• Title/Summary/Keyword: 수지온도

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Properties and Manufacture of High Density Woodceramics by Re-carbonization - Effect of Carbonization Temperature - (재 탄화에 의한 고밀도 우드세라믹 제조 및 성질 - 탄화온도의 영향 -)

  • Oh, Seung Won;Hwang, Jung Woo
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.6
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    • pp.517-523
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    • 2009
  • Repeated impregnation and carbonization processes were performed to prepare high-density woodceramics using a sawdust board. The physical properties were investigated to confirm morphological and structural changes of one-time and two-time phenolic resin-treated and carbonized woodceramics. As comparing between one-time and two-time carbonized woodceramics, the weight and the density of the two-time carbonized woodceramics decreased with an increase of the carbonization temperature. When the carbonization temperature was $600^{\circ}C$, the weight increased by 21.7% and density increased by 20.6% from $0.68g/cm^3$ to $0.82g/cm^3$, respectively, as a maximum value.

Effect of Aceton-Formaldehyde Resin Addition on Bonding Strength of Urea-Formaldehyde Resin Adhesive (요소수지(尿素樹脂)의 접착력(接着力)에 미치는 아세톤수지(樹脂) 첨가(添加)의 영향(影響))

  • Kim, Su Chang;Bae, Young Soo
    • Journal of Korean Society of Forest Science
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    • v.60 no.1
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    • pp.37-44
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    • 1983
  • Thermoplastic aceton-formaldehyde resin adhesive was added as a modifier for urea-formaldehyde resin adhesive and its effects on plywood smear strength and wood failure were investigated. The results are summarized as follows: 1) The plywood shear strength and wood failure showed the highest values at $120^{\circ}C$ of hot plate temperature, but the values decreased according to the rise of addition ratio of aceton resin. 2) The variation of molar ratio of aceton resin had no effect on plywood shear strength and wood failure. 3) The plywood bonded by the addition of aceton resin showed lower values than those of urea resin bonding plywoods in shear strength and wood failure. Therefore, aceton resin was inadequate as a modifier of urea resin adhesive.

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A Study on Adhesion Performance of Styrene-Block-Copolymer Based Hot Melt Pressure Sensitive Adhesives with Dicyclopentadiene Based Hydrogenated Hydrocarbon Resins (수첨 DCPD계 석유수지를 이용한 SBCs계 핫멜트점착제의 접착성능 연구)

  • Shim, Jaeho;Kim, Yunho;Lee, Jungjoon
    • Journal of Adhesion and Interface
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    • v.15 no.4
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    • pp.145-150
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    • 2014
  • Dicyclopentadiene (DCPD)-based hydrocarbon resins are widely used as tackifiers in many applications. In particular, hydrogenated DCPD-based hydrocarbon resins are widely used in premium hot-melt-type adhesives such as hot melt adhesives (HMAs) and/or hot melt pressure-sensitive adhesives (HMPSAs), because are water-white in color and possess excellent stability to light and heat. This article discusses the adhesive performance of various hydrogenated DCPD resins when they are used as tackifiers in styrene-block-copolymer (SBC)-based HMPSAs. This article shows the correlation between the characteristics of tackifiers and the adhesive performance of SBC-based HMPSAs. The higher the softening point of the tackifier, the higher is the $T_g$, softening point, and crossover temperature of the PSAs. High aromatic H wt% content reduces the high-temperature resistance of PSAs, as suggested by the decrease in the crossover temperature and softening point of the PSAs.

Synthesis and Characterisation of Acrylic-Modified Water-Reducible Alkyd Resin 1. Modification by TMPTA Graft Copolymerization (수용성 아크릴 변성 알키드수지의 합성과 물성 1.TMPTA그라프트 공중합에 의한 변성)

  • Cho, Young-Ho;Noh, Si-Tae
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.823-829
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    • 1993
  • The basic medium oil modified alkyd resin was synthesized from linseed oil fatty acid(LOFA), phthalic anhydride(PAA), trimellitic anhydride(TMA ), and trimthylol propane(TMP) by condensation polymerization at $230^{\circ}C$. TMPTA modified water-reducible alkyd resins were synthesized with TMPTA graft copolymerization onto the basic resin at $180^{\circ}C$. Acid value of the resin was controlled by the addition of TMA and N,N-Dimethylethanol amino(DMEA) was used as an neutralizing agent to prepare water-reducible alkyd. To evaluate the optimum formulation for anionic alkyd resin, water proofness and water reducibility were estimated from the acid value or TMA contents. The effect of TMPTA on the graft copoymerization of the resin was studied by measuring molecular weight, glass transition temperature(Tg), viscosity, and gel contents. The suitable balance of water proofness and water reducibility of the resin was obtained at range of 5.3~7.0wt.% of TMA contents or 40~50 of acid value of basic resin. The molecular weight, viscosity, and gel contents of water-reducible alkyd resin were increased according to the TMPTA graft copolymerization, but Tg was decreased.

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Deformation Behavior Investigation of Materials by Debonding Failure in Adhesion and Repairing-strengthening Methods of RC Construction (RC구조물 접착 보수·보강 공법의 박리와 연관한 재료의 변형 거동 분석)

  • Han, Cheon-Goo;Byun, Hang-Yong;Park, Yong-Kyu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.5
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    • pp.89-98
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    • 2007
  • This study investigates the deformation behavior, related to debonding failure, of adhesion and repairing-strengthening materials of RC construction. A strain-stress curve shows that when the stress of specimens reached the highest and then fails, the strain value of cement mortar is $2.0{\times}10^{-3}$, while concrete was indicated at around $1.3{\times}10^{-3}$, epoxy resins are $0.8{\times}10^{-3}$, polymer mortar is $2.5{\times}10^{-3}$, steel plate is $2.5{\times}10^{-3}$, and carbon bar was $9.1{\times}10^{-3}$, respectively. For a thermal expansion coefficient with temperature variation, those basis materials, cement mortar and concrete, exhibited around $10{\mu}{\varepsilon}/{^{\circ}C}$, but adhesive materials, such as epoxy resins and polymer mortar, were $41{\sim}54{\mu}{\varepsilon}/{^{\circ}C}$ and $-0.5{\sim}0.7{\mu}{\varepsilon}/{^{\circ}C}$, respectively. In the case of steel plate is similar to basic materials but carbon fiber is indicates at $-1.7{\mu}{\varepsilon}/{^{\circ}C}$, which is the lowest value. Especially, between basic and adhesive materials, the thermal expansion coefficient was highly different. Although the coefficient depends on the type of epoxy resins, it is clear that the epoxy resins are susceptible to be debonded in nature, when the difference of environmental temperature varies more than $20{\sim}35{^{\circ}C}$.

The Relation between Injection Molding Conditions and Gloss of ABS Molding (사출성형 조건과 ABS 성형품 광택의 관계)

  • Han, Seong-Ryeol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.11
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    • pp.5352-5356
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    • 2013
  • Plastic product manufacturing industry has usually focused on a mechanical and physical characteristics of molding. Recently, not only these characteristics but also the aesthetic value is significantly considering. Especially, the molding's gloss, which we can easily distinguish, is an important aesthetic point. In this study, it were investigated that the gloss variation of ABS moldings by changing injection conditions such as injection pressures, injection speed, holding pressures melt and mold temperatures by injection molding experiment. The experimental results revealed that the holding pressure was the most active condition on gloss of ABS molding.

The Prognostic Model for the Prediction of the Road Surface Temperature by Using the Surface Energy Balance Theory (지표면 에너지 수지 이론을 이용한 도로노면온도예측을 위한 예단 모델 개발)

  • Song, Dong-Woong
    • Journal of the Korean Geotechnical Society
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    • v.30 no.11
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    • pp.17-23
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    • 2014
  • In this study, the prognostic model for the prediction of the road surface temperature is developed using the surface energy balance theory. This model not only has a detailed micro meteorological physical attribute but also is able to accurately represent each surface energy budget. To verify the performance, the developed model output was compared with the German Weather Service (DWD)'s Energy Balance Model (EBM) output, which is based on the energy budget balance theory, and the observations. The simulated results by using both models are very similar to each other and are compatible with the observed data.

Evaluation of Thermal Degradation of CFRP Flexural Strength at Elevated Temperature (온도 상승에 따른 탄소 복합재의 굽힘 강도 저하 평가)

  • Hwang Tae-Kyung;Park Jae-Beom;Lee Sang-Yun;Kim Hyung-Geun;Park Byung-Yeol;Doh Young-Dae
    • Composites Research
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    • v.18 no.2
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    • pp.20-29
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    • 2005
  • To evaluate the flexural deformation and strength of composite motor case above the glass transition temperature$(T_g),\;170^{\circ}C$, of resin material, a finite element analysis(FEA) model in which material non-linearity and progressive failure mode were considered was proposed. The laminated flexural specimens which have the same lay-up and thickness as the composite motor case were tested by 4-point bending test to verify the validity of FEA model. Also. mechanical properties in high temperature were evaluated to obtain the input values for FEA. Because the material properties related to resin material were highly deteriorated in the temperature range beyond $T_g$, the flexural stiffness and strength of laminated flexural specimen in $200^{\circ}C$ were degraded by also $70\%\;and\;80\%$ in comparison with normal temperature results. Above $T_g$, the failure mode was changed from progressive failure mode initiated by matrix cracking at $90^{\circ}$ ply in bottom side and terminated by delamination at the center line of specimen to fiber compressive breakage mode at top side. From stress analysis, the progressive failure mechanism was well verified and the predicted bending stiffness and strength showed a good agreement with the test results.

Development of simulation method for heating line optimization of E-Mold by using commercial CAE softwares (전산모사 프로그램을 이용한 E-MOLD의 Heating Line 배치의 최적화 설계에 관한 연구)

  • Chung, Jae-Youp;Kim, Dong-Hak
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.6
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    • pp.1754-1759
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    • 2008
  • To produce plastic parts that have fine pattern through conventional injection molding, a lot of difficulties follow. Therefore, rapid heating and cooling methods are good candidates for manufacturing injection-molded parts with micro/nano patterns. In this study, we adopted the E-Mold patent technology. The mold for E-Mold technology has a separate heated core with micro heaters. It is very important to optimize the lay-out of the heaters in heated core because it influences both control and distribution of mold temperature. We developed a optimization method of heating line lay-out by using commercial softwares and compared the output with the experimental results. We used Pro-Engineer Wildfire 2.0 for the mold design, ICEMCFD for mesh generation, and FLUENT for heat transfer simulation. The simulation results showed the temperature profile from $60^{\circ}C$ to $120^{\circ}C$ or $180^{\circ}C$ during heating and cooling process which were compared with the injection molding experiments. We concluded that the simulation could well explain the experimental results. It was shown that the E-Mold optimization design for heater lay-out could be available through the simulation.

Studies on Finshing of Silk Fabric with Urea Formaldehyde Resin. (견직물에 대한 요소수지가공에 관한 연구)

  • 유영철
    • Journal of Sericultural and Entomological Science
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    • v.27 no.2
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    • pp.47-53
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    • 1985
  • The studies on the reaction of Urea-Formaldehyde(UF) resin with silk fabric were studied, and the final results summarized as below; 1. The pH and UF molar ratio for preparing liquid resin was found at pH 4-5 and UF molar ration 1:2 and above. 2. The weight gains were increased with respect to increase in concentration of UF resin solution, while moisture regains were decreased. 3. The weight gains were significant high in case of wet pick up 70%. 4. The weight gains were increased with respect to increase in curing temperature and the amount of catalyst((NH4)2SO4) found was 2.5% on the weight of Dimethylol urea and Hydrochloric acid was 1%, Tartaric acid was 10%. 5. The effect of different catalyst on wash fastness of UF resin was good where as in case of acidic catalyst was significantly high. 6. The weight gains with different catalyst was high where as in case of potential acid catalyst was significantly high. 7. The crease recovery are increased with the increase of the weight gain of silk fabric and also stiffness are increased.

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