• Journal of the Korean GEO-environmental Society
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• v.15 no.12
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• pp.15-24
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• 2014

This study was performed to investigate the removal characteristics of heavy metals in Acid Mine Drainage (AMD) using pellet-type Zeolite-StarFish ceramics (ZSF ceramics), in which natural zeolite and starfish were mixed and calcined with wood flour. Kinetic experiment showed the removal reaction of heavy metals by ZSF ceramics reached the equilibrium status within 3 hours. The optimal calcination temperature range for removal of heavy metals was measured to be $800{\sim}1,000^{\circ}C$. The calcination time had little effect on the removal of heavy metal in AMD. The adequate dose of ceramics was shown to be 1.0~1.2 % for removal of heavy metals in AMD. High removal efficiencies of heavy metals (Al, As, Cd, Cu, Fe, Mn, Zn) in AMD, more than 95 % except for Pb, were obtained under the condition of dose of ceramics more than 1.0 %. The removal efficiencies of heavy metals increased with increasing mixing concentration of wood flour. The adequate mixing concentration of wood flour was observed to be 10 %. The batch experimental results exhibited that the ZSF ceramics could act as an efficient ceramics for removal of heavy metals in AMD and the wood flour could provide porous ZSF ceramics with enhanced removal efficiency of heavy metals.

• Journal of the Korean GEO-environmental Society
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• v.8 no.3
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• pp.27-33
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• 2007

The vertical drain method recently being used in Korea is one of the popular soft ground improvement methods, and it is divided into the sand drain method, the pack drain method, the paper drain method, and the PBD method according to the drainage. However, these methods generate the disturbed zone called the smear zone when the drainage is penetrated into the in-situ ground. The characteristics of the smear zone generated cause the problems that the coefficient of permeability decreases, and then the consolidation time in the design becomes longer than expected. Even though the coefficient of horizontal consolidation and the coefficient of permeability in the smear zone are very important design factors directly influencing the degree of consolidation, in the existing studies, these coefficients have been empirically derived by the coefficient of vertical consolidation and used for the design. However, in case that these coefficients derived by the coefficient of vertical consolidation are applied to the actual design, a loss of the duration of construction and a loss of economical efficiency can be happened because of the inaccuracy of the coefficient of horizontal consolidation and the coefficient of permeability. Hence, in this study, in order to understand such influence, the laboratory test was carried out so as to reasonably determine the coefficient of permeability and the coefficient of consolidation in diverse ground conditions. Then, the range of smear effect on clay and silt was estimated with monitoring data through the laboratory test.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.9
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• pp.932-938
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• 2005

[ $TiO_2$ ] nanoparticles were prepared from the precipitation in $TiCl_4$ and the sol-gel profess in $Ti(OC_3H_7)_4$ as starting materials with various synthetic conditions. The samples were characterized by XRD, SEM, and TEM testing techniques. The photocatalytic degradation of congo red has been investigated in $TiO_2/UV$ process to evaluate photocatalytic activities for the samples. $TiO_2$ nanoparticles calcined at $400^{\circ}C$ had the best photocatalytic activity with the rate constant of the degradation of congo red as $0.0319\;min^{-1}$. The rate constant of $TiO_2$ photocatalysts was increased with the calcination temperature under $400^{\circ}C$ and decreased with the calcination temperature upper $400^{\circ}C$. In the case of $TiO_2$ photocatalysts, the photocatalytic activity wasn't greatly affected by the frequencies of usage. In the similar synthesis condition, the degradation efficiency of the $TiO_2$ particle prepared by $TiCl_4$ was increased to 8.8%, when the rate was compared with the sample prepared by $Ti(OC_3H_7)_4$. The photocatalytic activities of $TiO_2$ photocatalysts synthesized by $Ti(OC_3H_7)_4$ with various conditions were also discussed.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.4
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• pp.239-246
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• 2012

This study was performed to investigate the removal characteristics and mechanism of heavy metals using pellet-type ceramics(ZS ceramics), in which natural zeolite was mixed and calcined with converter slag. The optimal calcination temperature range was measured to be $600{\sim}800^{\circ}C$. The calcination time had little effect on the removal of heavy metal in acid wastewater. The adequate dose of ceramics was shown to be 2~5% for removal of heavy metals in acid wastewater. The maximum removal capacity of ZS ceramics for heavy metals were observed to be Al 84.7 mg/g, Cd 37.3 mg/g, Cr 81.7 mg/g, Cu 55.6 mg/g, Fe 57.2 mg/g, Mn 32.1 mg/g, Ni 38.0 mg/g, Pb 71.6 mg/g, Zn 46.3 mg/g. The pH played a pivotal role in the removal of heavy metals by ZS ceramics. The analysis results of mechanism exhibited that the ZS ceramics could act as a multi-functional ceramics for removal of heavy metals in acid wastewater by adsorption, ion-exchange, or precipitation.

• Journal of the Korean GEO-environmental Society
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• v.18 no.1
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• pp.23-29
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• 2017

This study, to provide quantitative data related to compaction characteristics, identifies the compaction characteristics of various types of soil samplers, in relation to their particle-size distribution and plasticity degree, and the compaction characteristics of artificially created granular materials, in relation to their A & D compaction. The results of the experiments show as follows. $r_{dmax}$ of clay is less than those of both sand and gravel approximately by 10%. O.M.C of clay has turned out to be greater than sand and gravel approximately by 20% and 30%, respectively. Changes in the compaction characteristics can be observed clearly around 30~60% of sand and 30~50% of passing No.200 sieve. It has also been shown that the compaction characteristics related to LL and PL are similar to each other in changes, and that the compaction characteristics become less clear with higher percent of fine grained soil. The compaction characteristics of the artificially created granular materials and field materials have appeared almost similar to each other. $r_{dmax}$ is less approximately by 30% and O.M.C greater approximately by 20% in A compaction than in D compaction. As $r_{dmax}$ and O.M.C become greater, its rate increases.

• Journal of the Korean GEO-environmental Society
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• v.8 no.4
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• pp.57-65
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• 2007

Earthquake is one of the factors to affect the stability of geotechnical structures. Numerous past earthquakes have shown that earthquakes have taught that damage of soil structures could occur on fine soils as well as coarse soils. For that reason, earthquake-induced decreasing tendency for strength on both coarse and fine soils has been investigated using direct simple shear (DSS) tests in laboratory. Based on the testing results the decreasing tendency for strength on coarse and fine soils is clearly identified in terms of the concept of volume decrease potential and plasticity index, respectively. Most of the soils except the weathered soil have shown similar reduction tendency of strength with the increasing number of cycles. Liquefaction strength of coarse and fine soils appears to decrease with the increment of volume decrease potential and the decrement of plasticity index, respectively. Reduction of strength on the weathered soil is particularly remarkable rather than others, which might be owing to the collapse phenomenon. From the DSS test results for soils, proposed is a simple method to evaluate strength decrement with the increasing number of cycles, and it can help estimate decrement of strength with the number of cycles easily.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.173-177
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• 2011

In this study, the formation of $AlPO_4$-type porous materials from alum sludge was investigated. The materials were synthesized by the reaction of aluminum hydroxide and phosphoric acid with an organic template. Cationic surfactant, natural humic acid, and amino acids were used for the organic template. The residual organic templates were removed by calcination at $600^{\circ}C$ in the air. Powder X-ray diffraction patterns showed the charicteristic patterns of the $AlPO_4$-type porous materials. The morphology of the material was examined using a scanning electron microscopy. The coordination environment of $Al^{3+}$ ion was investigated by $^{27}Al$ MAS NMR technique. Both tetrahedrally and octahedrally coordinated$Al^{3+}$ ions were found in the as-synthesized samples while all $Al^{3+}$ ions were tetrahedrally coordinated in the calcined products. The development of mesopore in the solid material was confirmed by the measurement of BET specific surface area. Finally, they were used for removal of toxic formaldehyde from the air and the formaldehyde molecules were adsorbed on the surface of pores. In conclusion, $AlPO_4$-type porous materials from alum sludge might be applicable in the removal of toxic volatile organic compounds from the air.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.3C
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• pp.149-158
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• 2010

In this study, the behavior of Pile-Bent structure with varying diameters subjected to lateral loads were evaluated by a load transfer approach. An analytical method based on the beam-column model and nonlinear load transfer curve method was proposed to consider material non-linearity (elastic, yielding) and P-${\Delta}$ effect. For an effective analysis of behavior Pile-Bent structure, the bending moment and fracture lateral load of material were evaluated. And special attention was given to lateral behavior of Pile-Bent structures depending on reinforcing effect of materials and ground conditions. Based on the parametric study, it is shown that the maximum bending moment is located within a depth (plastic hinge) approximately 1~3D (D: pile diameter) below ground surface when material non-linearity and P-${\Delta}$ effect are considered. And distribution of the lateral deflections and bending moments on a pile are highly influenced by the effect of yielding. It is also found that this method considering material yielding behavior and P-${\Delta}$ effect can be effectively used to perform the preliminary design of Pile-bent structures.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2002.05b
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• pp.273-274
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• 2002

본 연구는, 생활 하수 슬러지가 대부분인 충남 지역에서 발생되는 하수 슬러지의 물리ㆍ화학적인 성질을 기초로 하여 소각재의 안정적인 처분과 재활용을 위한 가능성을 확인하여 하수 슬러지 소각회의 적절한 처분방안과 제반 문제점 등을 제시하고, 그 문제점들의 해결방안을 모색하였다. 그 결과 하수 슬러지의 함수율은 약 80 % 정도 되며, 유기물이 고형물의 50% 정도로 관찰되었다. 그리고 비휘발성 고형물인 무기물은 $SiO_2$-$Al_2$$O_3$가 주성분으로 관찰되었으며, 주요 광물은 하수 슬러지가 소각 온도 및 소성 온도에 따라 변화하는 것으로 나타났다. 그리고, 이러한 변화는 소각재의 최종 처분시 고려되어야 하는 중요한 요인로 작용한다. 또한 하수 슬러지 소각재에 시멘트 및 첨가제의 종류, 그리고 양생 조건 등에 따라 약 100 ～ 200 kgㆍf/$\textrm{cm}^2$의 압축 강도를 가지는 것으로 조사되어, 소각에 따른 최종 부산물인 소각재의 재활용 가능성이 매우 높다는 것을 확인할 수 있었다.

• Journal of Environmental Health Sciences
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• v.30 no.5 s.81
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• pp.427-431
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• 2004

The calcination characteristics of the waste Corbicula Japonica and Ostrea virginjca shell were examined for the future use as desulfurization sorbent. The weight variation was measured according to thermal-decomposition using TGA and observed variation of the phase. The qualitative and quantitative analysis of the sample were performed using XRD and the structural analysis, SEM. The results of TGA and XRD experiments showed that the almost all of the raw samples Corbicula Japonica and Ostrea virginjca were changed from calcite to lime by firing and calcination reaction. The result of SEM experiment showed that the plate type of the raw sample was changed to circle type, so the surface area ratio was increased. Above results suggested that waste Corbicula Japonica and Ostrea virginjca were usable in the viewpoint of the reuse of resource and the decrease of environmental pollution.