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Effect of Pulse Frequency on the Properties of ZnO:Al Thin Films Prepared by Pulsed DC Magnetron Sputtering (펄스 DC 마그네트론 스퍼터링법에 의한 ZnO:Al 박막 증착시 펄스 주파수의 영향)

  • 고형덕;이충선;태원필;서수정;김용성
    • Journal of the Korean Ceramic Society
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    • v.41 no.6
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    • pp.476-480
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    • 2004
  • AZO (Al-doped ZnO) thin films were deposited on glass by pulsed magnetron sputtering method, and their structural, electrical and optical properties were investigated. XRD patterns showed that a highly c-axis preferred AZO film was grown in perpendicular to the substrate when pulse frequency of 30 ㎑ was applied to the target. Microstructure of thin films showed that the fibrous grain of tight dome shape was grown. The deposition rate decreased linearly with increase of pulse frequency, and the lowest resistivity was 8.67${\times}$10$\^$-4/ $\Omega$-cm for the film prepared at pulse frequency of 30 ㎑. The optical transmittance spectra of the films showed a very high transmittance of 85∼90%, within visible wavelength region and exhibited the absorption edge of about 350 nm. The characteristics of the low electrical resistivity and high optical transmittance of AXO films suggested a possibility for the application to transparent conducting oxides.

Microstructure and Magnetic Properties of Pulsed DC Magnetron Sputtered Zn0.8Co0.2O Film Deposited at Various Substrate Temperatures (증착온도를 달리하여 제조한 Zn0.8Co0.2O 박막의 미세조직 및 자기 특성)

  • Kang, Young-Hun;Kim, Bong-Seok;Tai, Weon-Pil;Kim, Ki-Chul;Suh, Su-Jeung;Park, Tae-Seok;Kim, Young-Sung
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.79-84
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    • 2006
  • We studied the microstructure and magnetic property of the pulsed DC magnetron sputtered $Zn_{\0.8}Co_{0.2}O$ film as a function of substrate temperatures. The X-ray patterns of the $Zn_{\0.8}Co_{0.2}O$ film showed a strong (002) preferential orientation at $500^{\circ}C$. The films with a crystallite size of 23-35 nm were grown in the form of nano-sized structure and this tendency was remarkable with increasing substrate temperature. The UV-visible result showed that the $Zn_{\0.8}Co_{0.2}O$ film prepared above $300^{\circ}C$ has a high optical transmittance of over $80\%$ in the visible region. The absorption bands were observed due to sp-d interchange action by $Co^{2+}$ complex ion and dd transition in the region from 500 to 700nm. The resistivity of the film was below $10^{-1}\;\Omega-cm\;above\;300^{\circ}C$. The AGM analysis results for the all films showed the magnetic hysteresis curves of ferromagnetic nature. The low electrical resistivity and room temperature ferromagnetism of ZnCoO thin films 'deposited above $300^{\circ}C$ suggested the possibility for the application to Diluted Magnetic Semiconductors (DMSs).

Toxicokinetics of 4-tert-octylphenol in rats (Rat에서의 Octylphenol의 독성동태 연구)

  • 손수정;강현구;이선우;서수경;박인숙;안미령;최홍석;조재민;손동환
    • Environmental Mutagens and Carcinogens
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    • v.21 no.2
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    • pp.122-127
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    • 2001
  • 4-tert-octylphenol (OP) is a surfactant additive widely used in the manufacture of a variety of detergents and plastic products. Also, OP is known to have estrogenic activity by interacting with development and functions of endocrine system. This study was carried out to obtain toxicokinetic parameters of OP in male Sprague-Dawley rats. Male rats were administered OP, by either single oral (gavage) applications of 50, 100 or 200 mg/kg body weight. or a single intravenous injections of 1, 5 or 10 mg/kg body weight. Blood samples taken at several time intervals after administration were obtained from the femoral artery. Analysis of blood samples for OP was performed by gas chromatography mass spectrometry (GC/MS). The detection limit of OP was 1.9 ng/$m\ell$ at SIM (selected ion monitoring) mode of GC/MS. Calibration curve for analysis of the concentrations of OP in plasma was (OP/butylphenol peak area ratio) = 0.0294 $\times$ (plasma cone.) + 0.028 ($r^2$= 0.9991). The OP plasma concentration was 3921 ng/$m\ell$ immediately after single intravenous application, decreased rapidly within 45 min, and was detectable at low concentration up to 6 hr after application. When administered orally in rats (50, 100 and 200 mg/kg), OP was detected in the blood early after gavage administration, indicating the rapid initial uptake from gastrointestinal tract, with Tmax obtained from 0.67~0.83 hr. Using the AUC (area under the curve) of plasma concentration vs. time, low oral bioavailabilities of 1.2, 5.0 and 5.3% were calculated for the 50, 100 and 200 mg/kg groups, respectively.

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Effect of quenching rate and crystallization behavior on the magnetic properties of annealed Nd-Fe-B ribbons (Melt-spun Nd-Fe-B 리본의 자기적 특성에 미치는 급속응고속도 및 결정화 거동의 영향)

  • 이경섭;서수정
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.655-659
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    • 1998
  • The effect of quenching speed of melt-spinning on intrinsic coercivity ($_iH_c$$) of annealed ribbons and the crystallization behavior from amorphous $Nd_{14.73}Fe_{78.67}B_{6.60}$ alloy have been studied. We have found that the intrinsic coecivity for annealed melt-spun ribbon is reduced with increasing of quenching rate. $\alpha$-Fe and $Fe_3B$ were formed as intermediate phases prior to the formation of $Nd_2Fe_{14}B$ phase during crystallization. The $Fe_3B$ is disappeared with crystallization of $Nd_2Fe_{14}B$ phase. But the $\alpha$-Fe phase is retained in fully crystallized ribbon by annealing. The intrinsic coercivity loss of annealed ribbon with increasing of quenching speed is believed to be due to existence of soft magnetic phase $\alpha$-Fe in annealed ribbons.

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The control of poly-grain and internal cavities for high-quality $CaF_2$ single crystal growth of 6inch in diameter (고품질의 직경 6 inch 형석($CaF_2$)단결정 성장을 위한 poly-grain 및 내부 cavity제어)

  • Seo, Soo-Hyung;Joo, Kyoung;Auh, Keun-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.550-554
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    • 1998
  • We suggested the new method of thermal screen in Bridgman-Stockbarger method to control the polygrain, the internal cavities and solid-liquid (SL) interface. $CaF_2$ single crystal of 6 inch was grown perfectly when we adopted to use a graphite pipe and a ceramic warmer in the conditions of growth rate 2 mm/hr, vertical temperature of $14^{\circ}C$ for freezing and temperature of $1324^{\circ}C$ at conical tip of crucible. The light scattering phenomena occurred by internal cavities were controlled as decreasing the freezing rate to 2 mm/hr and/or as adopting the rotation of melt (7 rpm).

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A study on the magnetic properties and microstructure of spin-valve type multilayer for giant magnetoresistance (스핀밸브형 거대자기저항 다층박막의 자기적 특성 및 미세구조에 관한 연구)

  • 노재철;이두현;이명신;윤대호;서수정
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.73-82
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    • 1998
  • The exchange anisotropy is the unidirectional magnetic anisotropy which comes from exchange interaction between antiferromagnetic layer and ferromagnetic layer. The application of this phenomenon to MR read head and spin-valve type GMR (Giant Magnetoresistance) head has been studied extensively. In our study, we intended to apply exchange anisotropy of NiO/NiFe bilayer to spin-valve type GMR element. Above all, we studied the exchange anisotropy of NiO/NiFe bilayer, and focused especially on the effect of NiO deposition condition. And we found that Ar pressure during NiO deposition was crucial factor for the exchange anisotropy of NiO/NiFe bilayer. The lower the Ar pressure is, the better the characteristics of exhange anisotropy is. Then, we applied this optimum condition of NiO/NiFe bilayer to spin-valve type GMR element. Finally we got spin-valve type GMR element which had 3.6 % MR ratio, 16 Oe switching field, and 0.25 %/Oe sensitivity.

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Structural Design and Installation of Tracking-type Floating PV Generation System (추적식 수상 태양광발전 시스템의 설계 및 시공)

  • Kim, Sun-Hee;Lee, Young-Guen;Seo, Su-Hong;Joo, Hyung-Joong;Yoon, Soon-Jong
    • Composites Research
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    • v.27 no.2
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    • pp.59-65
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    • 2014
  • Most of energy are obtained from oil, coal, and natural gas, most likely, fossil fuel which is limited throughout the world. Recently, high crude oil price, climate change, oil depletion, etc. are main reason to get attention to non-fossil energy including renewable energy in the world. In this study, we studied analysis and design of structure system composed of pultruded fiber reinforced polymer composite (PFRP) which has many advantages such as high specific strength and stiffness, high corrosion resistance and chemical resistance. For the design and construction of floating-type structure, PFRP structural members may be the first choice. Design of tracking-type floating PV generation structure was performed by using the results of the finite element analysis. The structure is fabricated and installed on the water surface. Before the installation of the structure, safety related problems associated with installation and operation are investigated using the finite element simulation and it was found that the structure is safe enough to resist externally applied loads.

Structural Behavior of Reinforced Concrete Beam Strengthened in Shear by Carbon Fiber Mesh and Mortar (탄소섬유메쉬와 모르터로 전단 보강된 RC보의 거동에 관한 연구)

  • Seo, Soo-Yeon;Yoon, Seung-Joe;Lee, Woo-Jin;Lee, Jong-Kyu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.8 no.2
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    • pp.205-211
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    • 2004
  • The purpose of this study is to investigate shear strengthening effects and behaviour of RC beams strengthened in shear by Carbon Fiber Mesh(CFM) and mortar for fixing CFM to concrete. Test parameters in experiment are shear span-to-depth ratio, layout of CFM and number of clip. From the test, it was shown that the governing failure patten was the bond failure between cover mortar and RC beam initiated at about 60% of maximum strength. And the strength of CFM was developed up to 19.6% of it's maximum tensile strength when the specimen reached to failure. The most effective enhancement using CFM and mortar were to attach CFM diagonally to concrete in a/d of 1.0 and increase the number of cilps in a/d of 1.5, respectively.

Applicability of Projective Transformation for Constructing Correspondences among Corners in Building Facade Imagery (건물벽면 영상내 코너점의 대응관계 구성을 위한 사영변환행렬의 적용성)

  • Seo, Suyoung
    • Korean Journal of Remote Sensing
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    • v.30 no.6
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    • pp.709-717
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    • 2014
  • The objective of this study is to analyze the degree of correspondences among corners found in building facade imagery when the projective transformation parameters are applied to. Additionally, an appropriate corner detection operator is determined through experiments. Modeling of the shape of a building has been studied in numerous approaches using various type of data such as aerial imagery, aerial lidar scanner imagery, terrestrial imagery, and terrestrial lidar imagery. This study compared the Harris operator with FAST operator and found that the Harris operator is superior in extracting major corner points. After extracting corners using the Harris operator and assessing the degree of correspondence among corners in difference images, real corresponding corners were found to be located in the closest distance. The experiment of the projective transformation with varying corners shows that more corner control points with a good distribution enhances the accuracy of the correspondences.

Effects of Sowing Density and Thinning Treatment on Growth Characteristics and Yield of 3-Year-Old Ginseng Cultivated in a Greenhouse (인삼 하우스 직파재배 시 파종밀도 및 솎음처리가 3 년근 인삼의 생육과 수량에 미치는 영향)

  • Suh, Su Jeoung;Jang, In Bae;Yu, Jin;Jang, In Bok;Hyun, Dong Yun;Park, Hong Woo;Kweon, Ki Bum
    • Korean Journal of Medicinal Crop Science
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    • v.26 no.1
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    • pp.64-71
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    • 2018
  • Background: The cultivation of ginseng (Panax ginseng C. A. Meyer) in greenhouses could reduce the use of pesticides and result in higher yield; however, construction costs are problematic. The adaptation of direct-sowing culture in greenhouses could reduce the cost of ginseng production. Methods and Results: To improve seedling establishment in direct-sowing culture, effects of sowing density (SD), number of seeds sown per hole (SN), and thinning (TH) treatment on the root yield were investigated after 3 years of seeding. The emergence rate was significantly influenced by SD, but not by SN or TH. Damping-off and rusty roots increased with an increase in SN with diminishing effects of SN on seedling establishment. Root weight and diameter were affected by SD, SN, and TH, however, there were no statistical significances. The total number of roots harvested per unit area increased with increasing SD and SN, and the weight of roots was affected by SD, but not by SN or TH. Conclusions: Multi-seed sowing per hole and/or thinning might not be an efficient method for the direct-sowing culture of ginseng. The SD for direct seeding culture in greenhouses should be approximately $33-42seeds/m^2$ for an optimum yield of 3-year-old ginseng.