• Proceedings of the Safety Management and Science Conference
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• 2005.05a
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• pp.399-415
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• 2005

1991년 6월 신규 계면활성제 [${\alpha}-SF$]의 제조 공정의 하나인 메탄올 정류탑에 있어서 폭발사고가 발생했다. 폭발 형태는 ${\ulcorner}$폭굉${\lrcorner}$ 이였다 라고 판단되어지고 정류탑은 대파되었으며 탑벽 파편은 대강 900m 범위로 비산되었고 사망자 2명, 부상자 13명의 피해를 입었다. 원인물질은 계면활성제의 표백으로 사용하는 메탄올과 과산화수소에 의해 미량 생성한 유기과산화물(Metal Hydroperoxide)에서 정류탑의 운전정지과정 중에 공급액의 $0.1\%$부터 수십$\%$까지 국부적으로 농축되어져 열 폭발을 일으킨 것으로 추정 되어진다.

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2002.05a
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• pp.433-438
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• 2002

화재 및 폭발 특성치로 인화점, 최소발화온도, 폭발한계, 최소발화에너지, 연소열 등을 들 수 있다 이 가운데 폭발한계(explosive limits)는 가연성물질(가스 및 증기)을 다루는 공정 설계 시 고려해야 할 중요한 변수로써, 발화원이 존재할 때 가연성가스와 공기가 혼합하여 일정 농도범위 내에서만 연소가 이루어지는 혼합범위를 말한다/sup 1)/. 특히 폭발범위는 온도, 압력, 불활성가스의 농도, 화임전과 방향, 용기의 크기, 무리리적 상태 등에 의해 변한다/sup 2)/.(중략)

• Journal of Hydrogen and New Energy
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• v.19 no.3
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• pp.239-247
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• 2008

Hydrogen production facility using very high temperature gas cooled reactor lies in situation of high temperature and corrosion which makes hydrogen release easily. In that case of hydrogen release, there lies a danger of explosion. However, from the point of thermal-hydraulics view, the long distance of them makes lower efficiency result. In this study, therefore, outlines of hydrogen production using nuclear energy are researched. Several methods for analyzing the effects of hydrogen explosion upon high temperature gas cooled reactor are reviewed. Reliability physics model which is appropriate for assessment is used. Using this model, leakage probability, rupture probability and structure failure probability of very high temperature gas cooled reactor are evaluated and classified by detonation volume and distance. Also based on standard safety criteria which is value of $1{\times}10^{-6}$, safety distance between the very high temperature gas cooled reactor and the hydrogen production facility is calculated.

• Journal of the Korean Institute of Gas
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• v.1 no.1
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• pp.49-55
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• 1997

Destruction phenomena of structure by gas explosion is due to the explosion pressure and heat. Explosion pressure is a kind of energy converted from the gas mixture explosion. In this paper, we tried to find the relationship between explosion characteristics and combustion heat of the hydrocarbon-oxygen mixtures. Experiment were carried out with the volume of $5916cm^3$ cylindrical explosion vessel. Hydrocarbon gases which used in this study were methane, ethylene, propane, and buthane Experimental parameter was the concentration of the gas mixtures. Explosion characteristics were measured with strain type pressure transducer through the digital storage oscilloscope. From the experimental result, it was found that explosion pressure depend upon the combustion heat.

• Journal of the Korean Society of Safety
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• v.19 no.4 s.68
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• pp.150-154
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• 2004

Gas explosion characteristics of hydrogen and liquefied petroleum gas(LPG) were measured in 6L cylindrical vessel, and experiment for explosion to fire transition phenomena of the gases were carried out using the 270L vessel. Explosion characteristics were measured using the stain type pressure transducer and explosion to fire transition phenomena was analyzed with the hish-speed camera. Base on the experiment, it was found that explosion pressure was most high slightly above the stoichiometric concentration, and explosion pressure rise rate and flame propagation velocity were proportional to the combustion velocity. And we find that those kind of explosion characteristics affect the explosion-to-fire transition, in addition, explosion flame temperature, flame residence time, are important parameters in explosion-to-fire transition.

• Journal of Hydrogen and New Energy
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• v.30 no.1
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• pp.29-34
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• 2019

Safety of hydrogen handling facilities is needed as supply of hydrogen cars has been expanded recently. In this study, the adequacy of safety regulations of hydrogen handling facilities and the risk of damage with hydrogen leakage were studied. The range of explosion hazard location of the hydrogen filling plant was investigated using the computational fluid dynamics (CFD) method, Explosive hazardous area is influenced by leakage type, hole size and sectional area. When the conditions of KS standard are applied, range explosive hazardous area is expanded 7.05 m, maximum. It is about 7 times larger than exceptional standard of hydrogen station. Meanwhile, distance from leakage point to 25% LEL of hydrogen is investigated 1.6 m. Considering the shape of charging hose, regulation of hydrogen station is appropriate.

• Journal of the Korean Institute of Gas
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• v.27 no.4
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• pp.102-109
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• 2023

In realizing a hydrogen society, it is important to secure the safety of the hydrogen refueling station, which is the facility where consumers can easily meet hydrogen. The hydrogen refueling station consists of compressed gas facilities that store high-pressure hydrogen, and there is a risk that the high-pressure compressed gas facility will rupture due to a fire explosion due to hydrogen leakage in the facility or the influence of surrounding fires. Accordingly, the Korea Gas Safety Corporation is making every effort to find out risk factors from the installation stage, reflect them in the design, and secure safety through legal inspection. In this study, a TNT explosion demonstration test using a protection wall was conducted to confirm the safety effect of the protection wall installed at the hydrogen refueling station, and the empirical test results were compared and verified using FLACS-CFD, a CFD program. As a result of the empirical test and CFD analysis, it was confirmed that the effect of reducing the explosion over-pressure at the rear end of the protection wall decreased from 50% to up to 90% depending on the location, but the effect decreased when it exceeded a certain distance. The results of the empirical test and computer analysis for verifying the safety of the protection wall will be used in proposals for optimizing the protection wall standards in the future.

• Journal of Internet Computing and Services
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• v.24 no.6
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• pp.171-180
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• 2023

Hydrogen energy technology is gaining importance in the era of the Fourth Industrial Revolution, offering military advantages when applied to military vehicles due to its characteristics such as reduced greenhouse gas emissions, noise, and low vibration. Korea's military has initiated the Army Tiger 4.0 plan, focusing on hydrogen application, downsizing, and AI-based smart features. The Ministry of National Defense plans to collaborate with the Ministry of Environment to expand hydrogen charging stations nationwide, anticipating increased deployment of military hydrogen vehicles. However, considering the Jet Fire and VCE(Vapor Cloud Explosion) nature of hydrogen, ensuring safety during installation is crucial. Current military guidelines specify a minimum safety distance of 2m from adjacent buildings for charging stations. Scientific methods have been employed to quantitatively assess the accident damage range of hydrogen, proposing a minimum safety distance beyond the affected area.

• Journal of Auto-vehicle Safety Association
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• v.13 no.4
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• pp.73-80
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• 2021

Recently, Korea has established a plan for the supply of hydrogen vehicles and is promoting the expansion of the supply. Risk factors for hydrogen vehicles are hydrogen leakage, jet fire, and explosion. Therefore Safety measures are necessary for this hazard. In addition, risks in semi-closed spaces such as tunnels, underground roads, and underground parking lots should be analyzed. In this study, an explosion experiment was conducted on a hydrogen tank used in a hydrogen vehicle to analyze the risk of a hydrogen vehicle explosion accident that may occur in a semi-closed space. As results, the effect on the structure and the human body was analyzed using the overpressure and impulse values for each distance generated during the explosion.

• Journal of the Korean Institute of Gas
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• v.9 no.3 s.28
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• pp.9-14
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• 2005

To estimate the explosion characteristics of converted gas, the study was examined into effects of altering oxygen concentration and adding hydrogen. From the result of the experiment, as the concentration of converted gas and hydrogen were increased at $21\%$ oxygen concentration, the lower explosion limit was low. Minimum explosion oxygen concentration was $6\%$. Maximum explosion pressure of converted gas was $4.61 kg_f/cm^2$, now Maximum explosion pressure rising velocity was $130.75 kg_f/cm^2/s$ at converted gas concentration $40\%$. Also, minimum ignition energy was 0.13 mJ at converted gas concentration $50\%$.