• Journal of the Semiconductor & Display Technology
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• v.9 no.2
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• pp.49-54
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• 2010

We have successfully synthesized $CeO_2$ nanopowders by means of the hydrothermal method, in a low temperature range of $100-200^{\circ}C$. In order to investigate the structure and morphology of the nanopowders, scanning electron microscopy and X-ray diffraction have been employed. In addition, for exploring the optical properties, Raman spectroscopy, Fourier transform infrared spectroscopy, and photoluminescence spectroscopy have been used. In the optimized condition, with the pH, velocity, and time of 4.5, 600 rpm, and 60 h, the $CeO_2$ nanopowders with a diameter ranging from 50 to 150 nm have been synthesized. The nanopowders exhibited the visible emission mainly in the blue region. With comparing the reaction time, it is revealed that the extinction of functional groups at 60 h contributed to the growth and homogenization of the $CeO_2$ powders. Since the overgrowth and agglomeration of nanopowders were found, we suggest that the cracking/growth process is more favorable mechanism than the dissolution/precipitation process.

• Journal of the Semiconductor & Display Technology
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• v.17 no.4
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• pp.11-15
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• 2018

The parts of equipment for semiconductor are protected by anodic aluminum oxide film to prevent corrosion. This study investigated contamination particle and cracking behavior of anodic oxidation in sulfuric acid containing cerium salt. The insulating properties of the sample were evaluated by measuring the breakdown voltage. It was confirmed that the breakdown voltage was about 50% higher when the cerium salt was added, and that the breakdown voltage after the heat treatment was 55% and 35% higher at $300^{\circ}C$ and $400^{\circ}C$, respectively. After heating at $300^{\circ}C$ and $400^{\circ}C$, cracks were observed in non cerium and cerium 3mM, and more cracks occur at $400^{\circ}C$ than at $30^{\circ}C$. The amount of contamination particles generated in the plasma is about 45% less than that of non-cerium specimens.

• Mineral and Industry
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• v.27
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• pp.8-15
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• 2014

In this study, a proposal for revision of HSK Code was established on legally designated minerals and national stockpile minerals. It is difficult to exactly identify trade balances of minerals, such as lithium ore, rare earth ore, serpentine, kidney stone in legally designated minerals and ingot of indium, ferro-tungsten, ingot of antimony, granule of selenium, gallium, lanthanum oxide, cerium carbonate in national stockpile minerals because HSK Codes of them were not allocated separately. Furthermore, specific use, standard, component, type of products cannot be exactly identified in current HSK Code system. Therefore, it is makes rule to separately manage minerals which were managed by government such as legally designated minerals and national stockpile minerals. However, a proposal for revision of HSK Code system was established to comply with international standard(HS Code) and the items over a certain size(amounts : over 50 mil.$, volumes : over 5000 ton) were selected as revised subjects. Moreover hierarchies between HSK Codes were considered.

• Particle and aerosol research
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• v.12 no.2
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• pp.37-42
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• 2016

$CeO_2$ nanoparticles were prepared by a flame spray pyrolysis from aqueous solution of cerium nitrate. The morphology, structure crystallinity and specific surface area of as-prepared nanoparticles were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and Brunauer-Emmett-Telle (BET). The $CeO_2$ nanoparticles about 5 nm in diameter showed a cubic fluorite structure and polyhedral morphology. The average particle size increased as the cerium nitrate concentration increased. UV absorption performance of the as-prepared nanoparticles was measured by UV-visible spectroscopy. UV absorption of $CeO_2$ nanoparticles was more effective than that of commercial $TiO_2$ nanoparticles. Effect of dopants such as Ti and Zn to $CeO_2$ nanoparticles on UV absorption properties was also investigated. In case of $Ti/CeO_2$, and $Zn/CeO_2$ nanoparticles, they showed a little higher UV absorption values compared with $CeO_2$ nanoparticles. The as-prepared nanoparticles can be promising materials with high UV absorption value.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.155-155
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• 2011

신재생에너지 수요가 확대됨에 따라 신재생에너지 관련 제품에 소요되는 물질에 대한 관심이 확대되고 있다. 이들 물질은 공급리스크가 존재하는 희유금속이 주를 이루고 있다. 본 연구에서는 신재생에너지 등의 high tech 기술 확대로 인한 희유금속의 수요 및 공급을 전망하고 있는 미국의 critical raw material 관리 전략을 살펴보고자 한다. 미국은 2010년 12월 미국 에너지성(DOE : Department of Energy)에서 위기 물질 전략(Critical Materials Strategy)에 관한 리포트를 공표하였다. 클린 에너지 기술 4개 분야(영구자석, 선진 전지, 태양전지 박막, 형광 물질)에서 핵심이 되는 물질(희유금속 등)의 수급 불균형이 일어날 가능성에 대해 조사를 실시하여 리스크 평가하여 단기, 중단기로 구분하여 위기물질을 선정하였다. 클린 에너지 기술 4개 분야에서 핵심이 되는 물질(네오디움, 디스프로슘, 코발트, 리튬, 랜턴, 세륨, 테룰, 인듐, 갈륨, 유로피움, 테르비움, 이트륨)의 12광종 수급을 2025년까지 전망한 결과 전체적으로 단기(2010년~2015년)보다 중기(2015년~2025년)에 공급 부족이 확대한다고 예측되었다. 단기적으로는 인듐이 약간 부족하는 것 외에 디스프로슘과 이트륨에 관해서도 공급 부족할 것으로 예측되었다. 중기적으로는 코발트(전지 기술에 사용)와 유로피움(고효율 조명용의 형광 물질에 사용) 외 대상이 된 다른 모든 물질은 공급 부족이 발생할 것으로 전망되었다. 이를 종합하여 단기적으로는 디스프리슘, 유로피움, 인듐, 테르븀, 네오디움, 이트륨 등이, 중기적으로는 디스프리슘, 유로피움, 테르븀, 네오디움, 이트륨 등이 위기물질(Critical Material)로 분석되었다. 에너지성은 위기물질을 공급원다각화, 대체물질개발, 리유즈, 리사이클링 등을 국제적 파트너와 함께 추진하여 리스크를 관리할 것이며, 2011년까지 최신정보를 구축하여 위기물질 전략을 재설정할 예정이다. 체계적인 위기물질 선정 및 관리전략 등을 참조하고, 신재생에너지기술 변화에 따른 원재료의 중요성 및 리스크 관리현황을 기초로 우리나라에 적합한 위기관리 물질 선정 및 관리가 필요할 것이다.

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.1
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• pp.32-39
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• 2007

CO oxidation and selective CO oxidation of $La_xCe_{1-x}Co_yCu_{1-y}O_{3-{\alpha}}$ perovskite(x=1, 0.9, 0.7. 0.5; y=1, 0.9, 0.7, 0.5) were investigated. For CO oxidation, catalytic activities were studied according to different preparation conditions such as pH and calcination temperature. The influence of the change of the $O_2$ concentration for selective CO oxidation was studied, too. The substitution of Ce for La improved the catalytic activity for CO oxidation and selective CO oxidation and best activity was observed for $La_{0.7}Ce_{0.3}CoO_3$ prepared at pH 11 and calcined at $600^{\circ}C$. The temperature of 90% CO conversion for CO oxidation using $La_{0.7}Ce_{0.3}CoO_3$ was $230^{\circ}C$. In contrast to the enhancement effect by Ce substitution, the partial substitution of Cu for Co in $LaCo_yCu_{1-y}O_{3-{\alpha}}$ decreased catalytic activities for CO oxidation reaction compared to that using $LaCoO_3$. For selective CO oxidation, the best CO conversion was 66% at $230^{\circ}C$ for $La_{0.7}Ce_{0.3}CoO_3$. The CO conversion of $La_{0.7}Ce_{0.3}CoO_3$ was greatly increased from 66% to 91% as increasing $O_2$ concentration from 1% to 2%.

• Journal of the Korean Solar Energy Society
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• v.33 no.2
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• pp.93-100
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• 2013

Two-step thermochemical cycle using ferrite-oxide($Fe_2O_4$) device was investigated. The $H_2O$(g) was converted into $H_2$ in the first experiment which was performed using a dish type solar thermal system. However the experiment was lasted only for 2 cycles because the metal oxide device was sintered and broken down. Another problem was that the reaction was taken place mainly on a side of the metal oxide device. The m-$ZrO_2$, which was widely known as a material preventing sintering, was applied on the metal oxide device. The ferrite loading rate and the thickness of the metal oxide device were increased from 10.67wt% to 20wt% and from 10mm to 15mm, respectively. The chemical reactor having two inlets was designed in order to supply the reactants uniformly to the metal oxide device. The second-experiment was lasted for 5 cycles, which was for 6 hours. The total amount of the $H_2$ production was 861.30ml. And cerium oxide($CeO_2$) device was used for increasing $H_2$ production rate. $CeO_2$ device had low thermal resistance, however, more $H_2$ production rate than $Fe_2O_4$ device.

• Journal of the Korean Chemical Society
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• v.20 no.4
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• pp.309-315
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• 1976

An efficient separation method and the utilization of sericin are searched. Sericin was extracted with hot water from cocoons under atmospheric pressure. The separated sericin was gel-filtrated with Sephadex G-75 and G-150 at room temperature and at $70^{\circ}C$. The results indicated that sericin is consisted of only one fraction in elution diagram. In the graft copolymerization of acrylonitrile to sericin ceric ammonium nitrate was chosen as an initiatior. A maximum yield was obtained at certain concentration of the initiator confirming our previous experiments. Viscosity measurement of alkali-hydrolyzed graft copolymers indicated that the polyacrylonitrile graft had the molecular weight in the range of 7,000.

• Membrane Journal
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• v.15 no.3
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• pp.198-205
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• 2005

Double-layered polymer films to assay the radioactive contamination were formulated using polysulfone (PSF) and cerium activated yttrium silicate (CAYS), consisting of a dense support layer and a CAYS-holding top layer prepared via the diffusion-induced phase inversion. As the vapor exposure process was omitted, the CAYS-holding layer showed a typical asymmetric structure, with CAYS being transfixed into the polymer network spread with large macropores. With the increase in vapor exposure time before immersion, morphology of the films transformed from asymmetric to sponge-like structures, with CAYS being localized in cellular structure. The border structure between the two layers reflects the phase inversion behavior of a cast solution during the coagulation. In the radioactive detection, the polymer phase in a film holding a sponge-like structure is so dense that the radionuclides, deposited on the film, could not filter through the phase, consequently resulting in the loss in the detection efficiency of the film.

• Korean Journal of Materials Research
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• v.30 no.5
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• pp.267-271
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• 2020

Cerium oxide (ceria, CeO₂) is one of the most wide-spread oxide supporting materials for the precious metal nanoparticle class of heterogeneous catalysts. Because ceria can store and release oxygen ions, it is an essential catalytic component for various oxidation reactions such as CO oxidation (2CO + O₂ 2CO₂). Moreover, reduced ceria is known to be reactive for water activation, which is a critical step for activation of water-gas shift reaction (CO + H₂O → H₂ + CO₂). Here, we apply van der Waals-corrected density functional theory (DFT) calculations combined with U correction to study the mechanism of water chemisorption on CeO₂(111) surfaces. A stoichiometric CeO₂(111) and a defected CeO₂(111) surface showed different water adsorption chemistry, suggesting that defected CeO₂ surfaces with oxygen vacancies are responsible for water binding and activation. An appropriate level of water-ceria chemisorption energy is deduced by vdW-corrected non-local correlation coupled with the optB86b exchange functional, whereas the conventional PBE functional describes weaker water-ceria interactions, which are insufficient to stabilize (chemisorb) water on the ceria surfaces.