• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.7
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• pp.1664-1673
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• 1994

As a fundamental study on effects of thermal-cycles on residual stress of ceramics/metal joints, residual stresses in $Si_3N_4$/SUS304 joint specimens were measured before and single thermal-cycle by X-ray diffraction method and finite element method(FEM). The residual stress was found to increase after single thermal-cycle, which was agreeable with the results of residual stress measurement by X-ray diffraction method and residual stress analysis by finite element method. After the residual stress measurement, 4-point bending tests were performed. The relationship between the bending strength, the thermal-cycle temperature and hold time was examined. The bending strength was found to decrease with the increase of residual stress in linear relation.

• Journal of Welding and Joining
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• v.32 no.1
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• pp.40-46
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• 2014

Bonding technology and bonding mechanism of metal to ceramic including brazing, diffusion bonding, friction welding and etc were reviewed in this study. Various factors should be considered from a bonding design step to acquire a good bonding joint because of a large difference between metal and ceramic in crystal lattice, coefficient of thermal expansion and various properties. In addition, metal and ceramic bonding technologies are constantly being developed according to precise components, multi-function and application to harsh environment. However, improvement of bonding properties and bonding reliability also should be accompanied. Bonding of ceramics, such as $ZrO_2$, $Ti_3AlC_2$ and SiC, to metals like Ti-alloy, TiAl and steel were described in this paper.

• Journal of the Korean Ceramic Society
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• v.16 no.3
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• pp.169-177
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• 1979

The effect of apparent porosity of the fired ceramics, metallizing temperature, and metallizing mixtures on the bond strength in metal-to-ceramic seals was investigated. Three different metallizing compounds were metallized on dense alumina bodies at 1300~$1500^{\circ}C$ in dry hydrogen atmosphere. Bond strength between metal and alumina body was measured by means of nstron test machine. The greater bond strength was observed as the apparent porosity and metallizing temperature was increased. This work indicated that the glassy phase in metallizing mixture, having had sufficient fluidity to migrate into the alumina body, reacted with alumina and thereby forming strong metal-ceramic interface bond. It also showed that the glassy phase having higher thermal expansion cofficient than molybdenum might contribute to the strong bond formation by providing compressive stress around the molybdenum particle.

• Proceedings of the Materials Research Society of Korea Conference
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• 2008.05a
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• pp.42.1-42.1
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• 2008

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.524-524
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• 2012

Thermal Barrier Coating (TBC)은 미사일, 로켓발사체와 같이 고온에 노출되는 장비를 열로부터 보호하기 위한 코팅이다. 일반적인 Thermal Barrier Coating (TBC)은 모재와 코팅층간의 낮은 접합력과 높은 열충격으로 인한 박리가 많이 나타난다. 그래서 접합력을 높이고, 열충격을 줄이기 위해 모재와 코팅층 사이에 본드코팅층을 만든 Duplex - Thermal Barrier Coating (Duplex-TBC)이 개발되었다. 그러나 Duplex - Thermal Barrier Coating (Duplex-TBC)은 금속재료인 본드코팅층과 세라믹재료인 탑코팅층 사이에서 박리가 많이 발생한다. 이러한 문제점을 해결하기 위해 두 가지 분말을 동시에 코팅하여 본드코팅과 탑코팅의 경계가 없는 Functional Gradient Material - Thermal Barrier Coating (FGM-TBC)의 연구가 필요하다. 본 연구에서는 Functional Gradient Material - Thermal Barrier Coating (FGM-TBC)의 열충격 특성에 미치는 진공 플라즈마 용사 조건의 영향을 조사하였다. Functional Gradient Material - Thermal Barrier Coating (FGM-TBC)는 진공 플라즈마 용사장치를 사용하여 Cu-Cr 합금위에 코팅하였다. 거리, Carrier gas flow, 그리고 챔버 내부의 압력을 달리하여 제조하였다. 사용한 분말은 본드코팅용으로 Amdry 962와 내열 세라믹코팅을 위해 204NS를 사용하였고, 각각 분말 공급조건을 조절하여 두 분말의 비율을 달리하였다. 제조한 Functional Gradient Material - Thermal Barrier Coating (FGM-TBC) 코팅은 전기로에서 50분간 가열한 후, 수조에서 10분간 냉각하는 열충격 실험을 통해 열차폐 성능을 평가 하였다. 이러한 과정에서 진공 플라즈마 용사 조건 및 FGM 조성과 비율이 내열충격 특성에 미치는 영향을 미세조직학적 관점에서 고찰하였다.

• Journal of Welding and Joining
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• v.14 no.2
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• pp.19-27
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• 1996

재료의 표면개질은 표면층의 조직변화에 대한 개질법과 표면피복에 의한 개질 법으로 나눌 수 있다. 조직변화에 의한 개질법으로는 침탄, 질화, 이온주입 및 금속 확산 등이 있고, 표면피복에 의한 개질법으로는 도장, 도금, 육성용접, 물리증착(PVD) 및 화학증착(CVD) 등이 있는데, 용사법은 표면피복에 의한 개질법에 속한다. 용사기술 은 비교적 최근에 발달된 표면피복 기술로서 그림1과 같이 플라즈마, 가스화염 또는 아크열원을 이용하여 금속 또는 비금속 재료를 용융 혹은 반용융 상태로 모재에 고속 도로 분사하여 충돌 적층시켜 피복하는 공정으로 다른 표면개질기술에 비해서 여러 가지 잇점을 가지고 있다. 이것은 거의 모든 재질의 모재(금속, 세라믹, 유기재료 등) 에 대해 피막의 형성이 가능하고, 용사재료의 종류도 다양하다(금속, 합금, 각종 세라 믹, 플라스틱, 각종 복합재료 등). 또한 노재크기의 제한이 없고, 대형의 재료에 대해 서 한정된 부위의 피복이 가능하며, 모재의 열영향이 적고, 피막의 형성속도가 다른 피막법에 비해 빠른 장점을 가지고 있다. 그 예로 알루미나(Al$_{2}$O$_{3}$)를 피복할 경우 화학증착(CVD)법에 의해서는 피막형성 속도가 약 2 * $10^{-4}$mm/min 인데 비해 용사법에 의해서는 약 7.5 * $10^{-1}$mm/min로 매우크다. 이와같은 많은 장점을 갖고있는 용사법을 이용한 표면개질에 대해 본 기술보고에서 서술하고자 한다.

• Proceedings of the KSME Conference
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• 2000.04a
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• pp.121-126
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• 2000

Metal/Ceramic structures have many attractive properties, with great potential for applications that demand high stiffness, as well as chemical and biological stability, thermal and electrical insulation. They are currently in use for mechanical and thermal protection in cutting tool and engine parts. With all their great advantage, ceramics suffer from one major problem they are brittle, and are especially susceptible to cracking from surface contacts. Delamination at the interfaces with adjacent layers is a particularly disturbing problem, and can cause premature failure of a composite system. so determination of adhesive properties of coating is one of the most important problems for the extension of the use of coated materials. In this work, mechanical characteristics of Interface of ceramic/Metal composites are evaluated by means of hardness test, indentation test apparent interfacial toughness and bonding strength test. The interface indentation test provides a relation between the applied load(P) and the length of the crack(a) created at the interface between the coating and the substrate.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 1998.10a
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• pp.248-253
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• 1998

Recently, the uses of Ceramic/metal bonded joints, resin/metal joints, adhesive joints, composite materials which are composed of dissimiliar materials have increased in various industry fields. Since the ceramic/metal bonded joints material is made at a high temperature, residual stress distributions due to differences in material properties were investigated by varying material parameters. The two dimensional finite element analysis was performed to study residual stress distribution in Si3N4/SM45C bonded joint with a copper interlayer between the silicon nitride(Si3N4) and the structural carbon steel(SM45C) and 4-point bending tests were carried out under room temperature. Fracture surface and crack propagation path were observed using scanning electron microscope and characteristics of its fracture was discussed.

• Journal of Welding and Joining
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• v.23 no.2
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• pp.59-65
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• 2005

A leaky surface acoustic wave (LSAW) velocity was measured using a scanning acoustic microscope on the ceramic/metal interface in order to investigate material properties. The inverse Fourier transform (IFFT) of the V(z) curve contains the reflectance function of a liquid-specimen interface. So, the longitudinal, transverse, and Rayleigh wave velocities for each layer are obtained by the inversion of the V(z) curve at the same time. This paper contains mainly the experimental procedure for measurements of the LSAW velocity, and the results obtained for the velocity variation of individual layer after the thermal shock. It is shown that this method is useful in measuring the material properties under external stress.

• Journal of the Korean Ceramic Society
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• v.15 no.2
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• pp.89-97
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• 1978

The basic mechanism of adherence in sintered high purity alumina ceramic-to-metal bonding was studied. Emphasis was placed on flux composition, porosity of the fired ceramics, and metallizing mixtures. The study was conducted on 95 and 99.5% alumina, using molydbenum-manganese, molybdenum-manganese-silicon dioxide metallizing compositions. Metallizing was performed in wet hydrogen (dew point, ＋17$^{\circ}C$) at 145$0^{\circ}C$ for 45min. This experiment indicated that adhernece mechanism of ultra high purity alumina ceramic was attributed to formation of $MnAl_2O_$4, and in the case of 95% alumina containing glass, the migration of glass from the interface into the void of the metal coating was the main role to the adhrence. It showed also that greater the bond-strength was resulted as porosity was increased.