• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.5
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• pp.119-125
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• 2020

Research on high-attenuation concrete for the vibration reduction performance by mixing epoxy-based synthetic resins and aggregates is actively being conducted. The curing time of high-attenuation concrete is very short because water is not used, and the physical and dynamic properties are very excellent. therefore, it is expected to be widely used in building structures requiring reduction of interior-floor noise and vibration. Furthermore, A way to expand the applicability of the high-damping concrete mixed with polymer in the field of reinforcement material have been variously studied. In order to replace polymer concrete with ordirnary concrete and existing anti-vibration reinforcement material, it is necessary to review overall vibration reduction performance considering physical properties, dynamic properties, productivity and field applicability. In this study, the physical and dynamic properties of polymer concrete by epoxy mixing ratio compared with ordirnary concrete. As a result, the elastic modulus was similar. On the other hand, polymer concrete for the compressive, tensile, and flexural strengths was quite more excellent. In particular, the measured tensile strength of polymer concrete was 4-10 times higher than that of ordirnary concrete. it was a big difference, and the frequency response function and damping ratio was studied through modal test and finite element analysis model. The dynamic stiffness of polymer concrete was 20% greater than that of ordirnary concrete, and the damping ratio of polymer concrete was approximately 3 times more than that of ordirnary concrete.

• Composites Research
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• v.12 no.4
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• pp.71-78
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• 1999

To determine the effect of chemical structure of linear amine curing agents on thermal and mechanical properties, standard epoxy resin DGEBA was cured with diaminodiphenyl methane (DDM), diaminodiphenyl sulphone (DDS) in a stoichiometrically equivalent ratio. From this work, the effect of aromatic amine curing agents. In contrast, the results show that the DGEBA/DDS cure system having the sulfone structure between the benzene rings had higher values in the conversion of epoxide, density, shrinkage (%), glass transition temperature, tensile modulus and strength, flexural modulus and strength than the DGEBA/DDM cure system having methylene structure between the benzene rings, whereas the DGEBA/DDM cure system presented higher values in the maximum exothermic temperature, thermal expansion coefficient, and thermal stability. These results are caused by the relative effects of sulfone group having strong electronegativity and methylene group having (+) repulsive property and stem from the effect of the conversion ratio of epoxide group. The result of fractography shows that the each grain size of the DDM/DGEBA system with feather-like structure is larger than that of the DDS/DGEBA system.

• Applied Chemistry for Engineering
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• v.26 no.5
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• pp.538-542
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• 2015

In this work, effects of the blend composition composed of 0, 10, 20, 30 and 40 wt% of nylon 6 to epoxy (diglycidylether of bisphenol-A, DGEBA) resin were investigated in terms of cure kinetics and thermal stability by differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA). As the content of the nylon 6 increased, the maximum exothermic temperature ($T_{max}$) and the value of cure activation energy ($E_a$) decreased. The maximum exothermic temperature of the blending samples decreased with increasing in nylon 6 content, resulting in the decrease in curing activation energy of them due to the rapid curing reaction with epoxy resin in this system. From TGA analysis results of the DGEBA/nylon 6, the thermal stability based on the thermal stability index ($A^*{\cdot}K^*$) and integral procedure decomposition temperature (IPDT) increased with increase in the nylon 6 content. This was because of the combination of DGEBA and nylon 6 having good heat resistance, resulting in improving thermal stability of the DGEBA/nylon 6.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.427-434
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• 2017

The generation of construction waste can be divided into a decommissioning phase and a new construction phase, and most of the waste is generated at the decommissioning stage. However, recently, domestic new construction construction has expanded to 150 trillion yards per year, so construction work is increasing rapidly. Especially, as the size of the construction work with much waste of construction waste exceeds 100 trillion, the management of the amount of construction waste in the new construction site is required. Unlike the dismantling work site, the new construction site can separate waste generated by each property, and relatively low foreign matter content is generated. The purpose of this study was to investigate the amount of construction waste generated by new construction sites and to calculate the unit amount of construction waste based on this. In addition, since the existing unit cost is centered on concrete and mixed waste, we set the basic unit by setting synthetic resin, waste wood, and waste board as additional items. The basic unit survey was carried out to investigate the wastes according to the characteristics of each construction period. As a result of the survey, the new construction site showed that most wastes were discharged in the first 30% and after 70% of the process, and the ratio of mixed construction waste was as high as 45%. As a result of this study, it was found that about twice as much waste was produced as compared with the conventional standard product.

• Composites Research
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• v.36 no.5
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• pp.297-302
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• 2023

There are several methods for shaping foams, but the most commonly used methods involve the use of resin mixed with a foaming agent, which is then foamed under high temperature and pressure in the case of compression foaming, or foamed under high temperature without applying pressure in the case of atmospheric foaming. The polymers used for foaming require design and analysis of optimal foaming conditions in order to achieve foaming under ambient pressure. Environmentally friendly bio-based polymers face challenges when it comes to foaming on their own, which has led to ongoing research in blending them with resins capable of traditional foam production. This study investigates changes in the characteristics of bio-based polymer-EVA blend foams based on variations in the content of bio-based polymers and explores the optimal foaming conditions according to crosslinking. The correlation between foaming characteristics and mechanical properties of the foams was examined. Through this research, we gained insights into how the content of bio-based polymers affects the properties of foams containing bio-based polymers and identified differences between ambient pressure and high-pressure foaming processes. Additionally, the feasibility of commercializing bio-based polymer-EVA composite foams was confirmed.

• Journal of the Korea Concrete Institute
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• v.18 no.2 s.92
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• pp.275-282
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• 2006

Recently, Fiber Reinforced Polymers(FRP) has been emerged as an alternative material to solve the corrosion of steel reinforcement in reinforced concrete structures. FRP exhibits higher specific strength and lower weight compared to steel reinforcement. Moreover, good resistance to corrosion of the FRP may be useful in aggressive environments causing deterioration such as chloride environment. However, causes for higher initial cost of FRP than that of steel, little information on the long-term behavior of FRP, and brittle failure make the efforts to apply FRP in civil structures slow. Glass fiber among the fibers used to manufacture FRP can be seen as the most beneficial material with regard to initial costs. But its low elastic modulus, which attains barely a quarter of steel, nay thus lead to excessive deflections when used as reinforcement for flexural members. This research was carried out on the tensile properties of hybrid rods made with glass and carbon fibers to improve those of FRP rod made with glass fiber. Parameters were resin type and the arrangement of glass and carbon fibers. The tensile properties of hybrid rods were compared with those of rods manufactured with only glass or carbon fibers. The results indicated that the tensile properties of hybrid rod were good when the carbon fiber was arranged in the core.

• Clean Technology
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• v.11 no.1
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• pp.41-50
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• 2005

In this study, semibatch emulsion copolymerization of n-BA as adhesive component and MMA as coagulant component were carried out for the stable acrylic polymer latex in aqueous phase for polymer cement using LE-type nonionic surfactant as environmental friendly surfactant. The stable polymer emulsion was obtained with the increases of chain length(n) of this surfactant. The effect on the amount of LE-50 as nonionic surfactant were showed that the concentration of polymer latex were increased by increasing the amount of LE-50, whereas the average particle size were decreased by increasing the amount. The addition of functional monomer in initial reactor charge showed a significant effect on the final polymer concentration and the latex particle size. The single polymerization of each n-BA or MMA showed a very low concentration of polymer latex and very big particle size due to coagulation. In the polymerization composed of mixed monomer with MMA and n-BA, the larger the ratio of MMA to n-BA in the copolymers, the greater the amount of coagulum produced. It was found that a stable copolymers were obtained in the range of 15-35 % of n-BA. Moreover, incorporation of some functional monomers in addition to of main monomers became more stable polymer latex. Through DSC and IR analysis, the final polymer latex was composed by MMA/n-BA/AA/AM with a single Tg depending on the reaction conditions. As a result, the conditions of this acrylic polymerization could also be effectively controlled to get the desired final products.

• Journal of Aquaculture
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• v.11 no.4
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• pp.487-493
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• 1998

This study was conducted to investgate the effect of fish meal analogue (FMA) on the growth of Israeli carp, Cyprinus carpio averageing 43g. Leather meal, meat and bone meal, feather meal, squid liver powder, poultry by-product and blood meal were used for ingredient of FMA. Four experimantal diets were formulated to contain 36% crude protein and 15.4 kJ available enery g-1. The percentage of follows ; Diet 1, 100% 3, 60% WFM + 40% FMA (40% FMA) ; Diet 4, 40% WFM + 60% FMA (60% FMA). In this expriment, fingerling Israeli carp averaging 43 g were assigned to each diet treatment. When the experiment was terminated, weigth gain (WG), feed conversion (FC), specific growth rate (SGR) and protein efficiency ratio (PER) were measured respectively. In the experiment, WG, FC, SGR and PER of Diet 2 were not significantly different from those of the control diet (P0.05). And WG, FC and SGR of Diet 3 were not significantly of the control Diet. In Diet 4, WG, FC and PER were not significantly different from those of the control Diet, but SGR was lower than that fo the control Diet. According to the results from this study, it might be possible to replace fish meal protein by FMA up to 60% in fingerling Israeli carp diets.

• Applied Biological Chemistry
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• v.10
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• pp.1-13
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• 1968

Phytin is a salt(mainly calcium and magnesium) of phytic acid and its purity and molecular formula can be determined by assaying the contents of phosporus, calcium and magnesium in phytin. In order to devise a new method for the quantitative analysis of the three elements in phytin, the chelatometric method was developed as follows: 1) As the pretreatment for phytin analysis, it was ashfied st $550{\sim}600^{\circ}C$ in the presence of concentrated nitric acid. This dry process is more accurate than the wet process. 2) Phosphorus, calcium and megnesium were analyzed by the conventional and the new method described here, for the phytin sample decomposed by the dry process. The ashfied phytin solution in hydrochloric acid was partitioned into cation and anion fractions by means of a ration exchange resin. A portion of the ration fraction was adjusted to pH 7.0, followed by readjustment to pH 10 and titrated with standard EDTA solution using the BT [Eriochrome black T] indicator to obtain the combined value of calcium and magnesium. Another portion of the ration fraction was made to pH 7.0, and a small volume of standard EDTA solution was added to it. pH was adjusted to $12{\sim}13$ with 8 N KOH and it was titrate by a standard EDTA solution in the presence of N-N[2-Hydroxy-1-(2-hydroxy-4-sulfo-1-naphytate)-3-naphthoic acid] diluted powder indicator in order to obtain the calcium content. Magnesium content was calculated from the difference between the two values. From the anion fraction the magnesium ammonium phosphate precipitate was obtained. The precipitate was dissolved in hydrochloric acid, and a standard EDTA solution was added to it. The solution was adjusted to pH 7.0 and then readjusted to pH 10.0 by a buffer solution and titrated with a standard magnesium sulfate solution in the presence of BT indicator to obtain the phosphorus content. The analytical data for phosphorus, calcium and magnesium were 98.9%, 97.1% and 99.1% respectively, in reference to the theoretical values for the formula $C_6H_6O_{24}P_6Mg_4CaNa_2{\cdot}5H_2O$. Statical analysis indicated a good coincidence of the theoretical and experimental values. On the other hand, the observed values for the three elements by the conventional method were 92.4%, 86.8% and 93.8%, respectively, revealing a remarkable difference from the theoretical. 3) When sodium phytate was admixed with starch and subjected to the analysis of phosphorus, calcium and magnesium by the chelatometric method, their recovery was almost 100% 4) In order to confirm the accuracy of this method, phytic acid was reacted with calcium chloride and magnesium chloride in the molar ratio of phytic: calcium chloride: magnesium chloride=1 : 5 : 20 to obtain sodium phytate containing one calcium atom and four magnesium atoms per molecule of sodium phytate. The analytical data for phosporus, calcium and magnesium were coincident with those as determine d by the aforementioned method. The new method employing the dry process, ion exchange resin and chelatometric assay of phosphorus, calcium and magnesium is considered accurate and rapid for the determination of phytin.

• The Korean Journal of Rheology
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• v.10 no.4
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• pp.217-226
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• 1998

The anisotropy caused by the fiber orientation, which is inevitably generated by the flow during injection molding of short fiber reinforced polymers, greatly influences dimensional accuracy, mechanical properties, and other quality of the final product. Since the filling stage of the injection molding process plays a vital role in determining fiber orientation, an accurate analysis of flow field for the filling stage is needed. Unbalanced filling occurs when a complex or a multi-cavity mold is used leading to development of regions where the fiber suspension is under compression. It is impossible to make an accurate calculation of the flow field during filling with the analysis assuming incompressible fluid. A mold with four cavities with different filling times was produced to compare the numerical analysis results with the experimental data. There was a good agreement between the experimental and theoretical results when the compressibility of the polymer melt was considered for the numerical simulation. The fiber orientation states for compressible and incompressible fluids were also compared qualitatively as well as quantitatively in this study.