• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.3
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• pp.359-364
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• 2004

For the development of high efficiency and low emission combustion systems, high temperature air combustion technology has been tested by utilizing preheated air over 1100 K and exhaust gas recirculation. In this system, combustion air is diluted with large amount of recirculated exhaust gases, such that the oxygen concentration is relatively low in the reaction zone, leading to low flame temperature. Since, the temperature fluctuations and sound emissions from the flame are small and flame luminosity is low, the combustion mode is expected to be flameless or mild combustion. Experiment was performed to investigate the turbulent flame structure and NO$_x$ emission characteristics in the high temperature air combustion focused on coflowing jet diffusion flames which has a fundamental structure of many practical combustion systems. The effect of turbulence has also been evaluated by installing perforated plate in the oxidizer inlet nozzle. LPG was used as a fuel. Results showed that even though NO$_x$ emission is sensitive to the combustion air temperature, the present high temperature air combustion system produce low NO$_x$ emission because it is operated in low oxygen concentration condition by the high exhaust gas recirculation.

• Journal of the Korean Society of Combustion
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• v.14 no.1
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• pp.31-38
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• 2009

The effects of acoustic excitation of coaxial air on mixing enhancement and reduction of nitrogen oxides (NOx) emission were investigated. A compression driver was attached to the coaxial air supply tube to impose excitation. Measurements of NOx emission with frequency sweeping were performed to observe the trend of NOx emission according to the fuel and air flow conditions and to inquire about the effective excitation frequency for reducing NOx. Then, Schlieren photographs were taken to visualize the flow field and to study the effect of excitation. In addition, phase-locked particle image velocimetry (PIV) was performed to acquire velocity field for each case and to investigate the effect of vortices more clearly. Direct photographs and OH chemiluminescence photographs were taken to study the variation of flame length and reaction zone. It was found that acoustic forcing frequencies close to the resonance frequencies of coaxial air supply tube could reduce NOx emission. This NOx reduction was influenced by mixing enhancement due to large-scale vortices formed by fluctuation of coaxial air jet velocity.

• Particle and aerosol research
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• v.4 no.2
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• pp.51-67
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• 2008

In this study, we devoted to kinetic measurement of the catalytic oxidation of iron-containing flame soot particles and better understanding the role of catalytic particles on carbon oxidation in particular at low temperature, targeting on autothermal regeneration of diesel particulate filter by diesel exhaust gas. Carbon-based Fe-containing particles generated by spraying ferrocene-doped diesel fuel in an oxy-hydrogen flame are tested and compared with a commercial carbon black powder for thermogravimetric analysis (TGA), secondary ion mass spectrometry (SIMS), Fourier-transform infrared spectroscopy (FTIR), Induced coupled plasma-Atomic emission spectroscopy (ICP-AES), and High-resolution transmission electron microscopy (HR-TEM). As a result, we found that a small amount of the ferrocene addition led to significant reductions in a on-set temperature and an activation energy of the carbon oxidation as well. An oxygenated surface complex forming at the particle surface could be thought as active species that would be readily consumed in particular at low temperature.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.4
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• pp.384-391
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• 2007

Hydrogen-blending effects in flame structure and NO emission behavior are numerically studied with detailed chemistry in methane-air counterflow diffusion flames. The composition of fuel is systematically changed from pure methane to the blending fuel of methane-hydrogen through $H_2$ molar addition up to 30%. Flame structure, which can be described representatively as a fuel consumption layer and a $H_2$-CO consumption layer, is shown to be changed considerably in hydrogen-blending methane flames, compared to pure methane flames. The differences are displayed through maximum flame temperature, the overlap of fuel and oxygen, and the behaviors of the production rates of major species. Hydrogen-blending into hydrocarbon fuel can be a promising technology to reduce both the CO and $CO_2$ emissions supposing that NOx emission should be reduced through some technologies in industrial burners. These drastic changes of flame structure affect NO emission behavior considerably. The changes of thermal NO and prompt NO are also provided according to hydrogen-blending. Importantly contributing reaction steps to prompt NO are addressed in pure methane and hydrogen-blending methane flames.