• Journal of the Korean Chemical Society
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• v.34 no.6
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• pp.561-568
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• 1990

Voltammetric behavior of some light lanthanide ions (La$^{3+}$, Pr$^{3+}$, Nd$^{3+}$, Sm$^{3+}$, and Eu$^{3+}$) in various supporting electrolytes has been investigated by several electrochemical techniques. The peak potentials and the peak currents, their dependency on the concentration, temperature and pH effects, the reversibility of the electrode reactions are described. The reduction of La$^{3+}$, Pr$^{3+}$ and Nd$^{3+}$ in 0.1 M lithium chloride proceeds by a three-electron change directly to the metallic state (Ln$^{3+}$ ＋ 3e- → Ln$^0$) and charge transfer is totally irreversible. However, the reduction of Sm$^{3+}$ in 0.1 M tetramethylammonium iodide and Eu$^{3+}$ in 0.1 M lithium chloride proceeds in two stages (Ln$^{3+}$ ＋ e- → Ln$^{2+}$ and Ln$^{2+}$ ＋ 2e- → Ln$^0$). At pH values lower than ca.4 the hydrated lanthanide species (Ln(OH)$^{2+}$) reduced before the lanthanide ions (Ln$^{3+}$) due to the catalytic effect of hydrogen ions, and peak current increase with in the order Eu$^{3+}$ < Sm$^{3+}$ < Nd$^{3+}$ < Pr$^{3+}$ < La$^{3+}$ in differential pulse polarography. Some representative plots of $i_{pc}V^{-1/2} (proportional to current function) vs. V show considerable influence of hydrogen ion/lanthanide ion concentration in cyclic voltammetry. It is shown that a reaction of lanthanide ions with proton and/or water and catalytic reaction is enhanced at lower pH and at decreased lanthanide ion concentration.

• Journal of Soil and Groundwater Environment
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• v.10 no.4
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• pp.18-25
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• 2005

Characteristics of phenanthrene removal in an electrokinetic (EK)-Fenton process were investigated in a viewpoint of concentration and ionic strength of electrolytes. When three kinds of electrolytes (NaCl, $KH_2PO_4,\;and\;MgSO_4$) were used, the increase in electrolyte concentration caused the decrease of electrical potential gradient. The increase of electrical conductivity was due to the increase of ionic concentration in soil. The decrease of accumulated electroosmotic flow (EOF) with increase in electrolyte concentration was due to the decrease of zeta potential. The removal efficiency was in proportion to accumulated EOF which depended on ionic strength. Total energy expenditure without electrolyte was 10-30 times higher than its with 0.5 M electrolyte. The lower removal efficiency was caused by the lower energy expenditure with 0.5 M one. An effective EK-Fenton process was determined from considering the removal efficiency and the energy expenditure, simultaneously.

• Journal of the Korean Chemical Society
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• v.31 no.1
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• pp.3-13
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• 1987

Infrared absorption spectra of alkyl alcohols in the OH stretching region were obtained from varying the concentrations of alcohols in $CCl_4$. The OH stretching bands were broadened and shifted to lower frequencies due to the hydrogen-bond formation. Three bands were obtained from the breakdown of these bands by the simplex method. Each band was assigned to various types of hydrogen-bonded OH groups. The electronic structures and interaction energies of dimeric and trimeric alcohols were calculated by semi-empirical MO(CNDO/2, INDO) methods. These results were in good agreement with those of deconvoluted ir spectra. The EDA(electron donor-acceptor) effect of alkyl group on hydrogen-bond formation was in the decreasing order of butyl > propyl > ethyl > methyl group. On the other hand, the experimental results were in the order : propyl > ethyl > butyl > methyl group. This seemed to be ascribed to the bulkiness of butyl alcohol.

• Korean Journal of Soil Science and Fertilizer
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• v.32 no.4
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• pp.429-439
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• 1999

Potentiometric titration data were collected for some humic acids purified from Korean upland and paddy soils over a range of pH (3.0 - 11.0) with $NaNO_3$ background electrolyte concentrations (0.01, 0.10, 0.50 and 1.00 M). The data were applied to model A and V which included both intrinsic heterogeneity of humic materials and electrostatic interaction influences on binding sites. The elemental analysis were conducted for various type of humic samples. The $E_4/E_6$ ratio proposed negative correlation with the total carboxyl groups ($r^2$= 0.9988). The charge ($cmol_c\;kg^{-1}$) on the humic acids became more negative as the ionic strength increased. In both continuous and batch titrations, the ionic strength effect was greater in Namweon series (pH 6.39) than others at pH 5.00. The effect of ionic strength on surface charge appears to be greater in batch titrations. This could suggest that continuous titrations do not represent an equilibrium state and the effects of electrolyte concentration was not fully realized during the course of titrations. Both models described experimental data obtained from continuous and batch titrations well over a range of ionic strengths. Model A is more simpler than model V but adaptes more fitted parameters. Thus, the observed change in apparent binding constants with surface charge is regarded solely due to electrostatic influences rather than functional group heterogeneity. However, Model V is more mechanistically realistic in a number of discrete ligand binding sites.

• Applied Chemistry for Engineering
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• v.5 no.1
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• pp.149-159
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• 1994

The kinetics and equilibrium of metal extraction by benzamidoxime and phenylacetamidoxime-chloroform were investigated to apply amidoxime to metal extraction as chelating agent. The overall extraction constant extraction mechanism and selective extraction of copper were examined from the relation among extraction ratio, hydrogen ion concentration and extractant concentration. The experimental rate equation of copper extraction coincided with the theoretical rate equation and was expressed as $R_o=k{\overline{C}}_{HRo}(C_{Mo}/C_{Ho})^{1/2}$. The chemical species extracted was found to the type of ${\overline{CuR_2}}$.

• Proceedings of KOSOMES biannual meeting
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• 2009.06a
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• pp.167-169
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• 2009

넙치 치어에 대한 Naphthalene의 급성독성을 조사하기 위하여 대조구($0{\mu}g/\ell$), 1000, 1800, 3200, 5200, $10000{\mu}g/\ell$의 6개의 Naphthalene 농도구를 실정하여 24시간 동안 노출험을 실시하고 혈액학적 성상을 분석하였다. 넙치치어에 대한 Naphthalene의 24h-$LC_{50}$은 $2346.19{\mu}g/\ell$를 나타냈다. 넙치의 혈액학적 반응에서 헤마토크리트값은 5600, $10000{\mu}g/\ell$의 농도에서 대조구와 비교하여 유의하게 증가하였고, 글루코스는 $10000{\mu}g/\ell$의 농도에서 유의하게 증가 하였다. 삼투압 농토는 3200, 5600, $10000{\mu}g/\ell$의 농노 구에서 유의하게 증가하였다. 반면, 이온 분석 결과 $Na^+$, $K^+$은 5600 및 $10000{\mu}g/\ell$ Naphthalene 농도구에서 유의하게 증가하였으나 $Cl^-$는 큰 차이를 보이지 않았다.

• 한국생물공학회:학술대회논문집
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• 2003.10a
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• pp.404-408
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• 2003

In this study, hydrogen gas produced by anaerobic mocrobial at anaerobic condition. To maintain the high MLSS concentration, anaerobic sludge was transformed to granular sluge by adding both high molecular cationic polymer(M.W>5,000,000) and silica sol. Hydrogen production was easily distributed, which seemed caused by methane producing microbial. Even low pH control(pH<5.5) was not the effective mean to block methane producing microbial. To decrease of $H_2$ production was closely related with the inclose of $CH_4$ production. Other mean expect for pH control must be devised for the efficient $H_2$ production.

• 한국생물공학회:학술대회논문집
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• 2003.04a
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• pp.339-342
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• 2003

In this study , hydrogen gas produced by anaerobic mocrobial at anaerobic condition. To maintain the high MLSS concentration, anaerobic sludge was transformed to granular sluge by adding both high molecular cationic polymer(M.W.>5,000,000) and silica sol. Hydrogen production was easily distributed, which seemed caused by methane producing microbial. Even low pH control(pH<5.5) was not the effective mean to block methane producing microbial. To decrease of $H_2$ production was closely related with the inclose of $CH_4$ production. Other mean expect for pH control must be devised for the efficient $H_2$ production.

• Resources Recycling
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• v.20 no.4
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• pp.65-70
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• 2011

Environmental friendly leaching process for the recovery of cobalt and lithium from the $LiCoO_2$ was investigated by organic acids as a leaching reagent. The experimental parameters, such as organic acid type, concentrations of leachant and hydrogen peroxide, reaction time and temperature as well as the pulp density were tested to obtain the most effective conditions for the leaching of cobalt and lithium. The results showed that the latic acid was the most effective leaching reagent for cobalt and lithium among the organic acids and was reached about 99.9% of leaching percentage respectively. With the increase of the concentration of citric acid, hydrogen peroxide and temperature, the leaching rate of cobalt and lithium increased. But the increase of pulp density decreased the leaching rate of cobalt and lithium.

• Journal of the Korean Wood Science and Technology
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• v.42 no.4
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• pp.460-466
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• 2014

To evaluate wood charcoal as raw material for mineral water production, dissolution of inorganic ions from charcoal to water, pH and adsorption ability of chlorine in water were investigated as main variables. More potassium ion was dissolved in water as higher temperature manufactured charcoal but other ions showed no difference with different charcoal making temperatures. Highest dissolved cation was potassium followed by calcium and sodium. Among wood species, charcoal from Quercus variabilis and Platanus occidentalis showed significantly higher potassium content in water than that of larch, red pine and white pine. Other cations had similar pattern to the potassium but their difference was not apparent as much as potassium. pH value of water treated with charcoal was higher for wood charcoals from Platanus occidentalis (pH 8.5) and Quercus variabilis (pH 8.4) which contained higher inorganic cations. In chlorine removal in water by charcoal, all wood charcoals showed greater chlorine removal than that of the control, but softwood charcoals resulted in higher removal than those of hardwoods. There was no significant difference in the dissolution of cations and pHs between particle charcoal and whole charcoal. With easy of control, whole charcoal is better for mineral water making raw material than particle charcoal does.