• Transactions of the Korean hydrogen and new energy society
• /
• v.23 no.1
• /
• pp.83-92
• /
• 2012

Syngas combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using simulated syngas and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction conditions and no NO emission at oxidation conditions. Moreover, OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration with temperature. However, fuel conversion and $CO_2$ selectivity increased and CO emission decreased as pressure and gas residence time increased.

• Transactions of the Korean hydrogen and new energy society
• /
• v.31 no.5
• /
• pp.411-418
• /
• 2020

A reformer is a device for producing hydrogen used in fuel cells. Among them, methanol steam reformer uses methanol as fuel, which is present as a liquid at room temperature. It has the advantage of low operating temperature, high energy density, and high hydrogen production. The purpose of this study is to improve the internal flow of the pressure vessel when a bundle of methanol steam reformer in the pressure vessel goes out to a single outlet. An analysis of equilibrium reaction to methanol steam reforming reaction was conducted using Aspen HYSYS^® (Aspen Technology Inc., Bedford, USA), and based on the results, computational analysis was conducted using ANSYS Fluent^® (ANSYS, Inc., Canonsburg, USA). For comparison of the results, the height of the pressure vessel, outlet diameter, and fillet was set as variables, and the optimum geometry was selected by comparing the effects of gravity and the amount of negative pressure.

• Transactions of the Korean hydrogen and new energy society
• /
• v.31 no.5
• /
• pp.480-488
• /
• 2020

This study was conducted to improve the flow uniformity inside the chip tester through changing the flow path formation according to the inlet and outlet position of chamber. The internal flow and velocity distributions of the modified chamber models (Cases 1-3) were compared with the reference chamber model through three-dimensional Reynolds-averaged Navier-Stokes equations with k-ε turbulence model. The modified chamber models showed the superior flow uniformity characteristics compared to the reference chamber model. To investigate the flow uniformity in the chip tester, the standard deviation of the velocity was defined and compared. Through the internal flow analysis and assesment of the standard deviation, Case 2 among the test cases including the reference model showed the best flow uniformity generally.

• 유체기계공업학회:학술대회논문집
• /
• 2006.08a
• /
• pp.227-230
• /
• 2006

The method of mass flow rate measurement using a critical nozzle is well established in the flow satisfying ideal gas law. However, in the case of measuring high-pressure gas flow, the current method shows invalid discharge coefficient because the flow does not follow ideal gas law. Therefore an appropriate equation of state considering real gas effects should be applied into the method. The present computational study has been performed to give an understanding of the physics of a critical nozzle flow for high-pressure hydrogen gas and find a way for the exact mass flow prediction. The two-dimensional, axisymmetric, compressible Navier-Stokes equations are computed using a fully implicit finite volume method. The real gas effects are considered in the calculation of discharge coefficient as well as in the computation. The computational results are compared with the previous experimental data and predict well the measured mass flow rates. It has been found that the discharge coefficient for high-pressure hydrogen gas can be corrected properly adopting the real gas effects.

• 한국신재생에너지학회:학술대회논문집
• /
• 2007.11a
• /
• pp.97-100
• /
• 2007

A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce $CO_2$ - free hydrogen . The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The methane decomposition rate with the carbon black N330 catalyst was quickly reached a quasi-steady state rate and remained for several hour. The methane and propane mixture decomposition reaction was carried out at the temperature range of 850 - 900 $^{\circ}C$, methane and propane mixture gas velocity of 1.0 $U_{mf}$ ${\sim}$ 3.0 $U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The produced carbon by the methane decomposition was deposited on the surfaces of carbon catalysts and the morphology was observed by TEM image.

• Transactions of the Korean hydrogen and new energy society
• /
• v.23 no.2
• /
• pp.173-182
• /
• 2012

Effects of temperature, pressure, and gas residence time on methane combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using methane and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction condition and very low NO emission at oxidation condition. Moreover OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration. However, $CO_2$ selectivity increased as pressure increased and fuel conversion increased as gas residence time increased.

• Journal of Power System Engineering
• /
• v.13 no.3
• /
• pp.27-32
• /
• 2009

Numerical analysis information of a complex discharge-passage will be very useful to improve hydrogen compression system. General information about an internal gas flow is presented by numerical analysis approach. Relating with hydrogen compressing system, which have an important role in hydrogen energy utilization, this should be a useful tool to observe the flow quickly and clearly. Flow characteristic analysis, including pressure and turbulence kinetic energy distribution of hydrogen gas from cylinder going to the chamber of a reciprocating compressor are presented in this paper. Discharge-passage model is designed based on real model of hydrogen compressor. Pressure boundary conditions are applied considering the real condition of operating system. The result shows pressure and turbulence kinetic energy are not distributed uniformly along the passage of the hydrogen compressing system. Path line or particles tracks help to demonstrate flow characteristics inside the passage. The existence of vortices and flow direction can be precisely predicted. Based on this result, the design improvement should be done. Consequently, development of the better hydrogen compressing system will be achieved.

• Transactions of the Korean hydrogen and new energy society
• /
• v.22 no.6
• /
• pp.878-883
• /
• 2011

Effect of flow uniformity on the reaction characteristics of a catalytic combustor for high temperature fuel cell system has been experimentally investigated in the present study. One of the most important factor in designing catalytic combustion is to avoid hot spot in catalysts. In this regard, it is very important to secure flow uniformity of combustor inlet. A couple of perforated plates were applied at the front of catalyst region as flow uniformity device with minimal pressure drop. Results show that the velocity and temperature profile became more uniform when applying the flow uniformity device. CO and $CH_4$ emissions at the combustor exit were decreased and the average exit temperature was slightly increased with the flow uniformity device.

• Transactions of the Korean hydrogen and new energy society
• /
• v.23 no.4
• /
• pp.293-299
• /
• 2012

The serpentine flow channel is widely used in polymer electrolyte membrane fuel cells (PEMFCs) to prevent flooding phenomena because it effectively removes liquid water in the flow channel. The pressure drop between inlet and outlet increases as compared with straight channels due to minor losses associated with the corners of the turning configurations. This results in a strong pressure gradient between adjacent channels in specific regions, where some amount of reactant gas can be delivered to catalyst layers by convection through a gas diffusion layer (GDL). The enhancement of the convective flow in the GDL, so-called bypass flow, affects fuel cell performance since the bypass flow influences the reactant transport and thus its concentration over the active area. In the present paper, for the bipolar plate design, a simple analytic model has been proposed to predict the bypass flow in the serpentine type flow channels and validated with three-dimensional numerical simulation results.

• Transactions of the Korean hydrogen and new energy society
• /
• v.27 no.3
• /
• pp.311-317
• /
• 2016

This paper presents the flow characteristics of a ball valve used for a gas pipeline. Understanding of the internal flow of a ball valve is an important to analyze the physical phenomena of the valve. Present experimental study was performed by IEC 60534-2-3, the international standard for an industrial control valve testing procedure. Pressure measured at upstream and downstream of the valve, flow-rate and gas temperature passing the inside of the gas pipeline were measured with respect to valve opening rates. Throughout the experimental measurement of the ball valve, empirical equation of the pressure drop between the ball valve according to the mass flow rates is successively obtained using a polynomial curve fitting method. In addition, flow coefficient for determining the valve capacity is also analyzed with respect to valve opening rates using the curve fitting method.