• Journal of the Korean Institute of Gas
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• v.24 no.1
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• pp.41-48
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• 2020

This study performed a quantitative risk assessment for hydrogen-CNG complex refueling stations. Individual and societal risks were calculated by deriving accident scenarios that could occur at hydrogen and CNG refueling stations and by considering the frequency of accidents occurring for each scenario. As a result of the risk assessment, societal risk levels were within the acceptable range. However, individual risk has occurred outside the allowable range in some areas. To identify and manage risk components, high risk components were discovered through risk contribution analysis. High risks at the hydrogen-CNG complex refueling station were large leakage from CNG storage containers, compressors, and control panels. The sum of these risks contributed to approximately 88% of the overall risk of the fueling station. Therefore, periodic and intensive safety management should be performed for these high-risk elements.

• Explosives and Blasting
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• v.40 no.4
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• pp.27-34
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• 2022

The government is promoting various policies to reduce greenhouse gas emissions for carbon neutrality, one of the key tasks is to revitalize the hydrogen economy. As one of these policies the government has formulated a plan to incorporate hydrogen into existing city gas pipes, and aims to commercialize 20% hydrogen mixing by 2026. In preparation for the commercialization of city gas and hydrogen mixture, this study quantitatively predicts the scale of damage and the range of impact in the event of leakage of these two gas mixtures. The quantitative damage prediction method is to calculate the damage conversion distance through the calculation of the TNT equivalent by setting the leakage amount of the gas mixture in the event of an accident under a virtual scenario.

• Journal of the Korean Institute of Gas
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• v.13 no.1
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• pp.45-51
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• 2009

A safety assessment was performed through the process analysis of hydrogen station. The purpose of this study provides basic information for the standard establishment about hydrogen stations. The processes of hydrogen stations were classified by four steps (process of manufacture, compression, storage, charge). FMEA (Failure Mode and Effect Analysis) method was applied to evaluate safety. Each risk element is following; S (severity), O (occurrence), D (detection). And the priority of order was decided by using RPN (Risk Priority Number) value multiplying three factors. Scenarios were generated based on FMEA results. And consequence analysis was practiced using PHAST program. In the result of C.A, jet fire and explosion were shown as accident types. In case of leakage of feed line in PSA process, concentration of CO gas is considered to prevent CO gas poisoning when the raw material that can product CO gas was used.

• Fire Science and Engineering
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• v.25 no.6
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• pp.32-38
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• 2011

As the using rate of an explosive gas has been increased in the industrial site, the regional residents adjacent to the site as well as the site workers have frequently fallen into a dangerous situation. Damage caused by accident in the process using hydrogen gas is not confined only to the relevant process, but also is linked to a large scale of fire or explosion and it bring about heavy casualties. Therefore, personnel in charge should investigate the kinds and causes of the accident, forecast the scale of damage and also, shall establish and manage safety countermeasures. We, in Anti-Calamity Research Center, forecasted the scope of danger if break out a fire or/and explosion in hydrogen gas facilities of MLCC firing process. We selected piping leak accident, which is the most frequent accident case based on an actual analysis of accident data occurred. We select and apply piping leak accident which is the most frequent case based on an actual accident data as a model of damage forecasting scenario caused by accident. A jet fire breaks out if hydrogen gas leaks through pipe size of 10 mm ${\Phi}$ under pressure of 120 bar, and in case of $4kw/m^2$ of radiation level, the radiation heat can produce an effect on up to distance of maximum 12.45 meter. Herein, we are going to recommend safety security and countermeasures for improvement through forecasting of accident damages.

• Journal of the Korean Institute of Gas
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• v.15 no.2
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• pp.1-8
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• 2011

In this research, the safety trends and technologies of HCNG, a mixture of hydrogen and natural gas, are analyzed. This is an attracting alternative fuels to meet the strengthened automotive exhaust gas emission standards. HCNG is very important opportunities and challenges in that it is available the existing CNG infrastructures, meets the strengthened emission standards, and the technical, social bridge of the coming era of hydrogen. It is essential for the commercialization of HCNG that hydrogen - compressed natural gas blended fuel for use in preparation of various safety considerations included accidents scenario, safety distance, hydrogen attack, ignition sources and fire detectors are examined. Risk assessments also are suggested as one of permission procedure for HCNG filling station.

• Journal of the Korean Institute of Gas
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• v.16 no.1
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• pp.15-21
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• 2012

An analysis was completed of the hazards distance of hydrogen accidents such as jet release, jet fire, and vapor cloud explosion(VCE) of hydrogen gas, and simplified equations have been proposed to predict the hazard distances to set up safety distance by the gas dispersion, fire, and explosion following hydrogen gas release. For a small release rate of hydrogen gas, such as from a pine-hole, the hazard distance from jet dispersion is longer than that from jet fire. The hazard distance is directly proportional to the pressure raised to a half power and to the diameter of hole and up to several tens meters. For a large release rate, such as from full bore rupture of a pipeline or a large hole of storage vessel, the hazard distance from a large jet fire is longer than that from unconfined vapor cloud explosion. The hazard distance from the fire may be up to several hundred meters. Hydrogen filling station in urban area is difficult to compliance with the safety distance criterion, if the accident scenario of large hydrogen gas release is basis for setting up the safety distance, which is minimum separation distance between the station and building. Therefore, the accident of large hydrogen gas release must be prevented by using safety devices and the safety distance may be set based on the small release rate of hydrogen gas. But if there are any possibility of large release, populated building, such as school, hospital etc, should be separated several hundred meters.

• Korean Journal of Environmental Agriculture
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• v.38 no.1
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• pp.54-60
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• 2019

BACKGROUND: Hydrogen fluoride is one of the 97 accident preparedness substances regulated by the Ministry of Environment (Republic of Korea) and chemical accidents should be managed centrally due to continual occurrence. Especially, hydrogen fluoride has a characteristic of rapid diffusion and very toxic when leaking into the environment. Therefore, it is important to predict the impact range quickly and to evaluate the residual contamination immediately to minimize the human and environmental damages. METHODS AND RESULTS: In order to estimate the accident impact range, the off-site consequence analysis (OCA) was performed to the worst and alternative scenarios. Also, in order to evaluate the residual contamination of hydrogen fluoride in crop, the samples in accident site were collected from 15-divided regions (East direction from accident sites based on the main wind direction), and the concentration was measured by fluoride ($F^-$) ion-selective electrode potentiometer (ISE). As a result of the OCA, the affected distance by the worst scenario was estimated to be >10 km from the accident site and the range by the alternative scenario was estimated to be about 1.9 km. The residual contamination of hydrogen fluoride was highest in the samples near the site of the accident (E-1, 276.82 mg/kg) and tended to decrease as it moved eastward. Meanwhile, the concentrations from SE and NE (4.96~28.98 mg/kg) tended to be lower than the samples near the accident site. As a result, the concentration of hydrogen fluoride was reduced to a low concentration within 2 km from the accident site (<5 mg/kg), and the actual damage range was estimated to be around 2.2 km. Therefore, it is suggested that the results are similar to those of alternative accident scenarios calculated by OCA (about 1.9 km). CONCLUSION: It is difficult to estimate the chemical accident-affecting range/region by the OCA evaluation, because it is not possible to input all physicochemical parameters. However simultaneous measurement of the residual contamination in the environment will be very helpful in determining the diffusion range of actual chemical accident.

• Journal of Korean Tunnelling and Underground Space Association
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• v.24 no.4
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• pp.305-316
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• 2022

Hydrogen energy is emerging as an alternative to the depletion of fossil fuels and environmental problems, and the use of hydrogen vehicles is increasing in the automobile industry as well. However, since hydrogen has a wide flammability limit of 4 to 75%, there is a high concern about safety in case of a hydrogen car accident. In particular, in semi-enclosed spaces such as tunnels and underground parking lots, a fire or explosion accompanied by hydrogen leakage is highly likely to cause a major accident. Therefore, it is necessary to review hydrogen safety through analysis of flammability areas caused by hydrogen leakage. Therefore, in this study, the effect of the air velocity in the tunnel on the flammability area was investigated by analyzing the hydrogen concentration according to the hydrogen leakage conditions of hydrogen vehicles and the air velocity in the tunnel in a road tunnel with standard section. Hydrogen leakage conditions were set as one tank leaking and three tanks leaking through the TPRD at the same time and a condition in which a large crack occurred and leaked. And the air velocity in the tunnel were considered 0, 1, 2.5, and 4.0 m/s. As a result of the analysis of the flammability area, it is shown that when the air velocity of 1 m/s or more exists, it is reduced by up to 25% compared to the case of air velocity of 0 m/s. But there is little effect of reducing the flammability area according to the increase of the wind speed. In particular, when a large crack occurs and completely leaks in about 2.5 seconds, the flammability area slightly increases as the air velocity increases. It was found that in the case of downward ejection, hydrogen gas remains under the vehicle for a considerably long time.

• Journal of the Society of Disaster Information
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• v.19 no.2
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• pp.411-420
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• 2023

Purpose: In order to compensate for the limitations of the risk assessment of hydrogen charging stations, it is proposed to apply business disaster reduction activities as a way to strengthen safety and business continuity for accidents that may occur during operation. Method: We explored the application of business disaster reduction activities that can reduce, eliminate, transfer, and accept risks by classifying risks according to the passage of time in the installation and operation of hydrogen charging stations, identifying key tasks, deriving risk scenarios. Result: Existing research results are appropriately applied to the risk assessment conducted in the stage before the installation of hydrogen charging stations. However, there is a limit to the risks that can occur at the operational stage, so applying business disaster reduction activities with several example scenarios has resulted in that it can be applied as a way to strengthen safety and business continuity. Conclusion: All of the currently implemented risk assessments for hydrogen charging stations are being used appropriately. However, it proposes business disaster reduction activities that apply various risk scenarios as an evaluation and response to possible risks at the operational stage.

• Journal of the Korean Institute of Gas
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• v.27 no.4
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• pp.70-77
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• 2023

In response to climate change, each country is proposing a goal to reduce greenhouse gases in its energy supply and demand plan, and the use of hydrogen gas is a topic that is always prioritized as an energy resource for implementation. A popular way to use this hydrogen gas is the use of hydrogen fuel cell vehicles, and expansion of hydrogen charging stations is essential for using these hydrogen fuel cell vehicles. However, there are several limitations to the expansion of hydrogen refueling stations, the most representative of which is resident acceptance. Most of the hydrogen charging stations currently built in Korea are located in the outskirts with low population density, so the inconvenience to hydrogen fuel cell vehicle users has not been resolved, and as a result, there has been no progress in the spread of hydrogen fuel cell vehicles. In this paper, we analyzed the consequences of accident damage to determine the risks of constructing a hydrogen charging station on a railroad site frequently used by citizens. The target hydrogen charging station site was a railroad depot in Busan, and there are trains, national highways, and commercial facilities around this site. Assuming the worst-case scenario, we would like to consider the safety of the hydrogen refueling station site by analyzing the area affected by the accident and its consequence.