• Journal of the Korean Electrochemical Society
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• v.3 no.2
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• pp.69-71
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• 2000

Redox-active calix[4]arenes with carboxylic acid and disulfide groups were prepared and spontaneous deposition on silver and gold surfaces was observed. Owing to their unusual structure, the calix[4]arenes exhibit selective affinity fur alkaline earth metal ions in aqueous media. When annular ionophores are immobilized on the surface, voltammetric and spectroscopic studies show the entrapment of metal ions. Furthermore, it was possible to reversibly capture and remove the ions using strong chelating agents such as ethylenediaminetetraacetic acid (EDTA).

• Korean Journal of Materials Research
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• v.6 no.10
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• pp.1025-1033
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• 1996

본 연구에서는 0.5M NaCI 용액내에서 일어나는 고분자재료로 피복된 강의 퇴화현상을 광학현미경 관찰 및 A.C. impedance spectroscopy를 이용하여 연구하였다. 강의 부식은 고분자재료로 피복된 강의 경우 국부부식(localized corrosion)의 형태로 나타난 반면, 피복되지 않은 강의 경우에는 전면부식(uniform corrosion)의 형태로 진행되었다. 고분자재료로 피복된 강의 부식이 국부적으로 진행되는 것은 피복층내에 존재하는 기공이나 크랙과 같은 결함 등에서 부식이 선택적으로 일어나기 때문으로 사료된다. 피복층의 박리(delamination) 현상은 고분자재료로 피복된 강/구리 갈바닉쌍(galvanic couple)의 경우 구리표면 위의 피복층에서만 관찰되었다. 이는 캐소드(cathode)로 작용하는 구리의표면에서 산소의 환원반응에 의해서 형성된 수산화이온(OH-)이 피복층의 박리를 조장하고 있음을 보여준다. 또한, 고분자재료 피복층의 파손 현상은 고분자재료/강의계면에서 석출된 부식생성물에 의해서 크게 조장되고 있음을 알 수 있다.

• Korean Journal of Cognitive Science
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• v.30 no.4
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• pp.199-217
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• 2019

Evolutionary research on mental disorders is relatively difficult compared to other medical studies. It is because the cause of mental disorder is unclear relative to other medical diseases, various proximate causations are involved. And it is difficult to distinguish cause and effect and to carry out experimental research. Despite these methodological difficulties, it is possible to establish an evolutionary hypothesis on mental disorders based on constructive reductionism, and to demonstrate actual data on the model based on this hypothesis. In this paper, I will discuss some conceptual definitions needed for applying ecological approaches to evolutionary psychiatric research. We will first discuss the appropriate level of explanations and the scope of the study subjects, then discuss the conceptual definition of behaviour and function, dysfunction and the appropriate level of selection.

• Journal of ILASS-Korea
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• v.9 no.2
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• pp.24-33
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• 2004

The effect of the working fluid flow conditions and nozzle geometry on the spray performance of a twin-fluid nozzle used in Selective Catalytic Reduction is investigated experimentally. The liquid pressure is varied in the range of 0.3atm to 1.5atm and the air pressure is varied from the 0.5atm to 3.0atm. relative position between liquid nozzle(internal nozzle) and air nozzle(external nozzle) tip changes front 1mm inside the air nozzle to 1mm outside the air nozzle. The orifice diameter of the air nozzle is varied with 5mm. 6mm and 7mm. Spray visualization is realized with CCD-Camera. SMD(Sauter Mean Diameter) and mean particle velocities are measured by PDPA(Phase Doppler Particle Analyzer) under various experimental conditions. The measuring point is 300mm away from the nozzle tip in the downstream spray. The experimental results are that spray angle is depended air flow rate because nozzle diameter, air pressure and nozzle tip relative positions are related air flow rate. SMD is depended air flow rate and water flow rate. Also, SMD is increased when water flow rate is bigger. SMD is decreased when Air flow rate is bigger.

• Korean Journal of Materials Research
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• v.9 no.11
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• pp.1062-1068
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• 1999

고정원으로부터 배출되는 질소산화물의 저감 기술 중에서 선택적 촉매 환원법(SCR법)은 가장 경제적이고 효율적인 방법으로 알려져 있다. 이 SCR 촉매의 탈질능을 향상시키기 위하여,$ TiOSO_4$ 및 Ti($SO_4$)$_2$용액으로부터 비표면적이 넓은 $TiO_2$의 비표면적 및 결정구조에 미치는 영향과 이들의 상관관계에 대하여 조사하였다. $TiOSO_4$용액으로부터 합성한 $TiO_2$의 최대 비표면적은 $382\m^2$/g이었고, Ti($SO_4$)$_2$용액으로부터 합성한 $TiO_2$의 최대 비표면적은 $335\m^2$/g이었으며, $TiO_2$는 비정질 형태의 결정구조를 보였다. 하소처리에 의해 비정질 $TiO_2$는 결정화되었고, 결정 중에 함유되어 있는 불순물은 $TiO_2$의 결정화를 억제하였다.

• Journal of ILASS-Korea
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• v.22 no.2
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• pp.96-102
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• 2017

In order to reduce the NOx, SCR technology is most suitable. In this study, we focused on studying the injector part of urea-SCR system. When stoichiometric 1 mole of urea is injected, 2 moles of $NH_3$ are created. $NH_3$ causes a SCR reaction by reacting with NOx. However, urea is decomposed by the side reaction of coming out HNCO, deposit formation is formed. In this study, it was to design a nozzle that can spray the optimal spray flow rate. Test nozzle used in this experiment is efferverscent type. The result of the experiment, liquid flow rate was confirmed to be that they are dominated by the exit orifice diameter. The area ratio is defined by ratio of the area of exit orifice hole and that of aerorator. The droplet size was measured by varying the area ratios. In addition, it was also confirmed that there is no change of the liquid flow rate and air flow rate to change the aerorator at the same exit orifice. Further, It was confirmed that the droplet size was relatively uniform even though the area ratio was different. Finally, there is little change in the SMD that air flow rate increases in 0.3 or more ALR.

• Resources Recycling
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• v.28 no.6
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• pp.79-86
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• 2019

Recently, the use of lithium ion battery(LIB) has increased. As a result, the price of lithium and the amount spent lithium on ion battery has increased. For this reason, research on recycling lithium in waste LIBs has been conducted1). In this study, the effect of roasting for the selective lithium leaching from the spent LIBs is studied. Chemical transformation is required for selective lithium leaching in NCM LiNi_xCo_yMn_zO₂) of the spent LIBs. The carbon in the waste EV cell powder reacts with the oxygen of the oxide at high temperature. After roasting at 550 ~ 850 ℃ in the Air/N₂ atmosphere, the chemical transformation is analysed by XRD. The heat treated powders are leached at a ratio of 1:10 in D.I water for ICP analysis. As a result of XRD analysis, Li₂CO₃ peak is observed at 700 ℃. After the heat treatment at 850 ℃, a peak of Li₂O was confirmed because Li₂CO₃ is decomposed into Li₂O and CO₂ over 723 ℃. The produced Li₂O reacted with Al at high temperature to form LiAlO₂, which does not leach in D.I water, leading to a decrease in lithium leaching ratio. As a result of lithium leaching in water after heat treatment, lithium leaching ratio was the highest after heat treatment at 700 ℃. After the solid-liquid separation, over 45 % of lithium leaching was confirmed by ICP analysis. After evaporation of the leached solution, peak of Li₂CO₃ was detected by XRD.

• Economic and Environmental Geology
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• v.11 no.3
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• pp.89-98
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• 1978

Mineralogy, beneficiation, and processes of titanium ores are reviewed from petrographic viewpoints. The most important titanium minerals are ilmenite ($FeTiO_3$) and rutile ($TiO_2$). Ilmenite will play major role :for raw material, because rutile are rapidly diminishing. Thus, there is a need to develope a successful process for producing high grade Ti02 from ilmenite. Commercial, as well as R and D processes to treat more abundant ilmenite ores fall in three general classess: 1. Iron in ilmenite is partially or completely reduced and separated either physically or chemically. 2. Iron is reduced to ferrous state and chemically leached away from the titanium. 3. Ore is treated to make chlorides either selectively or with subsequent separation and purification of $TiC_4$. Routes and efficiencies of these process technologies are primarily influenced by the particular ore deposit to be mined and secondly by environmental considerations. One deposit parameters which influence ilmenite process technologies are: 1. Complexity of microtextures of ilmenite intergrown with Fe-oxide minerals. 2. Composition of concentrates; ilmenites contain minor amounts of substituted Mg, Mn, and V. These elements plus iron and gangue minerals can cause difficulties to complete reactions, substantial acid consumption, difficulties of removing waste solids, and waste disposal problems. Major contributions to be made by petrologists for process optimization are: characterization and interpretation of compositional and physical changes of raw materials and solids derived from process streams. These informations can play significant role in selecting and improving process steps for titania production.

• Korean Chemical Engineering Research
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• v.47 no.5
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• pp.630-638
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• 2009

A computational fluid dynamics(CFD) model is developed and validated with on-site experiments for a urea-based SNCR(selective non-catalytic reduction) process to reduce the nitrogen oxides($NO_x$) in a municipal incinerator. The three-dimensional turbulent reacting flow CFD model having a seven global reaction mechanism under the condition of low CO concentration and 12% excess air and droplet evaporation is used for fluid dynamics simulation of the SNCR process installed in the incinerator. In this SNCR process, urea solution and atomizing air were injected into the secondary combustor, using one front nozzle and two side nozzles. The exit temperature($980^{\circ}C$) of simulation has the same value as in situ experiment one. The $NO_x$ reduction efficiencies of 57% and 59% are obtained from the experiment and CFD simulation, respectively at NSR=1.8(normalized stoichiometric ratio) for the equal flow rate ratio from the three nozzles. It is observed in the CFD simulations with varying the flowrate ratio of the three nozzles that the injection of a two times larger front nozzle flowrate than the side nozzle flowrate produces 8% higher $NO_x$ reduction efficiency than the injection of the equal ratio flowrate in each nozzle.

• Clean Technology
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• v.14 no.3
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• pp.204-210
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• 2008

A series of $V_{2}O_{5}-TiO_2$ xerogel catalysts were prepared by nonhydrolytic sol-gel method and analysed by various characterization techniques. These catalysts showed much higher surface areas and total pore volumes than conventional V$V_{2}O_{5}-TiO_2$ xerogel and impregnated $V_{2}O_{5}/TiO_2$ catalysts. It was found that the textural property of $V_{2}O_{5}-TiO_2$ material varies with the method and conditions of synthesis. Surface vanadates and $TiO_2$ anatase phase are the crucial factors to obtain high catalytic activities. The selective oxidation of hydrogen sulfide in the presence of excess water and ammonia was studied over these catalysts. Xerogel catalysts prepared by non-hydrolytic sol-gel method showed very high conversion of $H_{2}S$ without harmful emission of $SO_2$. The highest catalytic activity shown by these $V_{2}O_{5}-TiO_2$ catalysts may be due to their high surface area and good dispersion of vanadia species in the titania matrix.