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Analysis on Thermal Effects of Process Channel Geometry for Microchannel Fischer-Tropsch Reactor Using Computational Fluid Dynamics (전산유체역학을 이용한 Fischer-Tropsch 마이크로채널 반응기 반응채널구조에 따른 열적 효과 분석)

  • Lee, Yongkyu;Jung, Ikhwan;Na, Jonggeol;Park, Seongho;Kshetrimayum, Krishnadash S.;Han, Chonghun
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.818-823
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    • 2015
  • In this study, FT reaction in a microchannel was simulated using computational fluid dynamics(CFD), and sensitivity analyses conducted to see effects of channel geometry variables, namely, process channel width, height, gap between process channel and cooling channel, and gap between process channels on the channel temperature profile. Microchannel reactor considered in the study is composed of five reaction channels with height and width ranging from 0.5 mm to 5.0 mm. Cooling surfaces is assumed to be in isothermal condition to account for the heat exchange between the surface and process channels. A gas mixture of $H_2$ and CO($H_2/CO$ molar ratio = 2) is used as a reactant and operating conditions are the following: GHSV(gas hourly space velocity) = $10000h^{-1}$, pressure = 20 bar, and temperature = 483 K. From the simulation study, it was confirmed that heat removal in an FT microchannel reactor is affected channel geometry variables. Of the channel geometry variables considered, channel height and width have significant effect on the channel temperature profile. However, gap between cooling surface and process channel, and gap between process channels have little effect. Maximum temperature in the reaction channel was found to be proportional to channel height, and not affected by the width over a particular channel width size. Therefore, microchannels with smaller channel height(about less than 2 mm) and bigger channel width (about more than 4 mm), can be attractive design for better heat removal and higher production.

Dependance of hot-zone position on AlN single crystal growth by PVT method (PVT법에 의한 AlN 단결정 성장에서 Hot-Zone 의존성)

  • Yin, Gyong-Phil;Kang, Seung-Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.2
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    • pp.84-88
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    • 2016
  • AlN single crystals were grown by the PT (Physical vapor transport) method with position-changable induction coil. And the graphite crucible dimensioned ${\Phi}90{\times}H120$ was used on processing. The temperature was $1950{\sim}2050^{\circ}C$ and ambient pressure was 150~1 Torr. And the hot-zone was changed according to times on growing for result comparison. When hot-zone by coil is located below far enough (> 40 mm) from AlN crystal concentration position, the as-grown crystals physical size is better ($300{\mu}m/hr$) than another condition, but the condition-reproducibility was very poor. However the closer the distance between hot-zone and AlN growing posion, the smaller the size of as-grown crystal and the rarer the generation of the crystal nuclear, but the crystal growing condition is stable for quality. The best condition for both growth rate and quality is gained when the starting position of hot-zone coil is about 20 mm distance from growing position. For the best growth condition, the position of hot-zone is very sensitive factor and the further more the condition of speed of coil shift also must control.

Entrepreneurial intentions for University students Based on Theory of Planned Behaviors (대학생들의 경력개발과 관련된 계획된 행동들이 창업실행에 미치는 영향)

  • Han, Junghee;Cho, Geon
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.10 no.1
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    • pp.111-118
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    • 2015
  • Students have chosen the various behaviors to prepare for the future during the university life. In general to be employed by someone and to create one's own business is likely to be regarded as difference ways. The objectives of this study is to find that whether student's planned behaviors such as albeit, internship, getting some certification are to be related with entrepreneurial intention, and entrepreneurial intention has positive relation with entrepreneurial decision makings based on theory of Planned behaviors through empirical study. In order for that, this study sets four research hypothesis. In the empirical findings, 3 research hypothesis except H2 (subjective norms have positive relations with entrepreneurial intention) are accepted in statistically. Considering research findings, students' planned behaviors, such as albeit, internship, getting some certifications to have been regards as far away from entrepreneurship have positive relation with entrepreneurial intention and implementation. Entrepreneurship education and knowledge regarding start-ups given by Universities or private institutions should provide information to create imagination new venture business with spontaneity instead of giving intented contents concerning entrepreneurship when taking into consideration of result of hypothesis 2. In order words, entrepreneurship education to provide the self-efficacy is the right track for students.

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Development of Cylindrical Paperpot Manufacturing Equipment (원통형 종이포트 제조장치 개발)

  • Park, Minjung;Lee, Siyoung;Kang, Donghyeon;Kim, Jongkoo;Son, Jinkwan;Yoon, Sung-wook;An, Sewoong
    • Journal of Bio-Environment Control
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    • v.26 no.4
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    • pp.242-248
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    • 2017
  • This study was conducted to develop a cylindrical paperpot manufacturing equipment which is capable of continuously producing paperpots with a constant size. The equipment consists of the soil supply part, the paper supply part, the pot manufacturing part, the paperpot cutting part and its process for manufacturing paperpot from the soil supply to the paperpot cutting is continuously performed. As a result of the performance test using this equipment, we suggest that the optimal moisture content and injection pressure to supply soil are 50%~60%, and 0.5 Mpa respectively. Moreover the appropriate temperature for adhesive strength is $150{\sim}160^{\circ}C$ taking into account the performance of device and adhesion time. Also, considering the cutting speed and safety, it is appropriate to adopt a straight blade having a clean plan at a minimum angle of $30^{\circ}$. In addition, the manufacturing capacity of the developed equipment was 3300 pots per hour.

Gastroesophageal Reflux in Mechanically Ventilated Preterm Infants (기계적 환기 요법이 미숙아 위식도 역류에 미치는 영향)

  • Ku, Hye Jin;Park, Su Eun;Park, Jae Hong
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.7 no.1
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    • pp.48-53
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    • 2004
  • Purpose: Besides interferencence of esophageal motor function by the nasogastric tube, a decline of the positive gastro-esophageal pressure gradient caused by intermittent positive pressure ventilation seems to have a major role in the pathogenesis of gastroesophageal reflux (GER) in mechanically ventilated preterm infants. The aim of this study was to determine the incidence of GER and associated risk factors in mechanically ventilated preterm infants. Methods: Twenty four hour esophageal pH monitorings were performed using a antimony electrode on 11 mechanically ventilated preterm infants in Neonatal Intensive Care Unit in Pusan National University Hospital. We evaluated the following reflux parameters; reflux index, reflux episodes/hour, reflux episodes ${\geq}5min/hour$, duration of longest episode, and percent episodes ${\geq}5min$. Patients were considered to have significant GER if more than 2 among 5 parameters were satisfied. Results: The mean gestational age of the patients was 30.9 weeks, mean birth weight was 1,568 g, and mean age at the time of pH monitoring was 2.8 days. Significant GER was detected in 4 patients (36.4%). There was no relationship between the incidence of GER and gestational age, birth weight, postnatal age, or the ventilator settings. Conclusion: The incidence of GER in mechanically ventilated preterm infants was similar, compared with other previous studies. Associated risk factors of GER in these patients were not detected. Therefore, mechanical ventilation in preterm infants does not seem to be the high risk factor of GER.

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Experimental Study on Fire Resistance Performance of CFT (Concrete filled Tube) Column according to Cross Section of Steel, Concrete Compressive Strengths and Load Ratios (강관의 크기, 축력비 및 콘크리트 압축강도 변화에 따른 CFT 기둥부재의 내화성능에 관한 실험적 연구)

  • Cho, Kyung-Suk;Kim, Heung-Youl;Kim, Hyung-Jun;Min, Byung-Yeol;Kwon, In-Kyu
    • Fire Science and Engineering
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    • v.24 no.6
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    • pp.104-111
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    • 2010
  • The strength of steel in a concrete filled steel tube (CFT) is reduced in a fire, but the concrete filled structurally ensures the fire resistance due to its high thermal capacity. This research analyzed the fire resistance performance due to the variances of concrete strength filled inside of steel tube and the load ratios, which can influence on the fire resistance of CFT. As $280{\times}280{\times}6$ CFT columns with the concrete strengths of 24 MPa and 40 MPa and the axial load ratios of 0.9, 0.6, and 0.2 in accordance with KS F 2257-1 and 7 were heated with loading to examine the fire resistance performance, the fire resistance used to 24 MPa concrete showed 27, 113, and 180 minutes according to the axial load ratios, 0.9, 0.6, and 0.2 respectively. In case of 40 MPa concrete, the fire resistance were turned out to be 19 and 28 minutes for the axial load ratios, 0.9 and 0.6 respectively. The results of fire resistance with 40 MPa concrete showed the much lower fire resistance performance than those of 24 MPa concrete. In case of 40 MPa, the fire resistance performance was not increased significantly according to the axial load ratio than that of 24 MPa. The main reason why the higher concrete strength showed lower fire resistance than that of lower guessed the internal stress had the concrete strength weak.

Status of Damage and Restoration Planning of Forest Trail in Choansan(Mt.) Neighborhood Park, Seoul, South Korea (초안산근린공원 숲길 훼손 실태 및 복원방안 연구)

  • Han, Bong-Ho;Ki, Kyong-Seok;Noh, Tai-Hwan
    • Korean Journal of Environment and Ecology
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    • v.26 no.6
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    • pp.923-933
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    • 2012
  • The purpose of this study targeting Choansan(Mt.) Neighborhood Park in Seoul of South Korea, whose level of visitation and use pressure has been recently increasingly high, was to understand distribution and damage status of forest trail and accordingly, set up direction of how to improve forest trail in urban area. With regards to current damage on forest trail in Choansan(Mt.) Neighborhood Park, the damaged trail with road width of over 2m and with erosion depth of over 30cm amounted to 20.3% and 36.3% respectively. And the trail section with bare land erosion, root exposure or rock exposure and the section whose impact rating class exceeded IV occupied 47.0% and 70.6%, indicating the forest trail was severely damaged. The severely injured trail route mainly included the main forest trail formed along the main ridge, the byroad connected to the main forest trail and the steep forest trail in low-lying area. Based on the study results, five types of restoration of forest trail in Choansan(Mt.) Neighborhood Park were offered, including prevention of forest trail extension, stabilization of forest trail base, maintenance of forest trail surface, vegetation restoration after closing forest trail and maintenance. Ecological restoration was additionally offered. The prevention of forest trail extension was planned to prevent expanded width of forest trail where bare land was exposed. The stabilization of forest trail base was planned to prevent erosion in the forest trail and exposure of roots. The maintenance of forest trail surface was planned in a way to protect the severely damaged forest trail surface by using wood deck and wood stairs and surfacing the road.

An Experimental Study on Pumpability Characteristics of High Strength Concrete Mixed Polymix (폴리믹스 혼입 고강도 콘크리트의 펌프압송 성상에 관한 실험적 연구)

  • Lee, Joo-Ho;Moon, Hyung-Jae;Kim, Jeong-Jin
    • Journal of the Korea Concrete Institute
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    • v.24 no.5
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    • pp.509-516
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    • 2012
  • The aims of this research is to develop a fire resistant admixture to enhance high-pressured pumping of high-strength concrete (HSC) with a compressive strength of 60~80 MPa. Generally, the efficiency of HSC high-pressured pumping is dramatically reduced due to entanglement of short fibers added to prevent fire spalling. Therefore, the fire resistant admixture that can facilitate pumping of fire resistant HSC is urgently needed presently. The fire resistant HSC mix is comprised of Polypropylene fiber, Nylon fiber and Polymer powder. The test results showed that the slump-flow was improved by approximately 70% of the HSC without fire resistant admixture. However, the air void content was increased slightly due to the addition. The standard design compressive strength at 28-days was satisfied, while its flexural strength was similar to the concrete without the admixture. Since the flexural strength was 12~15% of its compressive strength, the general trend of flexural to compressive strength ratio in normal concrete was maintained. Even though its elastic modulus was decreased by adding the admixture, the study results showed that the concrete can be used for construction since all of the test results exceeded the code requirements.

Estimation on Discharge Capacity of Prefabricated Vortical Drains Considering Influence Factors (영향인자를 고려한 연직배수재의 통수능 평가)

  • Shin Eun-Chul;Park Jeong-Jun;Kim Jong-In
    • Journal of the Korean Geotechnical Society
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    • v.21 no.9
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    • pp.13-23
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    • 2005
  • The prefabricated vertical drains (PVDs) are one of the most widely used techniques to accelerate the consolidation of soft clay deposits and dredged soil. Discharge capacity is one of the factors affecting the behavior of PVDs. In the field, a PVD is confined by clay or dredged soil, which is normally remolded during PVD installation. Under field conditions, soil particles may enter the PVD drainage channels, and the consolidation settlement of the improved subsoil may cause 131ding of the PVD. These factors will affect the discharge capacity of the PVDs. In this study an experimental study was carried out to estimate the discharge capacity of three different types of PVDs by utilizing the large-scale laboratory model testing and small-scale laboratory model testing equipments. The several factors such as confinement condition (confined by soft marine clay or dredged soil) and variations of the discharge capacity were studied with time under soil specimen confinement, The test results indicated that discharge capacity decreases with increasing load, time, and hydraulic gradient. With load application, the cross-sectional area of the drainage channel of PVD decreases because the filter of PVD is pressed into the core. The discharge capacity of the soft marine clay-confined PVDs is much lower than that of the dredged soil-confined PVDs.

PECVD를 이용한 2차원 이황화몰리브데넘 박막의 저온합성법 개발

  • Kim, Hyeong-U;An, Chi-Seong;Arabale, Girish;Lee, Chang-Gu;Kim, Tae-Seong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.274-274
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    • 2014
  • 금속칼코게나이드 화합물중 하나인 $MoS_2$는 초저 마찰계수의 금속성 윤활제로 널리 사용되고 있으며 흑연과 비슷한 판상 구조를 지니고 있어 기계적 박리법을 통한 그래핀의 발견 이후 2차원 박막 합성법에 대한 활발한 연구가 진행되고 있다. 최근 다양한 응용이 진행 중인 그래핀의 경우 높은 전자이동도, 기계적 강도, 유연성, 열전도도 등 뛰어난 물리적 특성을 지니고 있으나 zero-bandgap으로 인한 낮은 on/off ratio는 thin film transistor (TFT), 논리회로(logic circuit) 등 반도체 소자 응용에 한계가 있다. 하지만 $MoS_2$는 벌크상태에서 약 1.2 eV의 indirect band-gap을 지닌 반면 단일층의 경우 1.8 eV의 direct-bandgap을 나타내고 있다. 또한 단일층 $MoS_2$를 이용하여 $HfO_2/MoS_2/SiO_2$ 구조의 트랜지스터를 제작하였을 때 $200cm^2/v^{-1}s^{-1}$의 높은 mobility와 $10^8$ 이상의 on/off ratio 나타낸다는 연구가 보고되어 있어 박막형 트랜지스터 응용을 위한 신소재로 주목을 받고 있다. 한편 2차원 $MoS_2$ 박막을 합성하기 위한 대표적인 방법인 기계적 박리법의 경우 고품질의 단일층 $MoS_2$ 성장이 가능하지만 대면적 합성에 한계를 지니고 있으며 화학기상증착법(CVD)의 경우 공정 gas의 분해를 위한 높은 온도가 요구되므로 박막형 투명 트랜지스터 응용을 위한 플라스틱 기판으로의 in-situ 성장이 어렵기 때문에 이를 보완할 수 있는 $MoS_2$ 박막 합성 공정 개발이 필요하다. 특히 Plasma enhanced chemical vapor deposition (PECVD) 방법은 공정 gas가 전기적 에너지로 분해되어 chamber 내부에서 cold-plasma 형태로 존 재하기 때문에 박막의 저온성장 및 대면적 합성이 가능하며 고진공을 바탕으로 합성 중 발생하는 오염 요소를 효과적으로 제어할 수 있다. 본 연구에서는PECVD를 이용하여 plasma power, 공정압력, 공정 gas의 유량 등 다양한 공정 변수를 조절함으로써 저온, 저압 조건하에서의 $MoS_2$ 박막 성장 가능성을 확인하였으며 전구체로는 Mo 금속과 $H_2S$ gas를 사용하였다. 또한 향후 flexible 소자 응용을 위한 플라스틱 기판의 녹는점을 고려하여 공정 온도는 $300^{\circ}C$ 이하로 설정하였으며 합성된 $MoS_2$ 박막의 두께 및 화학적 구성은 Raman spectroscopy를 이용하여 확인 하였다. 공정온도 $200^{\circ}C$$150^{\circ}C$에서 성장한 $MoS_2$ 박막의 Raman peak의 경우 상대적으로 낮은 공정온도로 인하여 Mo와 H2S의 화학적 결합이 감소된 것을 관찰할 수 있었고 $300^{\circ}C$의 경우 약 $26{\sim}27cm^{-1}$의 Raman peak 간격을 통해 5~6층의 $MoS_2$ 박막이 형성 된 것을 확인할 수 있었다.

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