• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.6
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• pp.314-319
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• 2013

Fabrication of nanocomposite material for the $Fe_2O_3-Al$ system by mechanical alloying (MA) has been investigated at room temperature. It is found that ${\alpha}-Fe/Al_2O_3$ nanocomposite powders in which $Al_2O_3$ is dispersed in ${\alpha}-Fe$ matrix are obtained by mechanical alloying of $Fe_2O_3$ with Al for 5 hours. The change in magnetization and coercivity also reflects the details of the solid state reduction process of hematite by pure metal of Al during mechanical alloying. Densification of the MA powders was performed in a spark plasma sintering (SPS) machine using graphite dies at $1000^{\circ}C$ and $1100^{\circ}C$ under 60 MPa. Shrinkage change after SPS of MA'ed sample for 5 hrs was significant above $700^{\circ}C$ and gradually increased with increasing temperature up to $1100^{\circ}C$. X-ray diffraction result shows that the average grain size of ${\alpha}-Fe$ in ${\alpha}-Fe/Al_2O_3$ nanocomposite sintered at $1100^{\circ}C$ is in the range of 180 nm. It can be also seen that the coercivity (Hc) of SPS sample sintered at $1000^{\circ}C$ is still high value of 88 Oe, suggesting that the grain growth of magnetic ${\alpha}-Fe$ phase during SPS process tend to be suppressed.

• Journal of the Korean Ceramic Society
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• v.37 no.11
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• pp.1044-1050
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• 2000

ZnO-Pr$_{6}$O$_{11}$-Co$_3$O$_4$-CaO 사성분계에 SiO$_2$를 0.4at%까지 첨가하여 1180, 1200 및 125$0^{\circ}C$에서 소성하여 미세구조 및 전기적인 특성을 조사하였다. 소성온도 120$0^{\circ}C$ 이상에서 치밀한 시편을 얻을 수 있었고, Si는 주로 입계에 분포하고 있으며, SiO$_2$첨가는 결정립성장을 억제하였다. 이 현상은 고상소결만이 일어나 120$0^{\circ}C$에서 소결된 시편과 액상소결이 일어난 125$0^{\circ}C$에서 소결된 시편 모두에서 관찰되었으며, SiO$_2$첨가에 의한 기공의 증가에 기인하는 것으로 판단된다. SiO$_2$의 첨가에 의해 바리스터의 비선형계수가 크게 변화하였으며, 시편의 소성과정이 고상소결인 경우 비선형계수가 증가한 반면 액상소결인 경우에는 감소하였다. 적절한 양의 SiO$_2$(약 0.3at%)를 첨가하여 액상이 형성되지 않는 120$0^{\circ}C$에서 소성하여 80 이상의 비선형계수를 갖는 바리스터를 제조할 수 있었다.

• 연구논문집
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• s.30
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• pp.111-119
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• 2000

Sintering of alumina powder was studied in the presence of Y-Si oxide and oxynitride additives. The main crystalline phase of the sintering aids pre-reacted at $1400^{\circ}C$ was $\alpha$ - $Y_2$$SiO_2$>$O_7$. Y-N apatite was co-existed in the Si-40N sintering aid because of its high content of N. During the sintering process, liquid phases were formed by the reaction between additives and alumina, and these liquid phases promote the densification of alumina. SEM micrographs showed that uniform grain growth occurred in the system with oxide additive(Si-0N). In the case of oxynitride additive system(Si-20N and Si-40N), bimodal microstructure was observed due to the exaggerated grain growth, As the nitrogen content in the additive system increased the exaggerated grain growth occurred extensively. Bloating, which seemed to be originated by the liberation of $N_2$ gas, occurred un the Si-40N oxynitride additive system.

• Korean Journal of Materials Research
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• v.8 no.1
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• pp.23-26
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• 1998

알루미나와 하소된 귤껍질의 소결반응에 의해 A $I_{2}$ $O_{3}$-CaO내화물이 제조되었다. 치밀화과정에서의 CaO의 영향과 A $I_{2}$ $O_{3}$-CaO 소결체의 특성을 고찰하였다. 소결체의 미세구조와 EDS 결과로 A $I_{2}$ $O_{3}$-CaO화합물을 확인하였다. 145$0^{\circ}C$에서 열처리한 소결체는 2.87/㎤의 부피비중과 12.03%의 겉보기 기공율을 가지며 압축강도는 312kg/$\textrm{cm}^2$이였다. 140$0^{\circ}C$에서 서결체의 열팽창 계수는 6.55Kx10$_{-6}$ $K_{-1}$이였다.

• Resources Recycling
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• v.9 no.2
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• pp.18-25
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• 2000

Magnetic and physical properties of sintered bodies prepare from waste sintered barium hexaferrite magnets which were come from fabrication process of isotropic permanent magnets were investigated. The properties of the sintered bodies were characterized by XRD, XRF, SEM, and BH curve tracer. After the waste permanent magnets were milled and granulated, the granules of the waste permanent magnet powders and the commercial granules were mixed with various proportions, pressed, and sintered. although the magnetic properties were decreased gradually with the content of waste magnet powder, the magnetic characteristics of the sintered magnets at $1150~1200^{\circ}C$ were comparable to those required for isotropic permanent magnets.

• Journal of the Korean Ceramic Society
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• v.25 no.6
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• pp.609-614
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• 1988

This study was carried out to investigate the effects of B4C or Y2O3 additives on the tendency of sintering, $\beta$-SiC synthesis and mineral phase changes by reaction bonding of SiC at 145$0^{\circ}C$. At the sintering temperature of 145$0^{\circ}C$, the additives such as B4C or Y2O3 did not improved porosity and bending strength. Added more than 1.5% of Y2O3, 0.5-0.3% of B4C, the formation of $\beta$-SiC was increased. At higher temperature above 145$0^{\circ}C$, it seems that the bodies added B4C, contained 3C form of SiC were denser than that of Y2O3 added. Because the transition of 3Clongrightarrow4Hlongrightarrow6H promoted sintering.

• Electrical & Electronic Materials
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• v.9 no.7
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• pp.680-689
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• 1996

SrCaCuO와 BiPbCuO 화합물로 이루어진 이중층시료가 만들어 졌으며, 소결과정에서 나타나는 확산과 입자간의 상호작용으로 108K의 임계온도를 나타내었다. 이 시료는 820.deg. C에서 0-210 시간동안 소결되었다. 초전도체의 생성, 성장메카니즘과 임계온도의 관계가 연구되었으며, 최적조건은 820.deg. C에서 210시간 소결하고 SrCaCuO와 BiPbCuO의 도포비가 1:0.6인 시편에서 나타났다. 또한 이중층시료에서 가장 좋은 조성비는 S $r_{2}$C $a_{2}$C $u_{2}$ $O_{x}$와 B $i_{1.9}$P $b_{0.5}$C $u_{3}$ $O_{y}$ 이었다.다.

• Proceedings of the International Microelectronics And Packaging Society Conference
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• 2002.11a
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• pp.109-113
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• 2002

본 연구에서는 공침법에 의한 초미세분말을 이용하여 제조된 (NiCuZn)-ferrite와 건식법을 이용하여 제조된 (NiCuZn)-ferrite의 저온소결 특성 및 전자기적 특성을 상호 비교 분석하였다. 조성은 (N $i_{0.4-x}$C $u_{x}$Z $n_{0.6}$)$_{1+w}$(F $e_2$ $O_4$/)$_{1-w}$에서 x의 값을 0.2, w의 값은 0.03으로 고정하였고, 소결은 공침법으로 합성된 분말의 경우 초기열처리과정을 거쳐 최종적으로 90$0^{\circ}C$에서, 건식법의 경우 11$50^{\circ}C$의 온도에서 진행하였다. 그 결과, 공침법으로 제조된 (NiCuZn)-ferrite는 건식법으로 제조된 (NiCuZn)-ferrite보다 20$0^{\circ}C$이상 낮은 소결온도에서 높은 소결밀도 값을 가졌으며, 품질계수 등 칩 인덕터에서 중요한 요소인 전자기적 특성이 우수하게 나타났다. 또한, 공침법으로 합성된 페라이트는 분말의 초기열처리온도에 따라 최종소결 특성이 크게 변하였다. 그밖에 공침법과 건식법으로 합성한 (NiCuZn)-ferrite의 결정성, 미세구조들을 XRD, SEM, TEM을 이용하여 비교 고찰하였다.하였다.다.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.15 no.2
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• pp.61-67
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• 2005

In this study a new growing method of silicon nitride whiskers in the inside of large pores made intentionally during the sintering was conducted. Pore size, pore vol%, and nitrogen pressure were used as experimental variables. Silicon nitride whiskers were well grown in the inside of pores with low pore vol% range from 14 to 27 but not grown with high pore vol% such as 39 and 50. On the other hand, pore size and nitrogen pressure did not have any influence on the whisker growth. Therefore the most important factor to grow silicon nitride whisker in the inside of large pores during sintering was to make pores isolated or closed.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.6
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• pp.251-256
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• 2019

In the process of ZnO ceramic sintering at a temperature of 1385℃, higher than the normal sintering temperature, some grains were growth up to mm scale. When sintered at 1400℃ for 8 hours, the size of the grains that are not involved in the abnormal growth is as large as 30~40 ㎛, but the size of the abnormal grown grain reaches 1,000 ㎛, which is more than 10,000 times bigger in volume than the normal one within 8 hr growth. As a cause of rapid and abnormal grain growth, primary particle size distribution, compaction density variation within sample and doping of impurities could be considered. The primary particle size distribution could be considered main reason for abnormal grain growth but no solid evidence was obtained. Through the observation of the microstructure, it is presumed that the giant grains grow absorbing the neighbor grains through a grain rotation process.