• Title/Summary/Keyword: 서부사료

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ESCA를 이용한 노화된 종이의 표면 변화 특성 관찰

  • 양봉숙;김형진;조병묵;오정수
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.11a
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    • pp.139-139
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    • 2000
  • 종이는 제조 후 시간의 경과에 따라 노화가 야기되기 시작하며 이에 수반되는 현상으로서 종이의 기계적 강도 손실 및 종이의 색 변화를 들 수 있다. 종이의 노화 현상은 주로 빛, 열, 대기 오염물질, 미생물, 곤충 및 화학약품 등의 외부 인자들에 의해 종이 내에서의 가수 분해 또는 산화작용을 발생시키며 이는 종이의 폭넓은 이용올 제한하는 중요한 원인이 되고 있다. 종이의 노화기작은 주로 산 가수분해 및 산화작용 그리고 가교결합 둥으로 해석되고 있다. 이는 종이의 주 구성요소인 셀룰로오스의 수산기가 반웅하여 카르보닐기를 형성하면 서 저분자화 되거나 산소에 의해 산화되면서 저분자화 되어 종이의 강도적 손실이 일어난다 고 보고되고 있으며 종이의 황색화(Yellowing) 현상은 주원인이 종이에 잔존하고 있는 리그 년이 빛과 열에 의해 반응하여 산화됨으로써 야기된다고 설명되고 있다. 즉, 열이나 자외선 및 가시광션의 조사로 인한 셀룰로오스 및 기타 종이 구성물의 산화에 의해 종이가 퇴색되 거나 강도가 저하되는 현상이 일어나게 된다. 특히 이러한 노화 거동은 상온의 경우에서는 펄프와 종이의 황색화가 천천히 일어나지만 옹도가 점차 올라갈수록 그 속도는 빨라진다. 종이가 노화되면서 일어나는 산화반용은 주로 대기 중의 산소와 접촉하기 쉬운 표변에서부 터 발생하기 쉽다. 열처리를 통해 표면에서의 산화 작용은 촉진되고 종이의 구성원소의 결 합에 화학적 변화가 야기된다. 이를 분석하기 위해서 모든 원소가 독특한 결합에너지를 가 지고 있다는 것에 착안 시료 표면에 특정 x-선 및 전자빔을 입사하여 방출하는 광전자의 에너지를 측정함으로써 시료 표면의 조성 및 화학적인 결합상태를 알 수 있는 ESCA ( (Electron Spectroscopy for Chemical Analysis)를 이용하였다 .. ESCA는 주로 표면 원소의 규 명 및 정량분석과 화학결합 상태의 정성, 정량 분석, 깊이에 따른 원소의 농도 분포 분석, 고분자화합물의 특성 조사, 표면 원소의 화학결합에 따른 전자상태 연구 둥에 활용되 고 있 다. 즉, 종이가 노화되면서 원소들 사이에 변화되는 결합을 이러한 에너지 분석에 의해 원소 정성분석 또는 정량분석을 하고자 하였으며, 이를 분석하여 열처리 시 종이 표면에서 일어 나는 변화를 구명하고자 하였다. 이에 따라 본 연구에서는 종이의 노화를 가속화시키는 빛, 대기오염물질, 및 기타 다른 인 자들은 배제하고 열 만을 가해 노화의 진행속도를 높인 후, 노화 진행 시 종이 표변에 일어 나는 산화작용 및 가수분해를 표면 분석 장치인 ESCA를 이용하여 종이의 주 구성원소인 탄소와 산소가 열처리 시 변하는 에너지를 측정하였다. 또한 카르복실기 정량과 종이의 pH 측정 및 X -ray Diffractometer를 이용하여 결정화도를 측정하였다. 본 연구의 결과, 시간의 경과에 따라서 탄소의 결합에너지는 분포가 C-H에서 COO-, 또는 C=O로 달라짐으로써 종 이가 산화되고 있다는 것을 알 수 있었다. 또한 이 결합에너지 분포의 변화가 펄프의 종류 에 따라서 다르게 이동함으로써 제조된 시트의 표면 산화반응이 서로 다르게 일어나고 있음 을 알 수 있었으며, 이는 사용한 펄프의 화학 조성분의 차이에 기인한 것이라 사료된다.

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A Study on Estimation of Design Tidal level Considering Sea Level Change in the Korean Peninsula (한반도의 해수면 상승을 고려한 설계조위 산정에 관한 연구)

  • Choo, Tai Ho;Sim, Su Yong;Yang, Da Un;Park, Sang Jin;Kwak, Kil Sin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.4
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    • pp.464-473
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    • 2016
  • The air temperatures of the coast and inland are rising due to an increase in carbon dioxide emissions and abnormal climate phenomena caused by global warming, El Nino, La Nina and so on. The sea levels of the Earth are rising by approximately 2.0 mm per year (global average value) due to the thermal expansion of sea water, melting of glaciers and other causes by global warming. On the other hand, when it comes to designing a hydraulic structure or coastal hydraulic structure, the standard of the design water level is decided by analyzing four largeness tide values and a harmonic constant with the observed tidal water level or simulating numerical model. Therefore, the design tidal water level needs to consider an increasing speed of the seawater level, which corresponds to the design frequency. In the present study, the observed tidal water levels targeting 46 tidal stations operated by the Korea Hydrographic and Oceanographic Administration (KHOA) from the beginning of observations to 2015 per hour were collected. The variation of the monthly and yearly and increasing ratio were performed and divided into 7 seas, such as east and west part of the Southern Sea, south part and middle of the East Sea, south part and middle of the Western Sea, and Jeju Sea. The current study could be used to determine the cause of local seawater rises and reflect the design tidal water level as basic data.

Storm Surge Vulnerability Assessment due to Typhoon Attack on Coastal area in Korea (태풍 내습으로 인한 연안역 해일 취약성 평가)

  • Kang, Tae-Soon;Oh, Hyeong-Min;Lee, Hae-Mi;Eum, Ho-Sik
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.21 no.5
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    • pp.608-616
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    • 2015
  • In this study, we have estimated the storm surge heights using numerical modeling on coastal area, and then evaluated the vulnerability index by applying the vulnerability assessment techniques. Surge modelling for 27 typhoons affected from 2000 to 2014 were simulated by applying the ADCIRC model. The results of validation and verification was in significant agreement as compared with observations for the top 6 ranking typhoons affected. As results, the storm surge heights in Jinhae Bay, Sacheon Bay, Gwangyang Bay, Cheonsu Bay and Gyeonggi Bay were higher than other inner coastal areas, then storm surge vulnerability assessment was performed using a standardization, normalization and gradation of storm surge heights. According to results of storm surge vulnerability assessment, index of Jinhae Bay, Sacheon Bay, Gwangyang Bay etc. are estimated to be vulnerable(4~5) because of the characteristics of storm surge such as inner bay are vulnerable compared with exposed to the open sea areas. However, index in the inner bay of western Jeonnam are not vulnerable(1~3) relatively. It may not appear the typhoons affected significantly for the past 15 years. So, the long-term vulnerability assessment with the sensitivity of geomorphology are necessary to reduce the uncertainty.

Investigation of the Level of Microbial Contamination in the Environment for Juice Production (생딸기 주스 제조 환경에서의 미생물학적 오염도 조사)

  • Kim, Se-Ri;Shim, Won-Bo;Park, Seon-Ja;Ha, Kwang-Soo;Yoon, Hae-Suk;Ha, Sang-Do;Kim, Keun-Sung;Lee, Kyu-Ho;Kim, Min-Gon;Kim, Kwang-Yup;Kim, Cheol-Ho;Chung, Duck-Hwa
    • Korean Journal of Food Science and Technology
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    • v.37 no.2
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    • pp.287-293
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    • 2005
  • Microbial contamination levels in commercial strawberry juices were examined for sanitary indication bacteria, such as aerobic plate count (APC), coliforms, and Escherchia coli, and pathogenic bacteria such as E. coli O157:H7, Salmonella spp., Staphylococcus aureus, and Listeria monocytogenes. APC and coliform count ranged 0-5.2 and $0-2.8\;log_{10}\;CFU/(mL,\;g,\;100cm^{2},\;hand)$, respectively, and 80% strawberry juices were contaminated with E. coli and S. aureus, detected at 19%, was found in employee's hands, strawberries, and strawberry juices, whereas E. coli O157:H7, Salmonella spp, and L. monocytogenes were not detected. These results will provide microbiological information for introduction of Hazard Analysis Critical Control Point (HACCP) system in juice shops.

A study on alluvial deposits of tributaries of Yungsan river, near Damyang. (담양지역 영산강 지류 하천 퇴적층의 특성에 대한 연구)

  • Kim, Jong Yeon;Hong, Se Sun
    • Journal of The Geomorphological Association of Korea
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    • v.20 no.4
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    • pp.51-70
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    • 2013
  • The characteristics of deposits formed by the Daejon-cheon and Soobuk-cheon, dissecting the mountains such as Byungpung Mt. and Samin Mt. in western part of Damyang county, Jeonmam province. Results from field survey and bore hole logging by KIGAM are used in interpreting depositional environment, in this study. By the result of deposits near of the channels Daejon-cheon and Soobuk-cheon, and main channel of Youngsan River, the depth of sediment layers in this area is 4~7m, far thinner than formerly estimated. Weathered material of local rocks forms the base of the sedimentary layers. It can be assumed that the location channel of the Youngsan river has been stable ever since the start of the sedimentary events. Sediment particles of tributaries are angular than those of Youngsan River. Particles are larger and sorting is poor. It is interpreted as mount flash flood deposits. Main sources of sediments at the valley bottom or deposition dominated area are the terrace deposits or slope deposits over the gentle foot-slope or front of surrounding mountains. Some particles show polygonal cracking on the surface originated from the strong chemical weathering, while most of these has high angularity. It means various geomorphic processes operate to produce and transport the particles in this area.Isolated hills within the sedimentary plains are made with weathered materials of local bedrock. In the case of foot-slope of the hills, thin sedimentary layers are found. So it can be concluded that surface features of deposition zone of the Daejon-cheon and Soobuk-cheon is formed by the filling of lower part of the valley and its feature partly controlled by the relief of the weathering front.

Effects of Shading on Growth of Maesa japonica Seedlings (차광 처리가 빌레나무 묘목 생장에 미치는 영향)

  • Min-Ji Park;Ju-Eun Yang;Chae-bin Lee;Yeon-Ok Seo;Byoung-Ki Choi;Eun-Young Im;Hyung-Soon Choi
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2021.04a
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    • pp.30-30
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    • 2021
  • 빌레나무는 국내에서 제주도 서부 곶자왈 지역에서만 자생하는, 어두운 환경을 선호하며 개체수가 희소한 종이다. 본 연구는 광 환경이 빌레나무 묘목 생장에 미치는 영향을 파악하고자 수행되었다. 서귀포시 난대아열대산림연구소 내 양묘장에 차광막을 이용하여 35%, 55%, 75% 차광 처리구를 설치하였고 노지에 비차광 처리구를 비교구로 설정하였다. 2019년 7월에 삽목 증식시킨 빌레나무를 2020년 5월에 각 처리구에 이식하였다. 2021년 3월에 각 차광 처리구의 모든 묘목의 묘고, 잎의 수, 줄기 수를 측정하고 생육이 건전하고 평균적인 묘목을 각 9본씩 굴취하여 건중량을 측정하였다. 35%, 55%, 75% 차광 처리구별 평균 묘고(cm)는 각각 53.2, 51.3, 41.4, 평균 잎의 수(개)는 41.3, 42.1, 24.4, 평균 줄기 수(개)는 3.1, 2.7, 2.2로 나타났다. 평균 묘고, 잎의 수, 줄기 수는 35% 차광 처리구와 55% 차광 처리구에서 75% 차광 처리구보다 높은 경향을 보였다. 건중량 분석 결과, 35%, 55%, 75% 차광 처리구별로 평균 잎 건중량(g)은 각각 11.3, 9.5, 5.5, 평균 줄기 건중량(g)은 5.6, 5.3, 2.6, 평균 뿌리 건중량(g)은 4.5, 3.6, 2.6으로 차광률이 낮을수록 증가하였으며 모든 부위별 건중량은 처리에 따른 통계적 유의성을 보였다(p<0.05). 지상부 대비 지하부 비율은 75% 차광 처리구에서 0.35로 가장 높았으며 35%, 55% 차광 처리구에서 0.27, 0.26로 나타났다. 한편, 비차광처리구의 모든 묘목들은 2021년 1~2월경 지상부가 고사하였다. 본 연구결과, 빌레나무 묘목은 노지에서 생존률이 불량하고, 차광 처리 시 차광률 증가에 따라 생장에 부정적인 영향을 받는 것으로 판단된다. 빌레나무의 건전한 생육 및 유무성증식을 통한 보급 증대에 기여하기 위하여 향후 온도, 수분 등 여러 환경 인자를 조절하는 연구가 필요한 것으로 사료된다.

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Impacts of Two Types of El Niño on Hydrologic Variability in Annual Maximum Flow and Low Flow in the Han River Basin (두 가지 El Niño 형태에 따른 한강 유역의 연최대홍수량 및 저유량의 변화 분석)

  • Kim, Jong-Suk;Yoon, Sun-Kwon;Lee, Joo-Heon
    • Journal of Korea Water Resources Association
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    • v.45 no.10
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    • pp.969-981
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    • 2012
  • In this study, we analysed hydrologic variability in quantity and onset of annual maximum flow and low flow by impacts of the different phases of ENSO (El Ni$\tilde{n}$o Southern Oscillation) over the Han River Basin. The results show that annual maximum flow has increased statistically significant about 48.3% of all over the watershed. The onset of annual maximum flow was delayed in the west of the Han River basins and in the east of the basins was likely to be rapid onset. Also, this study shows that 7-day low flow was deceased statistically significant about 26.0% of the total area in the Han River Basin, and onset of 7-day low flow tends to be faster in the upper-middle basins of the Han River. The onset of annual maximum flow shows similar pattern during the CT (Cold tongue)/WP (Warm-pool) El Ni$\tilde{n}$o years, but annual maximum flow appeared less in 89.0% of all basins during the CT El Ni$\tilde{n}$o years. In addition, the onset of 7-day low flow tended to be faster about 17 days on average during the WP El Ni$\tilde{n}$o years, and 72.7% of the basins show significant increase during the CT El Ni$\tilde{n}$o years. Consequently, it was found that the different phases of CT/WP El Ni$\tilde{n}$o have effects on sensitivity to variability in quantity and onset of water resources over the Han River Basin. We expect that the present diagnostic study on hydrological variability during different phases of ENSO will provide useful information for long-term prediction and water resources management.

Understanding of Phytoplankton Community Dynamics Through Algae Bioassay Experiment During Winter Season of Jinhae bay, Korea (생물검정실험을 통한 동계 진해만 식물플랑크톤의 군집 변동 특성 파악)

  • Hyun, Bong-Gil;Shin, Kyoung-Soon;Kim, Dong-Sun;Kim, Young-Ok;Joo, Hae-Mi;Baek, Seung-Ho
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.16 no.1
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    • pp.27-38
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    • 2011
  • The distributions of phytoplankton assemblages and environmental factors in Jinhae Bay and their relationships were investigated to estimate the potential limiting nutrient for phytoplankton growth and community structure. In situ algal bioassay experiments were also conducted to assess the species-specific characteristics in phytoplankton responses under different nutrient conditions (control, N(+) and P(+) treatment). During the study periods, bacillariophyceae and cryptophyceae occupied more than 90% of total phytoplankton assemblages. Phytoplankton standing crops in the inner part of Masan Bay were higher than that of Jinhae Bay. The DIN:DIP ratio, pH and transparency showed the significant positive correlation with phytoplankton biomass. According to cluster and multidimensiolnal scaling (MDS) analysis based on phytoplankton community data from each station, the bay was divided into three groups. The first group included stations from the south-western part of Jinhae bay where cryptophyta species were dominated. The second group was distinguished from inner stations in Masan Bay. These stations showed low transpancy and high DIN:DIP ratio. The other cluster included the stations from the eastern part and central part of Jinhae Bay, which was characterized by the high DSi:DIP ratio and dominant of diatom species. Phosphorous (P) was limited in Masan Bay due to significantly increases in the phytoplankton abundances. Based on stoichiometric limitation and algal bio-assay in Jinhae Bay, nitrogen (N) was a major limiting factor for phytoplankton production. However, silicate (Si) was not considered as limiting factor, since Si/DIN and Si/P ratio and absolute concentration of nutrient did not create any potential stoichiometric limitation in the bay. This implies that high Si availability in winter season contributes favorably to the maintenances of diatom species.

Geologic, Fluid Inclusion, and Sulfur Isotopic Studies of Hydrothermal Deposit in the Tanggueng District, West Java, Indonesia (인도네시아 서부자바 땅긍(Tanggueng)지역 열수광상의 지질, 유체포유물 및 황동위원소 연구)

  • Jae-Ho Lee;In-Joon Kim
    • Economic and Environmental Geology
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    • v.36 no.5
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    • pp.321-328
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    • 2003
  • The epithermal gold and base metal deposit of the Tanggeung district of West Java consists of four major veins(Celak, Cigodobras, Cilangkap and Pasirbedil) with NS to N10$^{\circ}$∼20$^{\circ}$E and N75$^{\circ}$W strikes. The veins occur within fractures cutting the crystal and lithic tuff of Jampang Formation(Oligo-Miocene) in and around the Mt. Subang of the western Java, Indonesia. The ore mineralization is characterized by the occurrence of pyrite, sphalerite, galena, chalcopyrite, and small amounts of bornite and Fe-oxides. Hydrothermal alteration, associated with the mineralization, was dominantly silicified and enveloped by the phyllitic(sericitic), argillic and propylitic alteration containing the disseminated pyrite. Gangue minerals consist of interstratified smectite-illite, chlorite, sericite, and minor kaolinite. The presence of vapor-rich fluid inclusions in quartz veins suggests that boiling occurred locally throughout ore deposition. Fluid inclusion studies suggest that the ore fluid evolved from initial high temperatures(〓34$0^{\circ}C$) to later lower temperatures(〓19$0^{\circ}C$). Salinities range from 0.0 to 8.3 wt percent NaCl equiv. The relatively high increase in salinity(up to 8.3 wt percent NaCl equiv) might be explained by a local boiling and by a participation of magmatic fluids, supported by the sulfur isotope results. Evidence of fluid boiling suggests that the pressure decreased from 200 bars to 120 bars. This corresponds to the depths of approximately 750 to 1,200 m in a hydrothermal system that changed from lithostatic to hydrostatic conditions. Using homogenization temperatures and paragenetic constraints, the calculated $\delta$$^{34}$ S values of $H_2S$ in ore fluid are -0.2 to 1.8 permil close to the 0 permil isotopic value of magmatic sulfur.

Geological Heritage Grade Distribution Mapping Using GIS (공간정보를 이용한 지질유산 등급분포도 작성 연구)

  • Lee, Soo-Jae;Lee, Sunmin;Lee, Moung-Jin
    • Korean Journal of Remote Sensing
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    • v.33 no.5_3
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    • pp.867-878
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    • 2017
  • Recent interest in geological heritage has been increased in that it can be used as a basic data onto predicting the global environmental change of its containing information about past global environment. In addition, due to the characteristics of the geological heritage, it is easy to damage and difficult to recover without continuous preservation and management. However, there are more damages occurring because of the sporadic spatial distribution and ambiguous management authority of geological heritage. Therefore, an integrated management system is needed by determining the spatial distribution of geological heritage preferentially. In this study, the detailed criteria for assessment of value from the preliminary studies were applied and the geological heritage grade distribution map was generated by using geospatial data in Seoul metropolitan area. For this purpose, the list of geological heritage sites in the Seoul metropolitan area, which is the study area, were complied through a literature review. The geospatial database was designed and constructed by applying the detailed criteria for assessment of value from the preliminary studies. After the construction of the spatial database, a grade map of the geological heritage was created. As a result of the geological heritage grade map in the Seoul metropolitan area, there were more than 35% of the geological heritage in northern Gyeonggi provinces such as Yeoncheon city (18.8%), Pocheon city (10.6%) and Paju city (6.3%). It is followed by 18.1% in Incheon and 8.1% in Ansan, which is approximately 26.2% in western Gyeonggi Province. The geological age of the geological heritage was the highest at in the fourth stage of the Cenozoic era of 16.9%. Through the results of this study, the geological heritage data of the Seoul metropolitan area were extracted from existing literature data and converted into spatial information. It enables comparing the geological features with the spatial distribution of geological heritage. In addition, a management system has been established based on spatial information of constantly building geological heritage data. This provides the integrated management system of the geological heritage to manage authority so that it can be used as a basis for the development of the geological park. Based on the results of this study, it is considered to be possible to systematically construct and utilize the geological heritage across the country.