• Applied Chemistry for Engineering
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• v.7 no.2
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• pp.228-236
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• 1996

An electrolysis system with a vertically circulating mercury capillary bundle electrode was developed with a very large electrode area in a minimum space. This system was operated by forcedly feeding mercury and aqueous solution containing metal ion into a fiber bundle packed densely within a small porous glass tube. In order to test the characteristics and stability of the electrolysis system, the reduction voltammograms of uranyl and ferric ions were measured with changes of the mercury flow rate and the aqueous flow rate. The aqueous flow rate had a large effect on the electrochemical reaction of metal ion occurring at the interface between the mercury and the aqueous solution and had to be regulated as an appropriate value to have a good limiting current shape. The limiting current was linearly proportional to the aqueous flow rate, and complete reductions of uranyl and ferric ions were rapidly and continuously accomplished at the potential showing limiting current. With a mercury flow rate high enough to keep a capillary continuum of mercury in the fiber bundle, the mercury flow rate had almost no effect on the electrochemical reaction. This system was confirmed to be effective and stable enough to control rapidly and continuously the oxidation state of metal ions fed into the system under an appropriate aqueous flow rate.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2006.11a
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• pp.469-472
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• 2006

BI 및 ETABr의 농도변화에 따른 속도상수의 변화는 이 반응이 단순한 1차 및 2차 반응 속도식에 맞지 않는다. 이와 같은 현상은 용액 속에서 두 반응 시약인 p-NPDPIN 및 BI와 상전이촉매인 ETABr 사이에 많은 수의 작은 응집된 입자(aggregates)을 형성함을 의미한다. 수용액 속에서는 불용성인 p-NPDPIN과 수용성인 BI가 충돌하여 반응할 기회가 적은데 반하여 ETABr은 이 두 시약을 함께 수용하여 세 분자 사이에 응집현상이 일어남으로 p-NPDPIN과 BI가 반응하기에 충분한 거리 내에 있게 된다. 바꾸어 말하면, 이 두 반응물질이 1:1 adducts로 반응하기보다는 여러 ETABr과 함께 많은 수의 반응분자들이 회합(응집) 되어 있음을 뜻한다.

• Clean Technology
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• v.4 no.2
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• pp.23-31
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• 1998

Photo-sensitized oxidation of benzene in aqueous solution was conducted with persulfate, nitrate, nitrite, sulfate and chloride as sensitizers.In the photo-sensitized oxidation of benzene persulfate, nitrate and nitrite could act as sensitizers, while no detectable effects could be observed with sulfate and chloride. With increasing nitrite concentration the photo-sensitized oxidation of benzene ran through a maximum value and decreased thereafter with increasing nitrite concentration. A build-up of nitrite ions seemed to scavenge hydroxyl radicals. When nitrite was present with other ions, nitrite inhibited the photo-sensitized oxidation of benzene. Phenol and biphenyl were identified as intermediate.

• Journal of the Korean Electrochemical Society
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• v.11 no.3
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• pp.159-164
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• 2008

We investigated chloride ion effects on anodic dissolution of copper using potentiodynamic method, cyclic voltammtery, chronoamperometry and chronocoulometry. The anodic dissolution reaction of copper in NaCl solution under argon atmosphere is $Cu+2Cl^{-}{\rightleftharpoons}{CuCl_2}^{-}+e^-$ and chloride ion adsorption process in copper surface can be explained by Temkin isotherm.

• Analytical Science and Technology
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• v.13 no.5
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• pp.549-557
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• 2000

FRIR-ATR spectrometry has been used to monitor the aqueous reactions of compounds without distinct chromophores in ultraviolet and visible regions. For example, hydrolysis reactions of ${\alpha}$-cyclodextrin and ${\gamma}$-cyclodextrin in acidic aqueous solution were studied. FTIR-ATR method has been used for the monitoring of cyclodextrin hydrolysis in 1.0 M. 0.5 M, and 0.1 M HCl solutions, respectively. We also found that the hydrolysis of ${\alpha}$-cyclodextrin produced glucose, but the hydrolysis of ${\gamma}$-cyclodextrin proceeded further to give more fragmented products than glucose.

• Proceedings of the KAIS Fall Conference
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• 2009.05a
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• pp.874-877
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• 2009

본 연구에서는 수용액 내의 오염물질 분해를 위하여 개발한 광촉매가 코팅된 실리카 비드의 광분 해반응 사용에 따른 활성저하 문제를 해결하기 위하여 반응에 사용한 비드의 활성을 향상시킬 수 있는 재생 방법에 관한 실험을 수행하였다. 비드의 재생방법으로 표면 세정법을 선택하였으며, 세정액으로는 물(증류수), 계면활성제, 아세톤 등 세정력이 서로 다른 3종의 용액을 사용하였다. 재생 과정은 서로 다른 3종의 세정액으로 반응에 사용하여 활성이 떨어진 비드를 세정한 후, 소성온도를 $100^{\circ}C$, $200^{\circ}C$, $300^{\circ}C$로 달리하여 30분간 처리하였다. 재생 처리과정은 각 1~3회 반복 수행하였으며, 서로 다른 조건에서 재생된 비드의 활성은 수용액 내의 methylene blue 광분해율로 측정하였다. 연구결과, 재생한 비드의 활성은 아세톤으로 세정한 후, $100^{\circ}C$에서 30분간 소성하였을 때 가장 우수한 것으로 나타났으며, 이러한 기초 연구결과를 토대로 현재보다 효율적인 재생 기술에 관한 연구를 수행 중에 있다.

• Resources Recycling
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• v.10 no.6
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• pp.3-8
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• 2001

This study was examed about leaching behavior in order to separate plasticizer selectively before dechlorination from flexible PVC material in alkali solutions at $80~120^{\circ}C$. The dechlorination of that was not almost occurred below $100^{\circ}C$. But the yield of elution of plasticizer was 100% above 5M NaOH. Therefore, by controlling alkali concentration and reaction temperature, it is possible to extract the plasticizer selectively without taking dechlorination.

• Magazine of the Korea Concrete Institute
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• v.9 no.1
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• pp.115-121
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• 1997

This study deals with the suppressing characteristics of alkali-silica reaction by ground granulated blast-furnace slag(GGBS) in NaCl solution. NaCl contents used in the experiment ranges over 0%, 2.8% and 20%. Reactive aggregate used is Japanese andesite. Also, three GGBSs of about 4.000. 6, 000 and $8, 000cm^2/g$ were used in the experiment. The replacement proportions of portland cement by GGBSs were 40%. 60%, 70% and 80%. respectively. The specimens with GGBS were severely contracted according to the increasing replacement ratio in NaCl solution. The contraction rate increases according to the increasing in NaCl content. Also. it does with increasing the blaine fineness of GGRS. It is concluded that the suppression of alkali-silica reaction by GGBS in NaCl solution is complished by contraction of GGBS due to chloride ion induced chemical shrinkage.

• Korean Chemical Engineering Research
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• v.45 no.2
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• pp.172-177
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• 2007

The hydrolysis reaction of sarin(GB), one of the nerve agents was studied in aqueous sodium hydroxide(NaOH) solutions to find the experimental conditions which can convert GB into the less toxic compounds. 10 wt% of GB was added into the aqueous NaOH(2.05 eq) in a small-scale jacket-attached reactor connected to a circulator. The reaction rate constants were measured at three temperatures(50, 70 and $90^{\circ}C$) and the reaction times required to degrade the material to > 99% were calculated at different temperatures. In this study, 10 wt% of GB was degraded to 99.99% in 1.2hr at $90^{\circ}C$ by the aqueous NaOH solution. The major hydrolysate of GB was isopropyl methylphosphonate.

• Applied Chemistry for Engineering
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• v.3 no.1
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• pp.100-110
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• 1992

Arylsulfonyl urea derivatives can be easily prepared in good yield by treating amines with arylsulfonyl carbamates in aqueous solution : 1) N-Arylsulfonyl-N'-aryl urea derivatives, 2) N-Arylsulfony-N'-alkyl urea derivatives, 3) N-Arylsulfonyl-N'- heterocyclic urea derivatives. The proposed reaction mechanisms for preparing arylsulfonyl ureas involve formation of an ion-pair conformation by initial acid-base reaction, then formation of a so-called tetrahedral intermediate by nucleophilic addition, followed by an acid-catalyzed elimination of an alkoxide ion and loss of a proton.