• Korean Journal of Materials Research
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• v.11 no.2
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• pp.76-81
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• 2001

In order to recover Au and Pd from the leaching solution of various electronic wastes by electrowinning, the electrochemical behavior of Au and Pd in hydorchloric acidic solution was investigated by means of voltammetry. The reduction potential of Au ion was 800mV and the limiting current appeared at 470mV in electrolytic solution of gold. The reduction potential of Pd ion was 500mv and the limiting current appeared at 150mV in electrolytic solution of Palladium. However, in Au-Pd electrolytic solution, the Potentials for reduction and the limiting current of Au decreased as the content of Pd in electrolyte increased, and the potentials for the limiting current of Au and Pd closed nearest together when percentage of Pd electrolytic solution was 37v71% in Au-Pd electrolyte.

• 대학교육
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• s.142
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• pp.14-18
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• 2006

'99학년도 부터 본격적으로 시행된 학부제는 현재 많은 문제에 직면해 있으며 특히 학생들에 의한 전공 학과 선택권 보장은 실질적인 허구임이 드러났다. 학부제가 당초의 취지를 제대로 살리지 못하고 있다면 지체 없이 학과별 모집 단위로 환원되어야 하며 학문 분야의 성격과 각 대학의 특성에 맞추어 해당 대학에서 학부제 실시 여부를 판단할 수 있게 해야 한다. 더불어 그에 따른 책임 또한 각 대학이 스스로 질 수 있게 해야 할 것이다.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.39 no.7
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• pp.692-701
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• 1990

New selective tungsyen deposition deposition on silicon process is described which makes use of a previously unreported, alternating cyclic,

• Clean Technology
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• v.17 no.3
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• pp.225-230
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• 2011

Characteristics of hydrocarbon selective catalytic reduction of NOx using various noble metal catalysts were investigated. The best active metal is Pt, supports are $CeO_2$ and $TiO_2$ by strong interactions between active metals, and 55% of conversion rate of NOx is shown. Pd, Rh and Ag catalysts presented a conversion of less than 20% as active metals, and supports also showed the poor activity compared to $SiO_2$ and $ZrO_2$. Experiments were performed with different types of reducing agents, amount, concentration of oxygen and space velocity in order to investigate the performance of catalysts according to operating conditions. The results confirm that the methane is better than propane as a reducing agent, and as the ratio of methane/nitrogen oxide increases, the catalytic activity increased, as the concentration of oxygen increases and space velocity decreases, the performance of catalysts increased.

• Journal of the Korean Electrochemical Society
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• v.12 no.1
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• pp.40-46
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• 2009

We present a method for spatially selective immobilization of functional materials, such as proteins and nanoparticles, onto pre-activated silicon surfaces by electrochemical reaction. Carboxymethylbenzendiazonium (CMBD) cations, being adsorbable on silicon surfaces through electrochemically reductive deposition, is used as an anchor molecule to prepare the pre-activated silicon surfaces. It is demonstrated that the use of BD reaction is very efficient for the selective immobilization because the functional materials are immobilized exclusively onto the pre-adsorbed CMBD region. The method is applied to immobilize gold nanoparticles on the selected nanowire of the nanowire array.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.739-744
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• 2011

Activated carbon SCR(CSCR) catalyst that is used to remove $NO_x$ in exhaust gas including boron discharged from the production process of liquid crystal display(LCD) shows deactivation when boron is deposited to block the pores within the catalyst or to cover its active sites. The spent carbon catalyst is regenerated by washing with various surfactants, drying and calcination. For comparison of the physical and chemical properties before and after the regeneration with the variables, type of surfactants and calcination condition, element analysis by ICP, $N_{2}$ adsorption were conducted. $DeNO_{x}$ in SCR with $NH_3$ was carried out in a fixed bed reactor at $120^{\circ}C$. The activated carbon catalyst regenerated through washing with a non-ionic surfactant in $H_{2}O$ at $90^{\circ}C$ and calcination under $N_{2}$ gas at $550^{\circ}C$ shows similar level of surface area and $NO_x$ removal efficiency with those of fresh catalyst.

• Applied Chemistry for Engineering
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• v.34 no.5
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• pp.507-514
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• 2023

The selective catalytic reduction (SCR) of nitrogen oxides (NO_x) was investigated in a catalyst (Ag/γ-Al₂O₃) packed dielectric barrier discharge plasma reactor. The intermittent generation of plasma in the catalyst bed partially oxidized the hydrocarbon reductant for NO_x removal to several aldehydes. Compared to using the catalyst alone, higher NO_x conversion was observed with the intermittent generation of plasma due to the formation of highly reductive aldehydes. Under the same operating conditions (temperature: 250 ℃; C/N: 8), the NO_x reduction efficiencies were 47.5%, 92%, and 96% for n-heptane, propionaldehyde, and butyraldehyde, respectively, demonstrating the high NO_x reduction capability of aldehydes. To determine the optimal condition for intermittent plasma generation, the high voltage on/off cycle was adjusted from 0.5 to 3 min. The NO_x reduction performance was compared between continuous and intermittent plasma generation on the same energy density basis. The highest NO_x reduction efficiency was achieved at 2-min high voltage on/off intervals. The reason that the intermittent plasma discharge exhibited higher NO_x reduction efficiency even at the same energy density, compared to the continuous plasma generation case, is that the intermediate products, such as aldehydes generated from hydrocarbon, were more efficiently utilized for the reduction of nitrogen oxides.

• Resources Recycling
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• v.5 no.1
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• pp.29-33
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• 1996

The cominnn plocesses lor rccoremg silver irom silvcr conlaincd waster are the lcachmg silver hy HNO;. the srlcctive precipilillion of sliver ion lo AgCl and thc rcduchon of Ag wrfh ;I proper reductant. In this sludy, thc reduction of AgCI lo Ag was invesllngated by using Na, CO, as a rcd\icta~lt. The variations wcic reaction time. ttmpcrarure thc amount of NalCO, . and the resulls %, ere analyzcd by using sialist~c:d tecl~niques such as the ]polynomial rcgressiun analysis and the response surh~ce method. More than Yh% Ag analyzed was rcduced 1rtm AgCI at 62UT. I hour ullder condillon of 2 stnlchio~nctric ratio of Na iCO, !AgCI.

• Applied Chemistry for Engineering
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• v.19 no.1
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• pp.92-97
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• 2008

Selective catalytic reduction (SCR) of NO with ammonia was carried out over the physical mixture of $MnO_2$ and K or Cu-loaded activated carbons (AC) at low temperature. Introduction of oxygen affected positively the reduction of NO. Metal-impregnated AC showed significantly enhanced catalytic activity. Without water, the mixed catalyst of $MnO_2$ and K-loaded AC exhibited the best activity in the reduction of NO at $120^{\circ}C$. On the contrary, the activities of all the catalysts were significantly diminished in the presence of water. The mixed catalyst of $MnO_2$ and Cu-loaded AC treated with nitric acid and heat (1 : 1, w/w) exhibited the better activity for the reduction of NO than each single catalyst in presence of water.

• Clean Technology
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• v.18 no.4
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• pp.410-418
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• 2012

The performance of the ammonia injection gun (AIG) used for maximizing the utilization of reducing agent in the selective catalytic reduction (SCR) system is decided by several parameters such as the pattern of flow distribution, geometry of the air distribution manifold (ADM) and the array and geometry of nozzles. In the study, the uniformity of jet flows from the nozzles in AIG was analyzed statistically by using the computational fluid dynamics (CFD) method to evaluate the role of design parameters on the performance of the SCR system. The uniformity of jet flows from the nozzles is being deteriorated with increasing the supplying flow rate to the AIG. Distribution rates to each branch pipe become lower with decreasing distance to the header, and flow rates from nozzle are also reduced with decreasing distance to the header. The uniformity of jet flows from nozzles becomes stable significantly when the ratio of summative area of nozzles to each sectional area of the branch pipe is below 0.5.