• Title/Summary/Keyword: 소성환경

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Characteristics of Red mud Ceramics according to Sintering Temperature and Contents of Red Mud from Industrial Byproducts (산업부산물 레드머드 첨가량에 따른 소성온도별 레드머드 세라믹의 특성)

  • Kang, Suk-Pyo;Kang, Hye-Ju;Lee, Min-Hi
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.5
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    • pp.401-409
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    • 2019
  • This paper aims to recycle red mud from a byproduct in the alumina industry as an alternative raw material for depleted natural resources. In order to apply red mud as a ceramic material, red mud ceramics were prepared according to mixing and temperature in a laboratory environment. Compared with KS L 4201 in terms of compression ratios and absorptions, it is found that two kinds of conditions for one type and three conditions for two types meet the standard. When red mud is used as a clay brick raw material, the substitution ratio of red mud is 10% or less, and the firing temperature is considered to be appropriate at $1200^{\circ}C$. In order to apply red mud to clay brick raw material in actual field, various samples and firing temperature should be considered in the future.

Performance Evaluation of Plate Heat Exchanger Applied Low Temperature Cofired Coating (저온소성 코팅을 적용한 판형 열교환기의 성능평가)

  • Lee, Won-Ju;Shin, Woo-Jung;Lee, Dong-kyu;Choi, Jae-Hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.4
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    • pp.407-414
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    • 2017
  • In this study, a performance evaluation was conducted using a SUS 304 plate applied to low-temperature co-fired coating as a replacement for titanium plates. As a result of computational fluid dynamic analysis, the SUS 304 plate, applied to low-temperature co-fired coating, showed better heat transfer performance than a titanium plate, for 100 micron thickness coating. The result of the experiments using an actual heat exchanger revealed that a coated SUS 304 plate showed better heat transfer performance than a titanium plate. Furthermore, as the degree of corrosion and scale formation of the plate was confirmed through an overhaul inspection, the corrosion resistance of a coated SUS 304 plate was found to be almost the same as that of a titanium plate, and the inhibition effect of scale formation by sea water was better with a coated SUS 304 plate.

Excess Pore Pressure Induced by Cone Penetration in OC Clay (콘관입으로 인한 과압밀점토의 과잉간극수압의 분포)

  • Kim, Tai-Jun;Kim, Sang-In;Lee, Woo-Jin
    • Journal of the Korean Geotechnical Society
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    • v.22 no.11
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    • pp.75-87
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    • 2006
  • A series of calibration chamber tests are performed to investigate the spatial distribution of the excess porewater pressure due to piezocone penetration into overconsolidated clays. It was observed that the excess porewater pressure increases monotonically from the piezocone surface to the outer boundary of the shear zone and then decreases logarithmically, approaching zero at the outer boundary of the plastic zone. It was also found that the size of the shear zone decreases from approximately 2.2 to 1.5 times the cone radius with increasing OCR, while the plastic radius is about 11 times the piezocone radius, regardless of the OCR. Based on the modified Cam clay model and the cylindrical cavity expansion theory, the expressions to predict the Initial porewater pressure at the piezocone were developed, considering the effects of the strain rate and stress anisotropy. The method of predicting the spatial distribution of excess porewater pressure proposed in this study was verified by comparing it with the porewater pressure measured in overconsolidated specimens in the calibration chamber.

Variation of Frit Size and Firing Conditions for High Transmittance in $P_2O_5$-ZnO-RO Glass System ($P_2O_5$-ZnO-RO 유리계의 고 투과율 특성을 위한 프릿 크기 및 소성조건의 변화)

  • 차명룡;전재삼;정병해;김형순
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.197-197
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    • 2003
  • 현재 PDP(Plasma Display Panel) 투명유전체층은 PbO 계열을 사용하고 있으나 제조공정 시 다량의 중금속 페기물이 방출됨에 따라 환경오염을 야기시킴으로 무연조성이며 저온소성이 가능한 저융점유리인 인산염계 유리에 대한 열적, 화학적, 광학적 특성에 대해 체계적인 연구가 진행되었다. 광학적 특성을 위 한 승온속도, 소성온도, 유지시간의 변화 그리고, 프릿 입도에 따른 광 투광성, 기포의 형성, 그리고 기포의 분포특성을 연구하였다. 열적특성은 DTA와 TMA를 이용하여 유리전이점(Tg) 및 선팽창계수(CTE)와 Littleton softning point (Ts)가 측정되었다. 광학적특성은 스크린프린팅법으로 후막 제조 후 소성하여 UV-visible spectrometer을 이용하여 300~800nm영역에서 투광성을 측정하였으며, FEG-SEM, AFM을 이용해 표면을 관찰하였다. 결과로써, Tg는 440-46$0^{\circ}C$ 와 CTE는 7~8.5$\times$$10^{-6}$K값을 보였고 높은 화학적 내구성과 60-80%의 광투과율을 나타내었다. 프릿의 미세화, 숭온속도의 감소는 기포의 생성을 줄이는데 효과를 보였으며, 그 결과 양호한 광투과율을 얻을 수 있었다. 이러한 결과에 따르면, P$_2$O$_{5}$-ZnO-RO 조성은 PDP용 투명유전체 조성으로써 기존의 PbO계열을 대체할만한 새로운 조성으로 고려된다.

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Preparation of Multi-functional Brick Using MSWI Fly Ash (소각재를 이용한 건축외장재 제조)

  • Ban, Hyo-Jin;Park, Eun-Zoo;Lee, Woo-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.2
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    • pp.114-118
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    • 2009
  • With the advance of industrialization and urbanization, a lot of waste has been discharged and treated by incineration. But fly and bottom ashes are generated in this process. In addition, the treatment method to recycle sewage sludge and melting slag is required to manage these wastes. The objective of this research was to prepare of multi-functional brick which were made from MSWI (Municipal solid wastes incinerator) fly ash, sewage sludge and slag. The bricks were made by mixing raw materials and then drying for 24 hours. Next, they were dried for 24 hours at $160^{\circ}C$ and fired for 2 hours. Calcination temperature was changed to discuss the effect of temperature from $1,080^{\circ}C$ to $1,130^{\circ}C$. Compressive strength of a brick was creased with the increase of temperature. To increase mixing ratio of fly ash and slag reduce the compressive strength the optimal condition was the mixing ratio of fly ash : melting slag : sewage sludge : clay as 10 : 20 : 5 : 65 and $1,150^{\circ}C$ of calcination temperature. Compressive strength was obtained as about 41 MPa at this condition.

Study on the Effect of NH3-Selective Catalytic Reduction Efficiency according to Sb Calcination Temperature in V/Sb/TiO2 Catalyst (V/Sb/TiO2 촉매에서 Sb 소성온도에 따른 NH3-SCR 효율 영향 연구)

  • Choi, Gyeong Ryun;Yeo, Jong Hyeon;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.31 no.6
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    • pp.646-652
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    • 2020
  • In this study, an NH3-selective catalytic reduction (SCR) experiment was performed to control NOx in the temperature range of 200~500 ℃. The reaction activity experiment was conducted by varying the firing temperature of Sb/TiO2 when using V/Sb/TiO2 composite as a catalyst. As a result, when the sintering temperature of Sb/TiO2 was 600 ℃, the efficiency was the best, and it was confirmed that the NOx conversion rate was close to 80% at the reaction temperature of 250 ℃. H2-temperature programmed reduction (TPR), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS) analyses were employed to derive the cause of the activity enhancement when prepared at different firing temperatures as described above. As a result, when the sintering temperature of Sb/TiO2, which showed an excellent activity, was prepared at 600 ℃, it was confirmed that VSbO4 was generated. This indicates that the non-stoichiometric species of V increased, resulting in the excellent NOx conversion rate of V/Sb/TiO2.

Evaluation of Flexural Ductility of Negative Moment Region of I-Girder with High Strength Steel (고강도 강재 적용 I-거더의 부모멘트부 휨연성 평가)

  • Joo, Hyunsung;Moon, Jiho;Choi, Byung-Ho;Lee, Hak-Eun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.6A
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    • pp.513-523
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    • 2010
  • For continuous I-girder bridges, a large negative bending moment is generated near pier region so that plastic hinge is first formed at this point. Then, the bending moment is redistributed when the I-girder has enough flexural ductility (or rotational capacity). However, for I-girder with high strength steel, it is known that the flexural ductility is considerably decreased by increasing the yield strength of material. Thus, it is necessary to conduct a study for guaranteeing proper flexural ductility of I-girder with high-strength steel. In this study, the evaluation of flexural ductility of negative moment region of I-girder with high strength steel where yield stress of steel is 680 MPa is presented based on the results of finite element analysis and experiment. From the results, it is found that the flexural ductility of the I-girder is significantly reduced due to the increase of elastic deformation and the decrease of plastic deformation ability of the material when the yield strength increases. In this study, the method to improve the flexural ductility of I-girder with high strength steel is proposed by an unequal installation of cross beam and an optimal position of cross beam is also suggested. Finally, the effects of the unequal installation of cross beam on the flexural ductility are discussed based on the experimental results.

The Attrition and Calcination Characteristics of Domestic Limestones for In-Situ Desulfurization in Circulating Fluidized Bed Boilers (순환유동층 로내 탈황을 위한 국내 석회석의 마모 및 소성 특성)

  • Kim, Ye Bin;Kang, Seo Yeong;Seo, Su Been;Keel, Sang In;Yun, Jin Han;Lee, See Hoon
    • Korean Chemical Engineering Research
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    • v.57 no.5
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    • pp.687-694
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    • 2019
  • In order to investigate the behavior of limestones which have been usually used for in-situ desulfurization reaction in circulating fluidized bed combustors, the attrition characteristics and calcination reactions of domestic limestones were analyzed in this study by using a thermogravimetric analyzer and an ASTM D5757-95 attrition tester. The average size distribution of limestones in circulating fluidized bed boilers have to be changed due to the attrition of particle-particle and particle-reactor wall and the calcination reaction. Domestic limestones might be used in commercial circulating fluidized bed boilers, but the attrition behaviors and particle size changes of limestones were varied. In calcination experiments at $850^{\circ}C$, the calcination reaction were varied with limestone samples. The calcination reaction time increased with an increase of particle size. Also, fine particles generated the attrition test of calcined limestone was 20% higher than those generated the attrition test of original limestone.