• Title/Summary/Keyword: 소자 열화

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그래핀 투명전도막의 전기적 특성에 미치는 Strain 영향

  • Lee, Byeong-Ju;Jeong, Gu-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.462-462
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    • 2011
  • 그래핀은 탄소원자로 구성된 원자단위 두께의 매우 얇은 2차원의 나노재료로서 높은 투광도 뿐만 아니라 우수한 기계적, 전기적 특성을 지니며 구조적 화학적 으로도 매우 안정한 것으로 알려져 있다. 이러한 그래핀을 얻는 방법에는 물리·화학적 박리법, 탄화규소의 흑연화, 열화학기 상증착법(thermal chemical vapor deposition; TCVD)등 많은 방법들이 존재한다. 이중 TCVD방법이 대면적으로 두께균일도가 높은 그래핀을 얻는데 가장 적합한 방법으로 알려져 있다. 한편 그래핀은 우수한 특성들을 기반으로 센서나 메모리와 같은 기능성 소자로 응용이 가능할 뿐 아니라 투명고분자 기판으로 전사함으로서 유연성 투명전극을 제작 가능하여 기존의 인듐산화물(indium tin oxide; ITO) 투명전극을 대체하여 디스플레이, 터치스크린, 전·자기 차폐재 등의 다양한 분야로의 응용이 가능하다고 예측되고 있다. 본 연구에서는 TCVD법을 이용하여 대면적으로 두께균일도가 높은 그래핀을 합성하여 투명 고분자 기판(polyethylene terephthalate; PET) 위에 전사하여 투명전도막을 제작한 후, 압축변형률(compressive strain)의 변화에 따른 전기적 특성 변화를 측정하였다. 그래핀은 300 nm 두께의 니켈박막이 증착된 산화물 실리콘 기판위에 원료가스로 메탄(CH4)을 사용하여 합성하였다. 합성 결과 단층 그래핀의 면적은 약 80% 이상이었으며, 합성된 그래핀은 분석의 용이함 및 향후 다양한 응용을 위하여 식각공정을 통해 산화막 실리콘 기판과 PET기판으로 전사하였다. PET기판 위로 전사하여 제작한 그래핀 투명전도막의 strain 인가에 따른 전기적 특성을 관찰한 결과, 약 20%의 비교적 높은 strain하에서도 전기적특성이 크게 변화하지 않는 것을 확인하였다. 그래핀의 특성분석을 위해서는 광학현미경, 라만 분광기, 투과전자현미경, 자외 및 가시선 분광광도계, 4탐침측정기 등을 이용하였다.

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나노입자 페이스트를 이용한 CuInSe2 태양전지 제작

  • Jo, Hyo-Jeong;Seong, Si-Jun;Park, Mi-Seon;Hwang, Dae-Gyu;Gang, Jin-Gyu;Kim, Dae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.412-412
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    • 2011
  • CI(G)S계 태양전지는 화합물 반도체로서, 우수한 광 전류 변환 효율을 보이며, 광조사 등에 의한 열화가 없어 유망한 태양전지로 인정받고 있다. CI(G)S계 태양전지를 구성하는 흡수층을 제조하는 방법은 진공 기반의 공증착법 및 스퍼터-셀렌화법이 대표적이며, 액상의 전구체 물질을 도포하고 이를 고온 열처리하는 용액공정법도 최근 많은 연구가 이루어지고 있다. 진공 증착법은 고효율의 흡수층을 제조할 수 있고 상용화에 적합한 방법이다. 그러나 고가의 진공 장비를 이용하는 진공증착법은 원가 절감 관점에서 한계를 지니고 있어, 미래의 저가 공정 실현을 위해 용액 기반 흡수층 제조법도 다양한 접근법으로 연구되고 있으며 현재까지는 진공공정에 비해 상대적으로 낮은 변환효율이 큰 문제점으로 인식되고 있다. 용액 공정에서 전구체 물질의 코팅법으로는 spray법, spin coating법, drop-casting법, doctor-blade법 등이 있으며, 이들 중 양산 공정에 실용화되기 가장 적합한 것으로 보이는 방법으로는, 화합물 나노입자 페이스트를 기재 상에 doctor blade 법으로 코팅한 후에 이를 열처리하여 흡수층을 제조하는 방법을 들 수 있다. 이러한 방법은 균일한 흡수층을 저비용으로 제조할 수 있는 장점은 있지만, 전구체로 사용하는 화합물 나노입자들이 화학적 및 열적으로 매우 안정한 물질이므로, 최종 흡수층에서 큰 결정을 얻기 어렵고, 그 결과 효율이 낮아지는 단점이 있다. 따라서, 치밀하고 조대한 grain 형성을 위하여 CISe 균일한 나노입자를 합성하고 셀레늄을 포함하는 용액을 추가로 도포하여 열처리 공정에서 Se의 손실을 막아 입자를 성장시키는 방법과 In-Se 균일한 나노입자를 합성한 후 Cu, Se이 포함된 용액을 도포하여 코어-쉘 (InSe/CuSe)을 제작하고 이를 Se 분위기하 열처리 하여 흡수층의 결정성을 증진시키고자 하였다. 또한 다양한 방법으로 제작한 CuInSe2 나노입자로 잉크를 제작하여 닥터블레이드 공정을 적용하여 박막을 제작하고 소자 적용성을 평가하였다.

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Compensation Algorithm of Beamforming Error for Wideband Conformal Array Antenna (광대역 컨포멀 위상 배열 안테나의 빔형성 열화 보상 알고리즘)

  • Yoon, Ho-Joon;Lee, Kang-In;Nam, Sang-Wook;Chung, Young-Seek;Yoon, Young-Joong
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.28 no.6
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    • pp.478-486
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    • 2017
  • In this paper, we propose an algorithm for the wideband beamforming in a conformal phased array antenna by compensating the errors. For the wideband beamforming, we used the True Time Delay(TTD), which was fabricated on the RF circuit board to obtain long delay lines. Beamforming errors in the conformal array antenna are the mutual coupling between the array elements, the dispersive error in the TTD circuit, and the quantization error by the digital control. We apply the compensation algorithm to the conformal phased array antenna of wideband 2~4 GHz, and verify the usefulness by comparing the results with the experiment results.

Computational Simulation on Power Prediction of Lithium Secondary Batteries by using Pulse-based Measurement Methods (펄스 측정법에 기반한 리튬이차전지 출력 측정에 관한 전산 모사)

  • Park, Joonam;Byun, Seoungwoo;Appiah, Williams Agyei;Han, Sekyung;Choi, Jin Hyeok;Ryou, Myung-Hyun;Lee, Yong Min
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.33-38
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    • 2015
  • Energy storage systems (ESSs) have been utilized widely in the world to optimize the power operation system and to improve the power quality. As lithium secondary batteries are the main power supplier for ESSs, it is very important to predict its cycle and power degradation behavior. In particular, the power, one of the hardest electrochemical properties to measure, needs lots of resources such as time and facilities. Due to these difficulties, computer modelling of lithium secondary batteries is applied to predict the DC-IR and power value during charging and discharging as a function of state of charge (SOC) by using pulse-based measurement methods. Moreover, based on the hybrid pulse power characteristics (HPPC) and J-Pulse (JEVS D 713, Japan Electric Vehicle Association Standards) methods, their electrochemical properties are also compared and discussed.

Sensitive Characteristics of Hot Carriers by Bias Stress in Hydrogenated n-chnnel Poly-silicon TFT (수소 처리시킨 N-채널 다결정 실리콘 TFT에서 스트레스인가에 의한 핫캐리어의 감지 특성)

  • Lee, Jong-Kuk;Lee, Yong-Jae
    • Journal of Sensor Science and Technology
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    • v.12 no.5
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    • pp.218-224
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    • 2003
  • The devices of n-channel poly silicon thin film transistors(TFTs) hydrogenated by plasma, $H_2$ and $H_2$/plasma processes are fabricated. The carriers sensitivity characteristics are analyzed with voltage bias stress at the gate oxide. The parametric sensitivity characteristics caused by electrical stress conditions in hydrogenated devices are investigated by measuring the drain current, threshold voltage($V_{th}$), subthreshold slope(S) and maximum transconductance($G_m$) values. As a analyzed results, the degradation characteristics in hydrogenated n-channel polysilicon thin film transistors are mainly caused by the enhancement of dangling bonds at the poly-Si/$SiO_2$ interface and the poly-Si grain boundary due to dissolution of Si-H bonds. The generation of traps in gate oxide are mainly dued to hot electrons injection into the gate oxide from the channel region.

Changes in Electrical Properties of ZnO Surge Arresters According to Surrounding Conditions (외부 환경조건에 따른 ZnO 피뢰기의 전기적 특성의 변화)

  • Lee, Seung-Ju;Lee, Su-Bong;Lee, Bok-Hee
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.9
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    • pp.62-68
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    • 2008
  • This paper describes the electrical characteristics of ZnO surge arresters associated with the variation of surrounding conditions. To investigate the deterioration behaviors of ZnO surge arresters due to lightning surges, 8/20[${\mu}s$], 2.5[kA] impulse currents were injected to the ZnO surge arrester under test. The leakage currents of ZnO surge arrester subject to power frequency AC voltage were measured in different surrounding temperature and wet conditions. As a result, it was found that the leakage current is increased and its asymmetry is pronounced as the number of injection of the impulse current and the ambient temperature increase. Also, in the wet test the outside leakage current flowing through the housing surface of the ZnO surge arrester is much larger than the intrinsic leakage current of ZnO surge arrester element. The results obtained in this work can be a lied as factors of improving the reliability and performance of monitoring system for surge arresters.

Optimization of Optical Coupling Properties of Active-Passive Butt Joint Structure in InP-Based Ridge Waveguide (InP계 리지 도파로 구조에서 활성층-수동층 버트 조인트의 광결합 효율 최적화 연구)

  • Song, Yeon Su;Myeong, Gi-Hwan;Kim, In;Yu, Joon Sang;Ryu, Sang-Wan
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.47-54
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    • 2020
  • Integration of active and passive waveguides is an essential component of the photonic integrated circuit and its elements. Butt joint is one of the important technologies to accomplish it with significant advantages. However, it suffers from high optical loss at the butt joint junction and need of accurate process control to align both waveguides. In this study, we used beam propagation method to simulate an integrated device composed of a laser diode and spot size converter (SSC). Two SSCs with different mode properties were combined with laser waveguide and optical coupling efficiency was simulated. The SSC with larger near field mode showed lower coupling efficiency, however its far field pattern was narrower and more symmetric. Tapered passive waveguide was utilized for enhancing the coupling efficiency and tolerance of waveguide offset at the butt joint without degrading the far field pattern. With this technique, high optical coupling efficiency of 89.6% with narrow far field divergence angle of 16°×16° was obtained.

Improved charge balance in quantum dot light-emitting diodes using self-assembled monolayer (자기조립단분자막을 이용한 양자점 발광다이오드의 전하 균형도 개선)

  • Sangwook Park;Woon Ho Jung;Yeyun Bae;Jaehoon Lim;Jeongkyun Roh
    • Journal of IKEEE
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    • v.27 no.1
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    • pp.30-37
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    • 2023
  • To improve the efficiency and stability of colloidal quantum dot light-emitting diodes (QD-LEDs), it is essential to achieve charge balance within the QD emissive layer. Zinc oxide (ZnO) is widely used for constructing an electron transport layer in the state-of-the-art QD-LEDs, but spontaneous electron injection from ZnO often results in excessive electrons in QDs that significantly deteriorate the performance of QD-LEDs. In this study, we demonstrated the improved performance of QD-LEDs by modifying the electron injection property of ZnO with self-assembled monolayer (SAM)-treatment. As a result of improved charge balance, the external quantum efficiency and maximum luminance of QD-LEDs with SAM-treatment were improved by 25% and 200%, respectively, compared to the devices without SAM-treatment.

Analysis of the Impact of Alignment Errors on Electrical Signal Transmission Efficiency in Interconnect and Bonding Structures (배선 및 본딩 접합 구조에서 정렬 오차에 따른 전기 신호 전달 효율 변화에 대한 분석)

  • Seung Hwan O;Seul Ki Hong
    • Journal of the Microelectronics and Packaging Society
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    • v.31 no.3
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    • pp.38-41
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    • 2024
  • In semiconductor manufacturing, the alignment process is fundamental to all manufacturing steps, and alignment errors are inevitably introduced. These alignment errors can lead to issues such as increased resistance, signal delay, and degradation. This study systematically analyzes the changes in the electrical characteristics of the bonding interface when alignment errors occur in metal interconnect and bonding structures. The results show that current density tends to concentrate at the edges of the bonding interface, with the middle part of the interface being particularly vulnerable. As alignment errors increase, the current path redistributes, causing previously concentrated current areas to disappear and an effect similar to an increase in contact area, resulting in a decrease in resistance in certain vulnerable parts. These findings suggest that proposing structural improvements to eliminate the vulnerable parts of the bonding interface could lead to interconnect with significantly improved resistance performance compared to existing structure. This study clarifies the impact of alignment errors on electrical characteristics, which is expected to play a crucial role in optimizing the electrical performance of semiconductor devices and enhancing the efficiency of the manufacturing process.

Improvement of duty rate of Meteor Burst communication with Buried Antenna (매설형 안테나를 이용한 유성 버스트 통신의 도통율 개선)

  • 김병철;이영철;김기채
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 1999.05a
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    • pp.254-260
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    • 1999
  • Meteor Burst Communication can provide effective and economical means of communication where long distance VHF NLOS data transmission is needed; often ranges more than 1000 km. It has been, however, so far considered unsuitable for short distance application because of phenomenal decrease in burst durations, which leads to decreation of total duty rate of the system. This paper extensively analyzes characteristics of shot distance MB(Meteor Burst) path and shows the low duty rate may be improved by increasing burst rate through adapting antenna beam width to cover entire hot-spot region in the space and, by compensating effective burst length through cutting down man-made noises introduced by antenna. Based on the analysis, we are developed a small-opening-cavity antenna, especially designed for short distance MB path. In operation, the antenna is to be buried under ground surface so as to improve directivity and reduces noise introduction. The antenna exhibits power gain of 3 dB with 90 degree beam width and thus enables to illuminate entire hot-spot regions with the elevation angle of 8-90 degree which is the case of transmission less than 100 km. Directivity horizontal to earth surface is suppressed to minimum which enables to cut man-made noises from near-by sources down to more than 3 dB from the level reported with conventional 4 element Yagi. A series of experiments performed on 100 km MB paths have conformed that, with the antenna installed at receiving site, the burst rate and duration time have been noticed to increase by 10 and 20 percent respectively from the values obtained by conventional 4-element Yagi antenna under same testing condition.

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