• Title/Summary/Keyword: 수분 수지

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The Aging Effect of $Avimid^(R)$ K3B/1M7 Laminates in $80^{\circ}C$ Water ($Avimid^(R)$ K3B/IM7 복합재료의 $80^{\circ}C$ 물에서의 노화현상)

  • Kim Hyung-Won
    • Journal of the Korean Society of Propulsion Engineers
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    • v.9 no.4
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    • pp.23-30
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    • 2005
  • The Hygrothermal aging of the laminates of $Avimid^(R)$ K3B/IM7 in $80^{\circ}C$ water was studied as a function of immersion time prior to forming microcracks. The factors causing the $80^{\circ}C$ water to degradation of the laminates could be the degradation of the matrix toughness, the change in residual stresses or the interfacial damage between the fiber and the matrix. The times to saturation in $80^{\circ}C$ water for the laminates and for the neat resin were 100 hours and 500 hours. After 500 hours aging of the neat resin, the glass transition temperature was changed less than 1% by DSC test, and the weight gain was 1.55% increase with the diffusion coefficient $7\times10^{-6}m/s^2$ and the fracture toughness was decreased about 41%. After 100 hours fully saturated aging of the ${[+45/0/-45/90]}_s$ K3B/IM7 laminates in $80^{\circ}C$ water, the weight gain was 0.41% increase with the diffusion coefficient $1\times10^{-6}m/s^2$. In 100 hours, the loss of the fracture toughness of the laminates was 43.8% of the original toughness by the microcracking fracture toughness criterion. Therefore, the main factor to degrade the microcracking toughness of the laminates could be the degradation of the matrix fracture toughness.

The Study of Water Stability of MDF Cement Composite by Addition of Silane Coupling Agent (Silane Coupling Agent 첨가에 의한 MDF Cement Composite의 수분안정성 연구)

  • 노준석;김진태;박춘근;오복진;최상홀
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.421-428
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    • 1998
  • The effect of silane coupling agents on the water stability of HAC/PVA based MDF cement composites which were modified with urethane and epoxy resin were studied as a function of the functional groups and addition amount of silane coupling agent. According to the composition of polymer matrix the silanes with different functional groups showed the different effectiveness. In case of the only PVA matrix the silane with vinyl functional group was more effective than other silanes. When the epoxy resin was added the silane of epoxy-methodxy group enhanced the flexural strength of dry and wet state more than other. In case of urethane-added MDF cement the silane of diamine group was effective and enhanced the water sta-bility fo MDF cement composite more and more as the addition amount of silane increased, Especially in case of warm-presed composite the effect of silane was enhanced By addition of 2wt% of silane with 야-amine group the flexural strength of urethane-added composites were enhanced by 20% more in dry state 40-70% in wet state in accord with the porosity analysis. The flexural strength of the poxy resin-added MDF cement composite was increased by addition of 1wt% and 2wt% silane of epoxy-methoxy group However the addition of 4wt% of silane decreased the flexural strength of dry and wet state by formation of closed pore in the polymer matrix.

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Experimental Study on Reducing Effect for Surface Temperature of Recycled Synthetic-Resin Permeable Block (재생 합성수지 투수블록의 표면온도 저감효과에 관한 실험적 연구)

  • Lee, Chul-Hee;Lee, Arum;Shin, Eun-Chul;Ryu, Byung-Hyun
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.1
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    • pp.79-89
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    • 2019
  • The field measurement and laboratory experiment were conducted to investigate the effect of reducing the surface temperature of the functional aspect of the heat island phenomenon of the permeable block which is made the recycled synthetic resin rather than the existing concrete permeable block. Field measurement was taken for 3 days in consideration of dry condition and wet condition and laboratory experiment was divided into dry condition, rainfall simulating condition, and wetting condition. The variations of temperature and the evaporation rate of water moisture content after experiment were confirmed. As a result of field measurement, it is confirmed that the surface temperature decreases due to the difference in albedo of the pore block surface rather than the cooling effect due to the latent heat of vaporization. The evaporation of moisture in a dry state where drought persisted or a certain level of moisture was not maintained in the surface layer. As a result of laboratory experiment, resin permeable block gives higher surface temperature when it is dry condition than concrete permeable block, but the evaporation of water in the pore is kept constant by capillary force in rainfall simulation condition, and higher temperature reduction rate. As a result of measuring the evaporation rate after laboratory experiment, it is confirmed that the effect of reducing temperature is increased as the evaporation rate of water is higher. Based on these results, correlation formula for evaporation rate and temperature reduction rate is derived.

Ecological Importance of Water Budget and Synergistic Effects of Water Stress of Plants due to Air Pollution and Soil Acidification in Korea (한국에서 수분수지의 생태적 중요성과 대기오염 및 토양 산성화로 인한 식물의 수분스트레스 증대 효과)

  • 이창석;이안나
    • The Korean Journal of Ecology
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    • v.26 no.3
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    • pp.143-150
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    • 2003
  • Korea has plentiful precipitation but rainfall events concentrate on several months of rainy season in her weather condition. Korea, therefore, experiences drought for a given period every year. Moreover the soil has usually low water holding capacity, as it is composed coarse particles originated from the granite. Response of several oaks and the Korean red pine (Pinus densiflora) on water stress showed that water budget was significant factor determining vegetation distribution. In addition, dehydration level due to cold resistance mechanism of several evergreen plants during the winter season was closely related to their distribution in natural condition. Experimental result under water stress showed that the Korean red pine was very tolerant to desiccation but the seedlings showed high mortality during the dry season. The mortality tended to proportionate to soil moisture content of each site. A comparison between soil moisture content during June when it is severe dry season and moisture content of the culture soil when the pine seedlings reached the permanent wilting point due to water withheld proved that high mortality during the dry season was due to water deficit. Water potential of sample plants measured during the exposure experiment to the air pollutant showed a probability that water related factors would dominate the occurrence of visible damage and the tolerance level of sample plants. In both field survey and laboratory experiment, plants exposed to air pollution showed more rapid transpiration than those grown in the unpolluted condition. The result would due to injury of leaf surface by air pollutants. Aluminum (Al/sup 3+/) increased in the acid soil not only inhibits root growth but also leads to abnormal distribution of root system and thereby caused water stress. The water stresses due to air pollution and soil acidification showed a possibility that they play dominating roles in inducing forest decline additionally to the existing water deficit due to weather and soil conditions in Korea. Sludge, which can contribute to improve field capacity, as it is almost composed of organic matter, showed an effect ameliorating the retarded growth of plant in the acidified soil. The effect was not less than that of dolomite known in widely as such a soil ameliorator. Litter extract contributed also to mitigate the water stress due to toxic Al/sup 3+/. We prepared a model showing the potential interaction of multiple stresses, which can cause forest decline in Korea by synthesizing those results. Furthermore, we suggested restoration plans, which can mitigate such forest decline in terms of soil amelioration and vegetation restoration.

The Effect of Mass Transfer on the Cure Properties of the Urea Resin Moulding Compounds Under the Drying Process (건조 공정 중 요소 수지 성형재료의 경화 특성에 대한 물질전달 효과)

  • Kim, Sang Yeul;Choi, Il Gon;Kim, Byoung Chul
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.681-686
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    • 2002
  • In the industrial field, the theory of drying process is different from the practical application, and it is effective to reduce energy by recirculation of the heat of exhausting gas. But the study of this field may not be performed still. The cure properties of the urea resin moulding compounds was investigated according to drying temperature, drying time, recycle rate of exhausting gas and moulding temperature in the process of drying and moulding. We obtained the following results; water content of material decreases with increasing drying time and drying temperature, and the rate of drying also decreases with increasing recycle rate of exhausting gas. Specially, The cure fluidity of the urea resin moulding compounds decreases, with increasing drying temperature, recycle rate of exhausting gas and moulding temperature. And the correlation equations on water content and cure fluidity of the urea resin moulding material were obtained through a regression analysis of experimental data.

Synthesis and Characterization of Poly(Urethane-Methyl methacrylate) Hybrid Emulsion as a Plastic Coating Resin (플라스틱 코팅용 Poly(Urethane-MMA) 혼성 에멀젼 합성 및 특성 연구)

  • Yeom, Ji-Yoon;Baek, Kyung-Hyun;Lee, Jun-Young;Yi, Gyoung-Bae;Yoo, Byung-Won;Kim, Jung-Hyun
    • Journal of Adhesion and Interface
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    • v.8 no.1
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    • pp.8-14
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    • 2007
  • Poly(urethane-methyl methacrylate) hybrid emulsions can be controlled with their thermal, mechanical and anti-chemical properties as plastic coating materials. In this study, water dispersed poly(urethane-methyl methacrylate) hybrid emulsions were prepared by prepolymer synthesis and soap free emulsion polymerization. For imparting hydrophilicity on polyurethane prepolymer, 2,2-bis (hydroxymethyl) propionic acid was added to the polyurethane prepolymer with methyl methacrylate monomer and was neutralizated by triethylamine (TEA). After neutralization, the prepolymer mixture was dispersed in the water phase with stable droplets. The synthesis was carried out with chain extension from the ethylene diamine and initiation of methyl methacrylate by soap free emulsion polymerization. Stable poly(urethane-methyl methacrylate) hybrid emulsion was successfully obtained with different synthetic conditions and acrylic monomer contents. Poly(urethane-methyl methacrylate) hybrid emulsion were characterized and compared with tensile strength, viscosity, and adhesion properties.

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Field Investigation of Environment Parameter in Aerobic Composting for Pig Slurry at a Scraper System (스크레파 축사에서 배출되는 돈분뇨슬러리 호기성 퇴비화의 환경요인 현장조사)

  • Ryoo, Jong-Won
    • Journal of Animal Environmental Science
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    • v.14 no.3
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    • pp.183-192
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    • 2008
  • This study was carried out to investigate the temperature, water balance, evaporation and physicochemical properties during the composting with pig slurry at a scraper system. The pig slurry was composted on farm trial using continuous aeration with turning machine for 5 month. A compost facility of rectangular concrete bin with dimension of 53 m (length) ${\times}$ 4.6 m (width) ${\times}$ 2 m (height) was bedded with sawdust. The environmental parameters were monitored in period of 5 months. The results were as follows ; 1. During the composting period, the temperature was varied in the range $50{\sim}70^{\circ}C$. The temperature of compost pile was highest in middle layer and lowest in under layer. Temperature difference between middle and under area of compost pile was $5{\sim}20^{\circ}C$. 2. The water content of compost pile varied $50{\sim}68%$. In the period of 50% of water content of compost pile, the temperature of compost was $20{\sim}30^{\circ}C$ and was not successfully composted. 3. In this study, total evaporation was 90% during composting. The amount of slurry per $1m^3$ sawdust by this method was $3.16m^3$ without treatment of effluent output. 4. The chemical properties of produced compost was high, but suitable for plant growth. Concentration of T-N, T-C in the final compost were 1.62, 34%, respectively.

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Changes in Water Potential of Pine Seedlings Inoculated with Bursaphelenchus xylophilus (소나무재선충 접종목의 수분포텐셜 변화)

  • Lee, Hwa-Yong;Koo, Chang-Duck;Sung, Joo-Han;Shin, Joon-Hwan;Yoo, Jong-Hyun
    • Journal of Korean Society of Forest Science
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    • v.99 no.3
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    • pp.337-343
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    • 2010
  • The purpose of this study was to understand water stress development in pine seedlings inoculated with Bursaphelenchus xylophilus. Leaf water potentials of four years old Pinus densiflora seedlings inoculated with the nematode were measured with a plant moisture system at predawn and midday. The midday leaf water potentials on the 35th day after the inoculation were -1.04 MPa in the infected seedlings, while -0.94 MPa in the non-infected seedlings. The predawn water potentials on the 56th day were -0.71 MPa in the infected, while -0.26 MPa in the non-infected. At this time the leaves of the infected seedlings became yellow and resin did not exude on the cut basal stem. Density of the nematode was maximum on the 28th day, but dropped sharply on the 68th day. The phloem and pith tissues became brown and the resin exudation reduced in the infected seedlings. In conclusion, pinewood nematode inoculation developed water stress in pine seedlings in a month.

An Analysis of the Drought Period Using Non-Linear Water Balance Model and Palmer Drought Severity1 Index (비선형 물수지모형과 팔머가뭄심도지수를 이용한 가뭄지속기간 분석)

  • Lee, Jae-Su
    • Journal of Korea Water Resources Association
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    • v.34 no.5
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    • pp.533-542
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    • 2001
  • In order to establish drought policy, the estimation of drought period for each drought situation should be preceded. Non-linear Water Balance Model(NWBM) and palmer Drought Severity Index (PDSI) can be used for analysis of drought period. As a water balance method considering moisture transfer between land surface and atmosphere, NWBM can be used to estimate transition time between dry and wet period induced by stochastic fluctuations. PDSI is also water balance method to show drought severity comparing actual precipitation with climatically appropriate precipitation based on precipitation and potential evapotranspiration. In this study, the drought periods are estimated using NWBM and PDSI for the Han River Basin. The drought periods according to the soil moisture estimated by NWBS and the drought periods according to drought severity index estimated by PDSI show similar trend. The estimated drought period from extreme drought to wet condition for the Han River Basin is about 3years.

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Development of GRld-eased Soil MOsture Routing Model (GRISMORM) Applied to Bocheongchun Watershed (격자기반의 토양수분추적표형 개발 : 보청천 유역 사례연구)

  • 김성준;채효석
    • Spatial Information Research
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    • v.7 no.1
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    • pp.39-48
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    • 1999
  • A GRId-based Soil MOsture Routing Model(GRISMORM) which predicts temporal variation and spatial distribution of water balance on a daily time step for each grid element of the watershed was developed. The model was programmed by C-language which aims for high flexibility to any kind of GIS softwares. The model uses ASCII-formatted map data supported by the irregular gridded map of the GRASS(Geographic Resources Analysis Support System)-GIS and generates daily or monthly spatial distribution map of water balance components within the watershed. The model was applied to Ipyunggyo watershed(75.6$km^2$) ; the part of Bocheongchun watershed. Predicted streamflows resulting from two years(95 and 96) daily data were compared with those observed at the watershed outlet. The results of temporal variation and spatial distribution of soil moisture are also presented by using GRASS.

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