are highest at the ranges of $425-850{\mu}m$ particle sizes. The results will provide the basic physico-chemical information of sediments to treat it as solid wastes and to determine the design criteria of sedimentation tank in structural BMPs.

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Pervaporation Separation of Trace Toluene from Water Using Hydrophobic Copolyimide Membranes (소수성 폴리이미드공중합체 막에 의한 저농도 톨루엔함유 수용액의 투과증발분리)

  • Kim, Jeong-Hoon;Chang, Bong-Jun;Lee, Soo-Bok
    • Membrane Journal
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    • v.17 no.4
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    • pp.287-293
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    • 2007
  • Pervaporation separation of toluene from water were studied using hydrophobic copolyimide membranes. The copolyimide membranes were prepared from 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and two diamines (polysiloxane diamine (SIDA)/2-(perfluorohexyl) ethyl-3,5-diaminobenzene (PFDAB)). The pervaporation properties for toluene/water were investigated in terms of mol ratio of SIDA/PFDAB in polyimide membranes. Sorption- and diffusion-related properties were measured to analyze the permeation properties in solution-diffusion theory, It was found that as the SIDA content in the membranes increased, sorption of toluene and sorption selectivity of toluene/water increased due to high affinity of siloxane moiety toward toluene. Diffusion coefficient of toluene and diffusion selectivity of toluene/water also increased with SIDA content due to high free volume of siloxane moiety. As the results, the permeation flux and pervaporation selectivity increased markedly from 0.005 $kg/m^2h$ to 049 $kg/m^2h$ and from 9 to 6380, respectively.

Iron Extraction Characteristics of Sediment Samples from a River Bank Filtration Site (강변 여과 취수 지역 퇴적물의 철 화학종 추출 특성)

  • Hyun, Sung Pil;Moon, Hee Sun;Yoon, Pilsun;Kim, BoA;Ha, Kyoochul
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.2
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    • pp.129-138
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    • 2013
  • River bank filtration has been considered as a promising alternative water management scheme, in which groundwater is extracted from an aquifer near a river after infiltration of the river water into the aquifer, thereby improving and maintaining the quality of water recovered. Iron (Fe) associated with sediment in contact with groundwater and infiltrating surface water is an important factor in determining the quality of water recovered from the pumping wells in river bank filtration. This study reports the results of Fe speciation in the aquifer sediment samples collected from different depths at the river bank filtration site in Changwon, studied using four different chemical extraction methods, namely, ferrozine, oxalate, HCl, and DCB methods. Overall, the results show that Fe(II) as well as the total Fe content decreases with depth down to ~20 m and then increases further below. This trend is consistent with the redox characteristics suggested by visual observation. The silt/clay size fraction (${\phi}$ < 62.5 ${\mu}M$) has up to 2~10 times more Fe compared with the sand size fraction (62.5 ${\mu}M$ < ${\phi}$ < 2 mm), depending on the extraction method. Of the four extraction methods, DCB solution extracted the most Fe from the sediment samples. The amounts of Fe extracted by the different extraction methods can be a good indicator of the redox conditions along the depth of the aquifer.

Sludge Minimization by Using Dewater and Thermal Treatment in the Water Treatment Plant (탈수(脫水) 및 건조기법(乾燥技法)을 이용한 정수장(淨水場) 슬러지 감량화(減量化))

  • Jun, Hang-Bae;Kim, Yong-Han;Kim, Ryang
    • Journal of the Korea Organic Resources Recycling Association
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    • v.2 no.1
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    • pp.87-98
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    • 1994
  • Sludge minimization in an water treatment plant can be achieved by optimizing a main water treatment process as well as by enhancing a thickening and a dewatering facilities. In this study, dewatering and drying techniques for reducing the quantity of the water sludge generated from the conventional water treatment plant in the local states were investigated by reducing its water content. Not only the types and dosages of polymers but also the mixing intensity of the mixtures of a concentrated sludge and polymers on the different pH were evaluated for the optimum dewatering conditions of the water sludge. Weight reduction of the water sludge was also tested at a given temperature range. The dewatering efficiency of the water sludge was not affected by the types of polymer but by mixing intensity(GT value) in this study. pH effect on dewaterbility of the water sludge took a major role at the neutral pH range. The optimal polymer dose was 1.5 mg-polymer/g-TSS(about 40mg/L as polymer). Dewaterability was enhanced at a lower mixing intensity(GTbelow 10,000 sec-1). Free water in the void of sludge cake was dried around $100^{\circ}C$, chemical bound water was evaporated around $320^{\circ}C$, and organic material was burned out at the range of 300 to $600^{\circ}C$. Ignition losses of the water sludge were varied 15 to 40 % as the raw water quality. The ignition loss due to the chemical bound water was 10-20% and the loss due to the organic material was 4-20% of the total ignition loss.

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Evaluation of Field Application for the Developed Retrofitting Process and Analysis of Bacterial Community Structure in Pilot Plant (하수처리장 Retrofit 공정의 현장적용성 평가 및 세균 군집 분포 연구)

  • Kim, Mee-Kyung;Hong, Jun-Hyeok;Kim, Youn-Kwon;Ahn, Tae-Seok;Shin, Eung-Bai
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.240-248
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    • 2006
  • In this study, a retrofitting BNR process that was modified for the economical applicability was proposed and evaluated in the pilot plant($50m^3/d$). At the same time the bacterial community structure was investigated in the pilot plant by using FISH(fluorescent in situ hybridization) method. Economically 16% of the initial construction cost for the proposed process(introduction of a biological nutrient removal process of $60,000m^3/d$ scale basis) was reduced due to the absence of a bioreactor. Water treatment efficiencies and maintenance facilities of the modified process were satisfied with the strengthened discharge permits in Korea throughout a long term pilot plant operating including a winter season. Bacterial populations in the pilot plant and in the control plant(A2/O process, B SIP(Sewage Treatment Plant)) were remained uniformly during the test period, but bacterial structure in the bioreactor was changed drastically. Proportions of ${\beta}$-proteobacteria group including soil bacteria which play a important role in wastewater treatment increased $25{\sim}607%$ in population.

A Study on the Optimum Design of Horizontal Collectors in Floodplain Filtration (홍수터여과에서 집수관의 최적설계 연구)

  • Pi, Seong-Min;Kim, Seung-Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.6
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    • pp.430-437
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    • 2012
  • In order to obtain information on the design parameters of the horizontal laterals in floodplain filtration, laboratory-scale sand-box experiments were performed where the head distributions on the laterals and the groundwater profiles were measured according to the change in parameters including lateral diameter, hydraulic conductivity of the sand, water level at the well and raw-water supply rate. Measured data were analyzed using a numerical code in order to identify the discharge intensity distribution along the laterals. It was observed from the result that the lowering of the water level at the well had minimal adverse effect on the performance of the floodplain filtration. Results also elucidated that the low conveyance of the laterals to transmit the filtrate was compensated and supplemented by a natural augmentation in horizontal conveyance through the aquifer when the raw-water supply rate exceeded the adequate recovery rate. With this mechanism, the water quality is expected to improve further since the travel distance through the aquifer is amplified. Based on these findings it can be suggested that the diameter of the lateral used in the floodplain filtration may be smaller than those in riverbank/bed filtration. It was also found that the ratio between the head loss occurring in a lateral and the total head loss in the floodplain filtration was proportional to the exit velocities of the laterals, which may be used to design and/or evaluate the lateral in floodplain filtration.

Evaluation of Contamination Level of the Sediments from Chusori and Chudong Areas in Daechung Reservoir (대청호 추소 및 추동 수역 퇴적물의 오염도 평가)

  • Oh, Kyoung-Hee;Cho, Young-Cheol
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.5
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    • pp.277-284
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    • 2015
  • In order to analyze the contamination level of sediment samples taken from Chusori and Chudong areas in Daechung Reservoir, the particle size and concentrations of organics and nutrients were analyzed and phosphorus fractionation analysis was conducted. The average fraction of silt-sized particles was 92% in the sediments taken from Chudong area and Chusori area at the site adjacent to main current, which was higher than that from the upper Chusori area. The concentrations of total phosphorus in the sediments at Chusori and Chudong area were 999 (${\pm}98$) and 1,123 (${\pm}119$) mg/kg sediment, respectively. The fractions of autochthonous phosphorus, which can be readily eluted by change of environmental conditions, were much higher than those of allochthonous phosphorus, indicating the internal load can contribute the eutrophication in these areas. The concentrations of total nitrogen were over 5,600 mg/kg sediment in all samples, which is the guideline of Contamination Assessment of River and Lake Sediments of the Ministry of Environment, indicating the contamination level of total nitrogen is serious in the sediments. It is concluded that the countermeasures to manage the quality of sediments are required to improve the water quality in the Daechung Reservoir.

Aging Deterioration for Electric Power Transmission Tower on Offshore Through Periodic Inspections (해상송전철탑 구조물의 주기점검을 통한 경년열화 변화특성)

  • Lee, Ho Beom;Jang, Il Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.4
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    • pp.25-33
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    • 2012
  • In electric power transmission tower structures on offshore, implementation of life management using the event data of regular safety inspections for structural and material damages is strongly recommended. In this study, six tower structures in Sihwa Lake around Yeoungheung island were target bodies for the safety inspections. safety inspections for deterioration about each of six towers were performed about three items for steel member, five items for concrete foundation, and four items for steel-pipe pile in seawater and seawater itself. Safety inspections for steel members included the visual observations of surface appearances, the measurements of member thicknesses, and the checks of painting states. Also safety inspections for concrete foundations comprised the estimation of crack features, the evaluation of non-destructive compression strengths, and the measurements of neutralization depths and chlorides contents. For steel-pipe piles in seawater the inspections comprised the surveys of corrosion states in accordance with potential levels tests and anode tests, the analyses of photos taken on surfaces of the piles as well as the evaluation of seawater quality. A set of deterioration inspections was performed at the same positions around october of each year for three consecutive years. As a result in this study, Newly developed deterioration indexes have been applied profitably to maintain structural safety for electric power transmission towers by utilizing these event data systematically.

Influences of pH on Heavy Metal Leaching in Water Supply Pipelines (상수도관내 중금속 용출에 대한 수소이온농도의 영향 평가 연구)

  • Lee, Jeongwon;Noh, Yoorae;Park, Joonhong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.37 no.1
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    • pp.73-82
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    • 2017
  • In Korea, previous certification of water supply infrastructure was mainly focused on economical and physical aspects. Recently, hygienic safety of water supply service has become a sensitive and important issue to our people for evaluating the water quality with growth of economy and education system. According on water quality in 497 Korean water supply facilities, pH values in the supplied water have ranged between 5.8-8.5. However, little is known about metal leachability at the pH conditions observed in the real water supply systems because a fixed pH condition (pH 7.0) has been used in the current standard method, 'Hygienic Safety Testing Method', in water supply. In this work, we examined the effects on heavy metal leachability with pH differences in the water supply pipes which are typically used in Korea. As a result, the amounts of metal leachability were tended to increase when pH levels were decreased. Especially at pH 5.8, Cu leachability from Cu pipes was found to exceed the public health standard level even after applying a normalization factor (NF) given by the current Korea standard method. The Cr and Cu leached from stainless steel pipes, Cd, Pb, Cu, and Zn from Cu-based pipe fittings, and Zn from Zn-based pipe fittings were exceeded the Korean hygienic safety standards while, after applying the NF, concentrations of the leached metals were satisfied with the current Korean standard. The findings from this work provide implications on the needs of reforming the current hygienic safety standard methodology.

산업의 주식시장 선행성에 관한 소고(小考)

  • Kim, Jong-Gwon
    • Proceedings of the Safety Management and Science Conference
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    • 2007.04a
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    • pp.471-476
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    • 2007
  • 본 논문의 목적은 과거의 산업 포트폴리오 수익률이 확률추세로부터 어떻게 전체 주식시장과 두 가지 거시경제 변수인 경기동행지수와 산업생산 등을 예측할 수 있는 지를 알아보는 데에 있다. 이를 위하여 본 연구에서는 연구모형을 설정한 후 세 가지 검정절차를 제시하고 이를 실증적으로 분석하였다. 당월의 전체 주식시장 수익률은 과거의 시차를 지닌 특정 산업부문 포트폴리오 수익률에 대하여 양(+)의 상관관계를 유지하고 있다는 '예측 1'과 전체 주식시장의 수익률은 특정 산업부문의 수익률에 대하여 선행성을 지닐 수 없다는 '예측 2'에 대한 검정 결과는 '예측 1'과 '예측 2'가 지지되고 있음을 파악할 수 있었다. 그리고 산업별 포트폴리오 수익률과 거시경제변수 간의 높은 상관관계를 토대로 하여 전체주식시장 수익률 예측을 가능하게 하는 업종 정보의 점진적 확산 현상이 발생하게 되는가를 검토하기 위하여 각 산업들의 포트폴리오 수익률과 전체 주식시장 수익률이 VAR모형을 토대로 볼 경우 Granger 인과관계를 갖고 있는 지를 분석하였다. 분석결과 21개 업종은 각 산업별 포트폴리오 수익률이 전체 주식시장 수익률을 5% 수준에서 통계적으로 유의한 영향을 주고 있음을 알 수 있었다. 이들 21개의 산업별 포트폴리오 수익률은 경제적으로도 중요한 의미를 지니고 있어 산업제품의 가격 상승과 하락이 경제에 미치는 영향을 파악할 수 있다. 특히 음료 업종에서 전체 주식시장 수익률과 상호간의 인과성을 나타내었으며, 인터넷과 화장품 업종에서는 전체 주식시장 수익률이 이들 업종에 대하여 일방적인 영향을 보이고 있음을 알 수 있었다.>$mgN\;{\cdot}\;L^{-1}$ 및 0.000-0.804 $mgN\;{\cdot}\;L^{-1}$이였다. 규소농도는 0.0-6.2 $mgSi\;{\cdot}\;L^{-1}$의 범위로 3-5월에 매우 낮았으며, 계절적인 변화가 뚜렷히 나타났다. 저질의 입자는 0-125인 silt및 coarse silt로 이루어져 있으며, COD는 51.4-116.9 $mgO_2\;{\cdot}\;gdw^{-1}$로 평균 93.0 $mgO_2\;{\cdot}\;gdw^{-1}$ 이였다. 저질내의 TP및 TN의 농도는 각각 0.04-1.46 $mgP\;{\cdot}\;gdw^{-1}$ 및 0.12-1.03 $mgN\;{\cdot}\;gdw^{-1}$이었다. 표층의 엽록소 a의 정점별 평균값은 정점 1, 2 및 3에서 각각 15.6, 15.2 및 16.0 $mg\;{\cdot}\;m^{-3}$으로 유사하였다. 식물플랑크톤은 총 49종이 출현하였으며, 생물량은 50-23, 350 cells ${\cdot}\;mL^{-1}$로 2001년 9월에 가장 많았다. 이 시기의 우점종은 녹조류인 Schroederia judayi이였으며, 생물량은 20,417 cells ${\cdot}\;mL^{-1}$이였다. 송지호의 수질을 개선하기 위해서는 인위적으로 화학성층을 파괴시켜 심충에 용존산소를 공급시켜야 할 것으로 판단되며, 모래톱으로 인해 막혀져 있는 해수

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