• Transactions of the Korean hydrogen and new energy society
• /
• v.33 no.6
• /
• pp.819-826
• /
• 2022

Fuel cell systems are being supplied to households and buildings to reduce greenhouse gases. The fuel cell systems have problems of high cost and slow startup due to fuel processors. Greenhouse gas reduction of the fuel cell systems is also limited by using natural gas. The problems can be solved by using a hydrogen generator consisting of a reformer and pressure swing adsorption (PSA). However, part load operation of the hydrogen generator is required depending on the hydrogen consumption. In this paper, PSA operation strategies are investigated for part load of the hydrogen generator. Adsorption and purge time were changed in the range of part load ratio between from 0.5 to 1.0. As adsorption time increased, hydrogen recovery increased from 29.09% to 48.34% at 0.5 of part load ratio. Hydrogen recovery and hydrogen purity were also improved by increasing adsorption and purge time. However, hydrogen recovery dramatically decreased to 35.01% at 0.5 of part load ratio.

• Transactions of the Korean hydrogen and new energy society
• /
• v.34 no.6
• /
• pp.728-733
• /
• 2023

Efforts are continuing to change from fossil fuels used to hydrogen energy society. In order to become a hydrogen society, stable production and real-life applicability are important. As a result, hydrogen generation system linked to fuel cell are being developed. Through this, it is expected that production to power generation will be possible where desired by utilizing the existing urban gas piping network. Hydrogen generation system and hydrogen fuel cell have been subjected to risk assessment and have already been commercialized, but no risk assessment has been conducted on the integrated system linking them. Therefore, it is intended to secure its safety by conducting a risk analysis on the integrated system.

• Journal of Power System Engineering
• /
• v.12 no.1
• /
• pp.20-27
• /
• 2008

수소 추출과 리포밍 과정, 연료 전지, 저장소로 구성된 수소 연료에 대한 연구는 세계적으로 번영하고 있는 중이다. 그러나 한국의 수소 스테이션에 대한 연구는 아직도 개발이 미미한 수준이다. 그리고 역시 수소 스테이션의 가장 중요한 부분인 수소 압축기에 대한 연구도 미흡하다. 수소압축기에서 가장 중요한 부분 중에 하나는 스너버인데 이것의 기능은 수소가스의 맥동압을 줄이고 불순물을 제거한다. 스너버 내부에는 버퍼라고 불리는 기울어진 판이 설치되어 맥동압을 줄이고 불순물을 제거하는 역할을 담당한다. 스너버 내부의 압력 손실과 맥동압이 최소가 될 때 스너버는 적절한 성능을 가졌다고 평가된다. 그러므로 이 연구의 목적은 수치해석을 통하여 스너버의 최적의 기하학적 크기와 버퍼의 각도에 따른 최적의 스너버를 찾는 것이다. 수치해석의 결과에서 다양한 버퍼각도에 따른 스너버의 독특한 특성을 볼 수 있다. 결과적으로 버퍼의 각도가 $35^{\circ}$일때 최소의 압력손실율이 발생했고, 버퍼의 각도가 $10^{\circ}$일 때 최소의 맥동압이 발생하였다.

• Proceedings of the KSMRM Conference
• /
• 2001.11a
• /
• pp.173-173
• /
• 2001

목적： 1.5T 생체용 자기공명영상기기를 이용한 수소자기공명분광법으로 용액 내 물질의 정량분석에 대한 가능성을 알아보고자 하였다. 대상 및 방법： 0.01％에서 50％까지의 여러 농도를 갖는 포도당+증류수 혼합액의 모델용액을 만들어 생체용 자기공명영상기기와 시험관 nuclear magnetic resonance (NMR) 분광기에서 각각 수소 자기공명분광법을 시행하여 스펙트럼을 얻었다. 또한 12명의 당뇨환자에서 방광내의 소변에 대해 생체용 자기공명영상기기에서 스펙트럼을 얻고 소변을 추출하여 시험관 NMR 분광기에서 수소자기공명분광법을 시행하였다 각각의 방법으로 얻은 스펙트럼 상에서 포도당 농도에 따른 포도당/물 피크의 면적 비의 변화를 구하였고, 통계처리는 상관분석과 단순선형회귀분석을 시행하였고 회귀식을 산출하였다. 또한 생체용 자기공명영상기기를 이용하여 얻은 결과가 객관적인지 알아보기 위해 시험관 NMR 분광기에서 얻은 결과와의 상관관계를 분석하였다.

• Proceedings of the Korean Vacuum Society Conference
• /
• 1995.06a
• /
• pp.112-113
• /
• 1995

• Analytical Science and Technology
• /
• v.16 no.4
• /
• pp.261-268
• /
• 2003

To investigate the matrix effect of sample for hydrogen analysis by inert gas fusion-thermal conductivity detection, calibration factor for the hydrogen analyser of the inert gas fusion-thermal conductivity detection method was measured with hydrogen standard materials in Ti, Zr-2.5Nb and by hydrogen gas dosing method. Also the hydrogen extraction efficiency for the different sample matrix, Ti and Zr-2.5Nb, was evaluated without adding tin flux. The calibration factor of the hydrogen analyser which was calibrated by hydrogen standard material in Zr-2.5Nb and Ti was 2~3% and 14% higher than that by hydrogen gas dosing method, respectively. Based on the results of calibration factor measurement, it could be concluded that the hydrogen extraction efficiency of the Ti matrix sample will be 12% lower than that of the Zr-2.5Nb. And according to the experimental results of hydrogen recovery test by no tin flux, the hydrogen recovery percentage of the Ti and Zr-2.5Nb matrix sample was about 70% but the recovery rate of Ti matrix sample was slightly lower than that of Zr-2.5Nb.

• Applied Chemistry for Engineering
• /
• v.34 no.4
• /
• pp.404-411
• /
• 2023

For the direct reforming of biogas, a three-phase gliding arc plasma reformer was designed to expand the plasma discharge region, and the operation conditions of the plasma reformer, such as the S/C ratio, the gas flow rate, and the plasma input power, were optimized. The H₂ production efficiency is increased at a lower specific plasma input energy density, but byproducts such as C_XH_Y and carbon soot are generated along with the increase in H₂ production efficiency. The formation of byproducts is decreased at higher specific plasma input energy densities and S/C ratios. The optimized operation conditions are 5.5 ~ 6.0 kJ/L for the specific plasma input energy density and 3 for the S/C ratio, considering the conversion efficiency, H₂ production, and byproduct formation. It is expected that the H₂ production efficiency will improve with the decrease in fuel consumption in biogas burners because the heat generated from plasma discharge heats up the feed gas to over 500 ℃.

• The Korean Journal of Petroleum Geology
• /
• v.6 no.1_2 s.7
• /
• pp.37-43
• /
• 1998

Chemical components of water, chemical and isotopic compositions of extractable gases were analyzed to characterize the properties of the natural gases which are dissolved in ground water in the Pohang area. Amount of total extracted gases ranges from 27 ml/l to 50.1 ml/l. Hydrocarbon gases are composed of methane ($27{\~}376,420 ppm$) and ethane ($19{\~}127 ppm$). Amount of total hydrocarbon gases is related to the lithology and geological factors around the reservoir. Quantity of hydrocarbon gases tends to increase in the Tertiary reservoirs and in the reservoirs where the Tertiary formations are thick enough. According to the relationship between hydrocarbon gases and total solids in the ground water, it is believed that the hydrocarbon gases were dissolved in the Tertiary formation water. Based on the methane content ($>99.9\%$) and isotopic composition (${\delta}C^{13};-73.1\%_{\circ}{\~}-43.22\%_{\circ}$), we interpret the gases to be of predominantly biogenic origin which were generated by the methanogenic bacterial processes under the low temperature and anoxic conditions.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.11 no.1
• /
• pp.99-105
• /
• 1997

In the paper, aging of insulating oil in pole transformer has been studied by performing accelerated thermal aging test. Dissolved gases were extracted by air bubbling method. Concentration of dissolved gases were modified by extraction ratio of each gases in insulating oil. Aging of insulating materials were proceeded by thermal degradation and oxidation reaction. Both of the reactions followed zeroch order kinetics. Formation rate equations for hydrocarbons, carbon oxides, and hydrogen were derived. It was conformed by gas analysis and UV-Visible spectrophotometric method that iron core and copper coil in pole transformer act as catalyst during the aging process.

• KSBB Journal
• /
• v.25 no.5
• /
• pp.421-428
• /
• 2010

This paper reports on the experimental investigation carried out to evaluate the physical optimal conditions in the absorption column to remove odorous hydrogen sulfide gas. Hydrogen sulfide gas, as a highly undesirable contaminant, is most widely emitted from environmental treatment facilities. The absorbent mixed with natural second metabolites extracted from conifer trees and chemical absorbent of 2-aminoethanol was applied to remove it via chemical neutralization. The absorbent of natural second metabolites was achieved by a removal efficiency of 20-40% by itself depending on the treatment conditions, but the complex absorbent mixed with 0.1% amine chemical provides the removal efficiency of 98%. The optimal removal efficiencies have been examined against the two major parameters of temperature and pH. This study shows that the aqueous solution by natural second metabolites can be used as an appropriate absorbent in the column absorbed for the removal of hydrogen sulfide gas.