• Polymer(Korea)
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• v.33 no.4
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• pp.319-325
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• 2009

The solution polymerization was conducted to synthesize pressure sensitive adhesive for polarizer film using acrylic monomers. 2-Ethylhexylacrylate, butylacrylate, acrylic acid were used as acrylic monomers. The ratio was 2-ethylliexylacrylate:butylacrylate:acrylic acid=25:50:3.6 by reflecting $-40^{\circ}C$ of glass transition temperature in the pressure sensitive adhesive. When 1 wt% of coupling agent was added to the polymerized pressure sensitive adhesive, the light transmissivity was significantly increased. This result is due to the enhancement of adhesive power against liquid crystal cell by Si-O bond of coupling agents. Cross-linking agent was added by 0.5, 1.0, and 1.5 wt% with respect to the synthesized polymer. Initial tackiness decreased, while cohesion increased with increasing crosslinking agent. In the analysis of contact angle, the increase of crosslinking agents yielded the enhancement of surface energy, resulting in the decrease of contact angle. From the measurement of heat resistance, the acrylic pressure sensitive adhesive showed excellent heat resistance regardless of change in temperature and contents in crosslinking agent. In the observation of a cutting plane, the increased crosslinking agent represented a smoother and cleaner section. Comprehensively, the optimum additive amount of crosslinking agent was determined to be 1.0 wt% to monomer.

• Journal of the Korean Geotechnical Society
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• v.28 no.12
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• pp.53-64
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• 2012

In this study, the modified cyclic triaxial tests with Joomunjin standard sand are performed for dynamic deformation characteristics, such as Young's moduli and damping ratio. The cyclic triaxial test is equipped with Local Displacement Transducer (LDT) on the outside of a cell which has a range from $10^{-4}$ to $10^{-1}$ of shear strains, ${\gamma}$ (%), instead of conventional cyclic triaxial test which has linear variable displacement transducer (LVDT) with low precision. With the small strain control, tests were carried out at various loading rates, void ratios, and effective confining pressures. Based on the test results, such as dynamic deformation characteristics, shear modulus, and damping ratio, it is found that the test can measure more range of medium strains (0.02-0.2%) than results obtained from conventional test (resonant column test). For the medium strain range, dynamic deformation characteristics investigated by the cyclic triaxial test are also different from those predicted by nonlinear model in conventional test.

• Journal of the Korean Geotechnical Society
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• v.28 no.12
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• pp.41-51
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• 2012

Soils are commonly unsaturated in the near surface. The stiffness of soils is affected by the amount of air and water. The objective of this study is to evaluate the porosity of the unsaturated soils by using the elastic waves including compressional and shear waves. The elastic waves are measured at different degrees of saturation by controlling the matric suction. Thus, the unsaturated soils are characterized at different levels of the matric suction. Shear and compressional waves are measured by using the bender elements and the piezo disk elements, respectively. Both transducers are installed on the walls of the rectangular cell. The unsaturated soils are prepared by using uniform size sands and silts. Test results show that both compressional and shear wave velocities change according to the matric suction. The elastic modulus, the shear modulus, and the Poisson's ratio are estimated based on the measured elastic wave velocities. In addition, the void ratio of the unsaturated soils estimated using elastic wave velocities matches well with the volume based void ratio. This study demonstrates that the elastic waves can be effectively used for the characterization of unsaturated soils.

• Korean Chemical Engineering Research
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• v.43 no.3
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• pp.352-359
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• 2005

This work has studied the changes of pH in both of anodic and cathodic chambers of a divided cell due to the electrolytic split of water during the ammonia decomposition to nitrogen, and has studied the continuous decomposition characteristics of ammonia in a multi-cell stacked electrolyzer. The electrolytic decomposition of ammonia was much affected by the change of pH of ammonia solution which was caused by the water split reactions. The water split reaction occurred at pH of less than 8 in the anodic chamber with producing proton ions, and occurred at pH of more than 11 in the cathodic chamber with producing hydroxyl ions. The pH of the anodic chamber using an anion exchange membrane was sustained to be higher than that using a cation exchange membrane, which resulted in the higher decomposition of ammonia in the anodic chamber. By using the electrolytic characteristics of the divided cell, a continuous electrolyzer with a self-pH adjustment function was newly devised, where a portion of the ammonia solution from a pHadjustment tank was circulated through the cathodic chambers of the electrolyzer. It enhanced the pH of the ammonia solution fed from the pH-adjustment tank into the anodic chambers of the electrolyzer, which caused a higher decomposition yield of ammonia. And then, based on the electrolyzer, a salt-free ammonia decomposition process was suggested. In that process, ammonia solution could be continuously decomposed into the environmentally-harmless nitrogen gas up to 83％, when chloride ion was added into the ammonia solution.

• Korean Chemical Engineering Research
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• v.43 no.3
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• pp.425-431
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• 2005

New type of supercapacitor using high surface area activated carbons mixed with high conductivity polypyrrole (Ppy) has been prepared in order to achieve low impedance and high energy density. Mixed carbons of BP-20 and MSP-20 were used as the active electrode material, and polypyrrole doped with 2-naphthalenesulfonic acid (2-NSA) and carbon black (Super P) as conducting agents were added to activated carbons in order to enhance good electric conductivity. Electrodes prepared with the activated electrode materials and the conducting agents were added to a solution of organic binder [P(VdF-co-HFP) / NMP]. The ratio of optimum electrode composition was 78 : 17 : 5 wt.％ of (MSP20 : BP-20=1 : 1), (Super P : Ppy=10 : 7) and P(VdF-co-HFP) respectively. The performance of unit cell with addition of 7 wt％ Ppy have shown specific capacitance of 28.02 F/g, DC-ESR of $1.34{\Omega}$, AC-ESR of $0.36{\Omega}$, specific energy of 19.87 Wh/kg and specific power of 9.77 kW/kg. With addition of Ppy, quick charge-discharge of unit cell was possible because of low ESR, low charge transfer resistance and quick reaction rate. And good stability up to 500 chargedischarge cycles were retained about 80％ of their original capacity. It was concluded that the specific capacitance originated highly from compound phenomena of the pseudocapacitance by oxidation-reduction of polypyrrole and the nonfaradaic capacitance by adsorption-desorption of activated carbons.

• Journal of the Korean Electrochemical Society
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• v.2 no.4
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• pp.218-220
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• 1999

The performance of the Electric Vehicle and Hybrid Electric Vehicle depends on that of the battery pack composed of series connected batteries. And thermal property is one of the main factors which decide the performance of the battery pack. So heat generation rate from the battery under the various driving mode must be measured as precise as possible because thermal characteristics of the battery affect the driving performance and battery pack's life cycle. Besides, to design and develop the battery thermal management system for the EV and HEV, the measurements of the thermal properties of the batteries are needed. However, the established calorimeter is not adequate to test an EV's battery because its cavity is too small to accommodate the EV's battery. Therefore we developed the calorimeter to test the thermal property of the EV's battery. Its cavity size is 120mm long, 75mm wide and 200mm high. The calorimeter is calibrated by the dummy cell which generates the heat rate from zero to 200W. The measuring accuracy of the calorimeter is within $2\%$ and its voltage stability is 2.5mV in the constant temperature bath.

• Journal of the Korean Electrochemical Society
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• v.16 no.3
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• pp.162-168
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• 2013

$Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn) nano-composite is a promising cathode material for xEV application due to its high theoretic capacity. However high voltage operating system of $Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn) has worked as a hurdle in its application because of the inherent demerits, such as cycle life degradation and gas evolution. In order to enhance cell performance of $Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn)/graphite cell, we examined electrolyte mainly composed of FEC, fluroalkyl ether and $LiPF_6$ (F-based EL). F-based EL showed much better discharging retention ratio than 1.3 M $LiPF_6$ EC/EMC/DMC (3/4/3, v/v/v) (STD). Furthermore gas evolution, especially CO and $CO_2$ during $60^{\circ}C$ storage for 30 days was dramatically reduced owing to thermal stable SEI formation effect of F-based EL.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.25 no.6
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• pp.664-670
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• 2014

Generally, the properties of metamaterials are analyzed based on the infinite array of the unit cells. In real application of the metamaterial, however, the array has to be finite. Hence, it is important that a method can analyze the effect of the finite array of the metamaterial. In this paper, a model is proposed which can calculate the scattering by a large-size finite array of an I-shaped metamaterial without a full-wave simulation. The proposed model is based on the surface current estimation of each unit cells. The ratio of the current distribution on a finite array of the metamaterial to that of the infinite array of the same metamaterial for a TM polarized incident wave is approximated as a quartic polynomial. The coefficients of the polynomial are a function of the physical dimension of the metallic patch. Hence, the current distribution of the finite metamaterial can be estimated based on the proposed polynomial and the current of the infinite array. The scattered field is calculated by using the surface current model. The proposed model is numerically and experimentally verified by comparing calculated and measured RCS(Radar Cross Section) data.

• Journal of the Microelectronics and Packaging Society
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• v.23 no.3
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• pp.57-61
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• 2016

In order to protect the solar cells from the moisture and oxygen, we evaluated the electrical and optical properties for the $Cu(In,Ga)Se_2$ (CIGS) solar cells which were prepared by the spray coating method. Generally, the EVA (ethylene-vinyl acetate) films are laminated to protect the CIGS flexible solar cells, which results in a high cost process due to complicated devices. In this study, we tried to prepare the protection layers of the flexible CIGS flexible solar cells by using spray coating method instead of conventional laminating films in order to reduce the device weight as well as the process time. The CIGS solar cells with spray coating method showed an enhanced efficiency than the before treated sample (2.77% to 2.93%) and relatively proper water vapor transmission rate of the solar cells about 62.891 gm/[$m^2-day$].

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2011.10a
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• pp.431-435
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• 2011

This paper presents optimized searching technique to improve the performance of H.264/AVC. The proposed CAVLC encoder uses forward and backward searching algorithm to compute the parameters. By zero-block skipping technique and pipelined scheduling, the proposed CAVLC encoder can obtain better performance. The experimental result shows that the proposed architecture needs only 66.6 cycles on average for each $16{\times}16$ macroblock encoding. The proposed architecture improves the performance by 13.8% than that of previous designs. The proposed CAVLC encoder was implemented using VerilogHDL and synthesized with Megnachip $0.18{\mu}m$ standard cell library. The synthesis result shows that the gate count is about 15.6K with 125Mhz clock frequency.