• Proceedings of the Korean Environmental Health Society Conference
• /
• 2005.11a
• /
• pp.138-142
• /
• 2005

DGM은 상온에서 휘발성을 가지는 수은의 독특한 화학적 성질 때문에 쉽게 대기로 방출될 수 있고, 대기 중으로의 DGM 방출은 수체 내 수은의 유일한 제거 기작일 뿐만 아니라, 고정상으로 존재하던 수은이 다시 이동상의 수은으로 변화하는 중요한 과정이다. 본 연구는 2005년 8월과 10월에 주암호를 대상으로 실시간 자동분석 장치(Tekran 2537A)를 이용하여 DGM 농도변화를 관찰하였다. 전반적인 주암호(n=23)의 여름철 평균 BGM 농도는 110 ${\pm}$ 21 pg $L^{-1}$으로 기존에 발표된 국외 호수에서의 DGM 농도보다 약 3배정도 높았다. 강우에 따른(강우량 : 0.4 mm) DGM 농도 변화는 비가오기 전 89 pg $L^{-1}$ 에서 비온 뒤 89 pg $L^{-1}$ 으로 약 9%가 증가했다. 그러나 가을철 평균 DGM 농도(n=21)는 20 ${\pm}$ 0.4pg $L^{-1}$ 로 여름철보다 약 5.5배 감소했고, 비가 내리는 날씨에서의 DGM 농도는 13.7 pg $L^{-1}$ 로 맑은 날 같은 시간에 비해(32 pg $L^{-1}$) 약 58% 감소했다.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.15 no.1
• /
• pp.22-27
• /
• 2001

We presented a modified triangular interlerorreter as an incoherent holography, which can eliminate bias and conjugate image problems of the conventional one. Also, to demonstrate the feasibility of incoherent holograrphy, the formation of an incoherent hologram using a mercury lamp and its numerical and optical reconstructions were presented.sented.

• Clean Technology
• /
• v.27 no.3
• /
• pp.207-216
• /
• 2021

Major anthropogenic emissions of elemental mercury (Hg⁰) occur from coal-fired power plants, and the emissions can be controlled successfully using NH₃-SCR (selective catalytic reduction) systems with catalysts. Although the catalysts can easily convert the gaseous mercury into Hg²⁺ species, the reactions are greatly dependent on the flue gas constituents and SCR conditions. Numerous deNO_xing catalysts have been proposed for considerable reduction in power plant mercury emissions; however, there are few studies to date of elemental mercury oxidation using SCR processes with MW- and full-scale coal-fired boilers. In these flue gas streams, the chemistry of the mercury oxidation is very complicated. Coal types, deNO_xing catalytic systems, and operating conditions are critical in determining the extent of the oxidation. Of these parameters, halogen element levels in coals may become a key vehicle for obtaining better Hg⁰ oxidation efficiency. Such halogens are Cl, Br, and F and the former one is predominant in coals. The chlorine exists in the form of salts and is transformed to gaseous HCl with a trace amount of Cl₂ during the course of coal combustion. The HCl acts as a very powerful promoter for high catalytic Hg⁰ oxidation; however, this can be strongly dependent on the type of coal because of a wide variation in the chlorine contents of coal.

• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 2004.11a
• /
• pp.166-167
• /
• 2004

• Journal of Aquaculture
• /
• v.18 no.4
• /
• pp.280-286
• /
• 2005

Experiments were conducted to examine the differences in ammonia removal rates with the different filter media between sand and zeolite, the expanding rates between $50\%$ and $100\%$, the water temperatures between $15^{\circ}C$ and $25^{\circ}C$, and the ammonia loading rates between 2 mg/L and 5 mg/L in the seawater fluidized bed filters system (FBF). The 2.1 m high FBF (8.3 cm diameter) consisted of the clear acrylic for the upper half and a PVC pipe for the lower half, Sand and zeolite were used as the filter media in sizes of 0.5$\pm$0.1mm. Each biofilter contained 5.4 L of media. The ammonia removal rates of the biofilter were higher at the $25^{\circ}C$ water temperature than those of the biofilter at $15^{\circ}C$ water temperature, and higher at the $50\%$ expanding rate of filter media than those of the biofilter at $100\%$ expanding rate of filter media. Also, the ammonia removal rates of FBF were higher at 5 mg/L ammonia concentration than those of FBF at 2 mg/L ammonia concentration in rearing water. With these better conditions the ammonia removal rates of FBF per day are practically acceptable and ranged ken 80.6 to $210.6g/m^3$.

• Clean Technology
• /
• v.28 no.1
• /
• pp.38-45
• /
• 2022

CuCl₂-loaded V₂O₅-WO₃/TiO₂ catalyst showed excellent activity in the catalytic oxidation of elemental mercury to oxidized mercury even under SCR condition in the presence of NH₃, which is well known to significantly inhibit the oxidation activity of elemental mercury by HCl. Moreover, it was confirmed that, when SO₂ was present in the reaction gas together with HCl, excellent elemental mercury oxidation activity was maintained even though CuCl₂ supported on the catalyst surface was converted to CuSO₄. This is thought to be because not only HCl but also the SO₄ component generated on the catalyst surface promotes the oxidation of elemental mercury. However, in the presence of SO₂, the total mercury balance before and after the catalytic reaction was not matched, especially as the concentration of SO₂ increased. In order to understand the cause of this, further studies are needed to investigate the effect of SO₂ in the SnCl₂ aqueous solution employed for mercury species analysis and the effect of sulfate ions generated on elemental mercury oxidation. It was confirmed that SO₂ also promotes NO_x removal activity, which is thought to be because the increase in acid sites by SO₄ generated on the catalyst surface by SO₂ facilitates NH₃ adsorption. The composition change and structure of the components present on the catalyst surface under various reaction conditions were measured by XRD and XRF. These measurement results were presented as a rational explanation for the results that SO₂ enhances the oxidation activity of elemental mercury and the NO_x removal activity in this catalyst system.

• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 2009.10a
• /
• pp.592-593
• /
• 2009

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.22 no.5
• /
• pp.1-6
• /
• 2021

Mercury, once released, is not destroyed but accumulates and circulates in the natural environment, causing serious harm to ecosystems and human health. In the United States, sulfur-impregnated activated carbon is being considered for the removal of vapor mercury from the flue gas of coal-fired power plants, which accounts for about 32 % of the anthropogenic emissions of mercury. In this study, a high-efficiency porous mercury adsorption material was developed to reduce the mercury vapor in the exhaust gas of coal combustion facilities, and the mercury adsorption characteristics of the material were investigated. As a result of the investigation of the vapor mercury adsorption capacity at 30℃, the silica nanotube MCM-41 was only about 35 % compared to the activated carbon Darco FGD commercially used for mercury adsorption, but it increased to 133 % when impregnated with 1.5 % sulfur. In addition, the furnace fly ash recovered from the waste copper regeneration process showed an efficiency of 523 %. Furthermore, the adsorption capacity was investigated at temperatures of 30 ℃, 80 ℃, and 120 ℃, and the best adsorption performance was found to be 80 ℃. MCM-41 is a silica nanotube that can be reused many times due to its rigid structure and has additional advantages, including no possibility of fire due to the formation of hot spots, which is a concern when using activated carbon.

• Journal of Environmental Health Sciences
• /
• v.23 no.4
• /
• pp.21-25
• /
• 1997

A study on the removal of mercury by Saccharomyces cerevisiae and Aureobasidium pullulans was done, in which the model of adsorption isotherm and adsorption rate was proposed. The adsorption isotherm of mercury by S. cerevisiae was accorded with Langmuir model but A. pullulans was followed to Freundlich model. The amount of mercury removed by A. pullulans was higher than that of S. cerevisiae, but the adsorption rate of mercury by A. pullulans was slower than that of S. cerevisiae. In a rapid adsorption process, therefore, it is more useful to use S. cerevisiae as a biosobent.

• Journal of the Korean Chemical Society
• /
• v.41 no.8
• /
• pp.392-398
• /
• 1997

A method of selective determination of inorganic and organic mercury compounds has been described. The $CHCl_3$ solution of a high molecular quaternary alkylammonium salt, Aliquat 336 was used for the simultaneous preconcentration of both inorganic, $Hg^{2+}$ as its thiocyanate complex, and organic mercury compounds, $CH_3HgCl$ and $C_2H_3O_2$ $HgC_6H_5$ by extraction from their aqueous solution. Selective separation of the inorganic mercury from the extract was followed by stripping with 3 M $HClO_4 $ solution for the subsequent determination by CVAAS. Organic mercury was also determined by CVAAS after removal of $CHCl_3solvent$ from the extract and decomposition of the residue with 4% $KMnO_4 $-1 MH_2$S0_4$. The mixtures of inorganic and organic mercury compounds contained 1.0 $\mug$ as Hg in 50 mL of sample solution(0.02 ${\mu}gHg/mL$) were analysed within ${\pm}6%$ by absolute errors.