• Resources Recycling
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• v.29 no.6
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• pp.3-14
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• 2020

This study aims to introduce and review on the recovery technologies of rare earth elements(REEs) from coal ash. Many researchers have been carried out by various beneficiation processes, such as particle size separation, magnetic separation, specific gravity, and flotation to recover rare earth elements from coal ash generated from Pulverized Coal(PC) boiler. Through the beneficiation process, it was confirmed that concentration of rare earth elements was much lower than the 4,700 ppm, and that additional enrichment treatment through wet process was needed for the products recovered after the beneficiation process. It was confirmed that the rare earth elements contained in coal ash were applied to the leaching process after pretreatment such as alkali-fusion to improve leaching efficiency. Although beneficiation and leaching methods have been studied, its optimum recovery technologies for rare earth elements not been confirmed up to now, research on the recovery of rare earth contained in coal ash is reported to continue. In case of Korea, the technology for the recovery of rare earth elements from coal ash and coal by-product could not been confirmed up to present. In these reasons, it is urgent to develop technologies such as beneficiation and leaching process continuously.

• Geotechnical Engineering
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• v.12 no.1
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• pp.73-86
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• 1996

In this study, the possibility of the utilization of coal ash as earthwork materials is investigated. For this purpose, some laboratory experiments were carried out. The samples used in these tests are fly ash(FA), bottom ash(BA), coal ash dropped into ash pond(FA:BA=8:2), and mixed coal ash(FA:BA=5:5), which were discharged as a by-product at Yong-Yeul thermoelectric power plant, and general road filling materials. And for the deformation analysis of coal ash reclamation ground, several hyperbolic model parameters were determined by triaxial compression test. As a result of this study, coal ash has excellent engineering properties such as strength parameters comparing with general soils of the same grain size, especially in case of being used as backfill materials and reclamation materials on soft ground, and coal ash is superior to general earthwork materials in engineering properties becasuse of self hardening behaveiour, light weight property, etc.

• Resources Recycling
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• v.28 no.6
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• pp.26-35
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• 2019

This study aims to introduce and economical review on the possibilities of rare earth elements(REEs) recovery from coal ashes and the analysis of economical evaluation factors based on the data for securing domestic rare earth elements. The cut-off grade of REEs on recovering from coal ash was confirmed to be 1,000 ppm on total rare earth oxides(TREO) basis, and while the economic value of coal ash changed with contents and specific elements of rare earth elements. This shall be resulted in the price differences of rare earth elements required by the current industry, and it probably varies depending on the future demand of rare earth components. For developing of commercial recovery technology on REEs in coal ashes, many researches have been carried out by various analyzing methods, such as evaluation of holding value of REEs in ashes, assessment between supply and demand of industry, comparison of investment and its profitability for the REEs's production from coal ashes, and so on. Although these methods have been suggested, its recovery system with economical feasibility could not been confirmed up to present. In this reason, the process design of recovering REEs from coal ash shall be researched continuously to solve the problems of the global rare earth market. And also these researches shall be conducted actively in Korea for the purpose of securing the REEs resources and their recovering technologies.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.4
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• pp.553-560
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• 2021

In this study, cement clinker using a pure sample and clinker using 7% coal ash were sintered at a temperature of 1050~1500℃. Changes in the content of cement minerals and changes in microstructure by sintering temperature were reviewed. The application of coal ash as a raw material for cement clinker was applicable as a source of Al₂O₃ and SiO₂. At a sintering temperature of 1350℃ or higher, the cement clinker applied with coal ash showed the same level of mineral content as compared to the cement clinker applied with pure raw material. The microstructure also showed a similar state, confirming that coal ash can be used as a raw material for cement. In XRD-Reitveld analysis, a maximum amount of Belite was produced at 1250℃. The conversion from Belite to Alite was observed from 1350℃. From 1350℃, the interstitial phase and the mineral phase presumed to be alite were distinguished. It was clearly distinguished from 1400℃. As the sintering temperature increased, the shape and boundary of the crystal phase became clear, and the size of the crystal phase was also increased.

• Journal of the Korean GEO-environmental Society
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• v.6 no.1
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• pp.15-21
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• 2005

In this study, the utilization of coal-ash and phosphogypsum was considered as the evapotranspiration final landfill cover(ET cover) material. Cover material considered was the mixture of the weathered granite soil, coal-ash and phosphogypsum and so we sequentially performed the leaching test, column test and field model test to investigate the environmental effects of mixtures of coal-ash and phosphogypsum. In the leaching test, all materials had lower heavy metal concentration than the regulated threshold values. The column test and the review of related regulations were carried out to determine the optimum mixing ratio(OMR) and OMR was soil(4):coal-ash(1): phosphogypsum(1) on the volume base, which was applied to field model test. Field model tests were continued from February to June, 2004 in the soil box that was constructed with cement block. It was verified that coal-ash and phospogypsum mixed with soil was safe environmentally and the mixture of both wastes could improve the water retention capacity of cover materials.

• Korean Journal of Poultry Science
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• v.33 no.1
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• pp.65-80
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• 2006

Ash amendment to manure holds potential as a method to neutralize manure for reducing odor and reduce phosphorus (P) solubility in runoff from fields where manure has been applied. This review focuses on the literature published about ash characteristics and their environmental uses. There is no uniform physico-chemical definition of the selected ashes (coal fly ash-CFA, wood ash-WA, and rice hull ash-RHA) used in various studies. These ashes vary greatly in their acidity (pH<6.0) or alkalinity (pH>12.5) based on the conditions at which they were farmed and the composition of the ash source. CFA amendment to manure reduced manure-P solubility and application of CFA amended manure to agricultural soils is a method to improve water quality WA may prove to be a valuable manure odor control amendment since WA contains a high level of carbon. A major biomass source is rice hull (husk) which provides an ash source (RHA). The .ice hull and RHA are sources of silica, compromising about 20% and 60%, respectively. So far research has been directed at the use of CFA, WA and RHA as soil amendments, but there is potential use of these materials as manure additives to sequester P and reduce odors.

• Journal of Energy Engineering
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• v.8 no.1
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• pp.67-75
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• 1999

여러 종류의 내화재로 구성된 석탄가스화기에서의 온도분포 및 열손실량을 구하기 위한 전산해석을 수행하였다. 석탄가스화기 내화재 설계를 위한 적절한 방법론을 제안하기 위하여 1차원 이론적 해석, 2차원 전도열전달 해석 및 3차원 대류-전도 복합열전달 해석 등 세가지 방법론으로 해석을 각각 수행하였다. 해석 결과들은 석탄가스화기 실험 결과와 정상적 정량적으로 잘 일치하는 것으로 나타났다. 결과의 정확성, 수치해석 상의 수렴성 및 계산시간 등을 종합적으로 고려해 볼 때, 전산해석에 핵심 경계조건인 가스화기 내벽의 온도를 적절히 설정할 수 있는 경우에는 2차원 전도열전달 해석이 공학적 설계에 적용하기 알맞은 방법론으로 판단되었다. 전산해석 결과에 의하면, 현재 실험이 진행중인 하루 3톤 처리 용량급의 석탄가스화기에서의 총 열손실량은 설계치 운전 기준으로 약 1% 정도인 것으로 판별되었다.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.11a
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• pp.156-157
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• 2014

Inorganic binding material was made by recycled resource and its applicability as pile-filling material was examined. The result was that the material had same liquidity with the liquidity of OPC and high reactivity with site soil. According to dynamic/static loading tests by site test-construction, the inorganic binding material met both design bearing capacity and settlement. Since the inorganic binding material showed same or better performance than OPC, the utilization possibility of the inorganic binding material made of recycled resource as pile-filling material was verified.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.4
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• pp.514-519
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• 2020

In this study, cement clinkers were sintered at each temperature by replacing some of the clay components of cement clinkers with coal materials. The mineral phase change of sintered cement clinker was quantitatively analyzed by XRD-Rietveld method. As the sintering temperature of cement clinker increased, the amount of belite decreased, the amount of alite increased, and the amount of free-CaO decreased. The form of alite and belite could be distinguished at sintering temperature of 1450℃ or higher. The crystal size was greatly increased at 1500℃ sintering. It was confirmed that the excessive sintering was progressed. Free-CaO decreased with the increase of sintering temperature. At 1450 ℃ or higher, it was less than 0.5%. In 1450℃ or greater, it is determined that enough sintering is included. Therefore, the application of fly ash as a raw material of cement clinker was judged to be usable as a source of chemical components of alumina and iron raw materials.

• Journal of Energy Engineering
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• v.27 no.2
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• pp.55-60
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• 2018

In this study investigated the Controlled Low Strength Materials using coal ash and steel slag(KR slag) as the main material in the thermal power plant classified as waste resource. Bottom ash and KR slag are mixed at a ratio of 7: 3 to expand the use of industrial by-products through carbonate($CO_2$-fixation) reactions and inhibit the exudation of heavy metals. The results showed that the water content increased as the content of bottom ash increased. It was confirmed that as the powder content increased, the bleeding ratio decreased. Also, as the content of one kind of ordinary portland cement (OPC) decreased, activation of hydration reaction decreased and compressive strength decreased. However, when the mixed composition is appropriately adjusted, the compressive strength of 2.0 MPa required for the controlled low-strength material can be satisfied.