• Title/Summary/Keyword: 수은제거

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Comparison of Cold Vapor Atomic Absorption Spectrophotometry Analysis and EPA Method 101A for Measurement of Mercury in the Flue Gas (배출가스중 수은 측정을 위한 환원기화 원자흡광광도법과 EPA Method 101A의 비교 연구)

  • 김경희;최양일;박일수;홍지형;차준석;석광설;김대곤
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.92-93
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    • 1999
  • 수은은 상온에서 액체상태로 존재하는 유일한 금속으로서, 증기압이 매우 높기 때문에 가장 쉽게 휘발될 수 있는 중금속이다. 다른 중금속들은 거의 입자 상태로 변환되기 때문에 전기 집진기 등과 같은 일반적인 입자 제어시설에서 98%이상이 제거되지만, 증기압이 매우 높은 수은은 다단계 습식 스크러버, 활성탄을 사용하는 전기집진기/습식 스크러버가 결합된 특정한 방지시설에 없는 한 거의 대부분이 그대로 배출된다.(중략)

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A Study on the Emission Characteristics of Mercury from Municipal Solid Waste Incineration (생활 폐기물 소각시설에서의 수은 배출특성에 관한 연구)

  • 강경희;홍지형;최양일;박일수;차준석;석광설;김대곤
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.04a
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    • pp.103-104
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    • 2000
  • 수은은 상온에서 액체상태로 존재하는 유일한 금속으로서, 증기압이 매우 높기 때문에 가장 쉽게 휘발될 수 있는 중금속이다. 다른 중금속들은 거의 입자 상태로 변환되기 때문에 전기 집진기 등과 같은 일반적인 입자 제어시설에서 98%이상이 제거되지만, 증기압이 매우 높은 수은은 다단계 습식 스크러버, 활성탄을 사용하는 전기집진기/습식 스크러버가 결합된 특정한 방지시설에 없는 한 거의 대부분이 그대로 배출된다. (중략)

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EXPERIMENTAL ESOPHAGEAL INJURY WITH DISC BATTERY (수은전지에 의한 식도손상)

  • 박언우;남부현;나기상;유장열;박찬일
    • Proceedings of the KOR-BRONCHOESO Conference
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    • 1987.05a
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    • pp.14-14
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    • 1987
  • 최근 수은전지의 사용이 증가함에 따라 이에 의한 식도이물의 가능성도 증가하게 되었다. 저자는 수은전지에 의한 식도손상을 관찰하기 위하여 가토(1.7kg~2.5kg)에서 수은전지(충전된 전지, 방전된 전지)와 같은 모양, 크기의 철판(대조군)을 상절치에서 약 15cm되는 식도에 삽입 후 시간별로(1, 3, 6, 12, 24시간)육안적, 조직학적 관찰을 하였다. 충전된 전지를 삽입한 군에서는 삽입 후 1시간부터 식도손상을 보였고 시간경과에 따라 그 정도가 심해졌으며, 방전된 전지를 삽입한 군에서는 삽입후 3시간부터 식도손상을 보였고 시간 경과에 따라 그 정도가 심해졌으나 충전된 전지군에 비하여는 경한 손상을 보였으며, 대조군에서는 삽입 후 24시간까지 손상을 보이지 않았다. 따라서 수은전지에 의한 식도이물은 조기에 심한 식도손상을 초래하므로 가능한 한 신속히 제거해야 할 것으로 생각된다.

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3rd Order Type Mercury Rotate Marine Light with LED Optical System (LED광학 시스템이 포함된 3등대형 수은조식 해상용 등명기 개량)

  • Kim, Yeong-Jae;Kang, Dae-Woong;Lee, Yong-Jae;Jeong, Hwan;Lee, Jong-Bok;Shin, Kyung-Ho;Park, Kwang-Woo;Yoo, Seong-Hwan
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2017.11a
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    • pp.206-208
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    • 2017
  • In recent years, we have been working on the improvement project of mercury 3-lecture type at the Geummundo lighthouse for more than 100 years. We have installed toxic mercury removal, LED light source, and dualization system for nonstop. It can be seen as an example. Circular restoration of the entire frame is performed, and the real-time status can be grasped through the installation of the double-ball bearing and the remote control system. After installation, optical measurement through Hanvit secured the optical performance of 2,000,000 cd of floating brightness of 300cd, proving the efficient possibility of introducing the domestic rotary type light source using LED light source.

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A Study on the Separation of Mercury from Spent Mercury Batteries (단추형 폐수은 전지로부터 수은 분리에 관한 연구)

  • 손정수;박경호
    • Resources Recycling
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    • v.3 no.1
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    • pp.32-37
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    • 1994
  • Mercury in spent button type batteries can be separated and recovered with vacuum distillation method. It was found that mercury in the battery began to distill at $150^{\circ}C$ and organic substanced like a packing material was decomposed at$ 300^{\circ}C$. More than 99.9% of mercury contained in the battery was distiled and separated at about $250^{\circ}C$ and 20 torr with 8 hours' reaction time. The dissolution tests of the residue after distillation showed that mercury concentration in the solution were lower than 5 ppb and this values satisfied the environ-mental condition. Also as the furnace heating rate was above $15^{\circ}C$/min, it was found that the spent battery was destroyed because of increased pressure in the battery inside.

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A Study on Applicability of Mercury-contaminated Tailing and Soil Remediation around abandoned Mines using Washing Process (세척공법을 이용한 광산주변 수은 함유 오염물질 처리 적용성 평가)

  • Kwon, Yo Seb;Park, So Young;Koh, Il Ha;Ji, Won Hyun;Lee, Jin Soo;Ko, Ju In
    • Economic and Environmental Geology
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    • v.53 no.4
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    • pp.337-346
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    • 2020
  • This study was carried out to evaluate the applicability of the soil washing process to remediation mercury-contaminated mine tailing or solid material (soil and sediments etc.) around abandoned mines. First, the physicochemical characteristics of mine tailing were analyzed through particle size analysis and sequential extraction. Secondly, laboratory scale washing experiments were performed using hydrochloric acid, nitric acid, potassium iodide and sodium thiosulfate. As a results of particle size analysis, mine tailing particle were concentrated below 40 mesh and the particle size below 200 mesh was the most analyzed. As a result of sequential extraction, elemental mercury fraction was analyzed as the highest with 69.12%, with strongly bound fraction 15.25% and residual and HgS fractions 11.97%, respectively. Laboratory scale washing experiments showed low applicability for nitric acid and sodium thiosulfate solutions. In case of hydrochloric acid solution, it was analyzed that mercury removal was possible at particle size of 200 mesh or more. Therefore, it is considered to be performed together with the physical sorting process. Potassium iodide solution was analyzed to have high washing efficiency at all concentrations and particle sizes. In particular, the mercury removal efficiency is high in the micro particles, and thus the applicability of the washing technology is the highest.

Oxidation of Elemental Mercury using Dielectric Barrier Discharge Process (유전체 장벽 방전을 이용한 원소수은의 산화특성)

  • Byun, Youngchul;Ko, Kyung Bo;Cho, Moo Hyun;NamKung, Won;Shin, Dong Nam;Koh, Dong Jun;Kim, Kyoung Tae
    • Korean Chemical Engineering Research
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    • v.45 no.2
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    • pp.183-189
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    • 2007
  • We have investigated the oxidation of gas phase elemental mercury using dielectric barrier discharge (DBD). In the DBD process, active species such as $O_3$, OH, O and $HO_2$ are generated by collisions between electrons and gas molecules. Search active species convert elemental mercury into mercury oxide which is deposited into the wall of DBD reactor because of its low vapor pressure. The oxidation efficiency of elemental mercury has been decreased from 60 to 30% by increasing the initial concentration of the elemental mercury from 72 to $655{\mu}g/Nm^3$. The gas retention time at the DBD reactor has showed the little effect on the oxidation efficiency. The more oxygen concentration has induced the more oxidation of elemental mercury, whereas there has been no appreciable oxidation within pure $N_2$ discharge. It has indicated that oxygen atom and ozone, generated in air condition determine the oxidation of elemental mercury.

Decontamination of Mercury Contained in CCFLs (Cold Cathode Fluorescence Light) Disassembled from Waste LCDs (Liquid Crystal Display) (폐 LCD (Liquid Crystal Display) 해체 후 분리된 CCFL (Cold Cathode Fluorescence Light) 내 수은의 건식 제거 공정)

  • Park, Jae Layng;Lee, Sungkyu;Kang, Leeseung;Lee, Chan Gi;Cho, Sung-Su;Hong, Myung Hwan;Hong, Hyun Seon
    • Resources Recycling
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    • v.23 no.2
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    • pp.61-70
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    • 2014
  • LCD televisions and monitors use cold cathode fluorescence lamps (CCFLs) to illuminate the screen. Most CCFLs contain mercury and they have to be carefully handled at the end of their lives as per minimum treatment standards under the Waste Electrical and Electronic Equipment (WEEE) and Restriction of Hazardous Substances (RoHS) directives. CCFLs were carefully separated from mold frames of waste LCD units for primary decontamination of mercury/fluorescent compound mixture using CCFL decontamination system designed and fabricated in the present research. Residual mercury was further removed by employing a pyro-process, where crushed CCFL tubes transferred from primary decontamination process were subject to heat treatment at $550^{\circ}C$ in a box furnace: more than 99% of mercury was removable from waste CCFLs.

A Characteristics of Hg, Pb, As and Se Emitted from Small and Medium Size Waste Incinerator Stacks (중.소형 폐기물 소각시설에서 배출되는 수은, 납, 비소, 셀렌 배출특성)

  • Lee, Han-Kook;Moon, Bu-Shik;Lee, Dong-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.11
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    • pp.1205-1214
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    • 2005
  • This study was carried out to investigate the emission characteristics of volatile metals(Hg, As, Se) and semi volatile metals such as Pb from small and medium size municipal solid waste incinerators(MSWIs). The concentrations of Hg, Pb, As and Se in emission gas from small size waste incinerators were higher than those of medium size waste incinerators. This is probably due to less air pollutant control devices and high emission gas temperature of the small size waste incinerators relative to the medium size waste incinerators. Emission gas temperature from small and medium size waste incinerators were divided into 2 groups. The first group was about $100^{\circ}C$ and the second roup in the range of $400{\sim}700^{\circ}C$. The concentrations of emission gas at the second group were Hg $70.43\;{\mu}g/Sm^3$, Pb $0.94\;{\mu}g/Sm^3$, As $9.83\;{\mu}g/Sm^3$ and Se $5.05\;{\mu}g/Sm^3$. The concentrations of Hg, Pb, As and Se at the first group were lower than those found at the second group. Besides, the removal efficiencies of Hg in medium size waste incinerators were $55.2{\sim}95.9%$. Emission gas temperature reduction from waste heat boiler(WHB) contribute to control of Hg. Based on above results, we postulate that the temperature of flue gas should play a very important role in volatile metal control in small and medium size MSWIs. In order to improve the volatile metals removal efficiency, the temperature of cooling system must be controlled and the air pollution control device should be operated properly.