• Title/Summary/Keyword: 생화학적 부식

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금속 및 금속염계 항균제가 혼입된 항균 콘크리트 개발 (Development on Antibiotic Concrete Mixed with Antibacterial Metals and Metallic Salts)

  • 최홍식;허권;이호범;이시우;곽홍신
    • 한국건설순환자원학회논문집
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    • 제1권2호
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    • pp.136-143
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    • 2013
  • 하수시설 및 복개 구조물 등은 용해 시 산성으로 작용하는 황화수소에 크게 노출되어, 황산화균의 작용에 의해 강산성의 황산이온이 생성된다. 이에 따라 콘크리트의 생화학적 부식에 의한 열화가 촉진되며, 콘크리트 손상을 더욱 가속화하여 내구성이 크게 저하될 수 있다. 본 연구에서는 콘크리트에서 황산화균이 유기 생체적으로 사용하는 황화수소를 제거하기 위해, 금속의 살균성을 이용하여 금속 및 금속염 분말을 콘크리트에 혼입한 후, 황산화 억제 성능을 평가하였다. 이를 위해 중성화한 콘크리트 시편의 황산화균에 대한 항균 성능을 비교 평가하였고, 급속 염소이온 침투시험을 통해 금속 및 금속염계 항균제 첨가량에 따른 콘크리트 염화물 침투깊이 및 확산계수를 측정하였다. 또한 야외에서 폭로시킨 콘크리트 시편의 표면 상태의 생화학적 상태를 관측하여, 항균콘크리트의 성능 및 적용성을 확인하였다.

항균제를 도포한 하수시설 콘크리트의 생화학적 부식특성 평가를 위한 폭로시험 (An Exposure Experiment for the Evaluation of Corrosion Properties of Sewage Concrete Covered with Antibiotics)

  • 노경민;이의배;김영덕;이병기;김규용;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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    • pp.73-76
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    • 2006
  • Sewage facilities mainly consisted of concrete structures are being deteriorated seriously by biodeterioration originated from sulfur-oxidizing bacteria. To prevent biochemical corrosion of the sewage concrete, antibiotics which prevent growth of sulfur-oxidizing bacteria were developed. Recently, to evaluate biochemical corrosion properties of concrete, antimicrobial performance and resistance to sulfuric acid were investigated respectively. But, in this study, to evaluate it complexly, concrete specimen covered with antibiotics were exposed in the actual sewage environment and were investigated about corrosion properties after three months. As a result, weight change ratio, nature potential and sulfuric ratio of concrete covered with antibiotics were less than plain concrete.

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하수시설 콘크리트의 생화학적 부식특성 평가를 위한 실내 인공촉진 시험방법 (A Testing Method of Indoor Artificial Acceleration for the evaluation of Biochemical Corrosion Properties of Sewage Concrete)

  • 이의배;김도수;길배수;이승훈;김규용;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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    • pp.69-72
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    • 2006
  • Recently sewage facilities mainly consisted of concrete structures are being deteriorated seriously by biodeterioration originated from sulfur-oxidizing bacteria. To prevent biochemical corrosion of the sewage concrete, antibiotics which prevent growth of sulfur-oxidizing bacteria were developed. Existing methods to evaluate properties of biochemical corrosion of concrete examine the antimicrobial performance and resistance to sulfuric acid separately, but don't complexly. So, in this study, new method to test properties of biochemical corrosion of concrete complexly is suggested.

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항균제를 도포한 하수시설용 단면복구 모르타르의 기초물성 및 내구특성에 관한 실험적 연구 (An Experimental Study on the Fundamental Properties and Durability of Sewer Type Restorative Mortar Spread with Antibiotics)

  • 김무한;김규용;김재환;조봉석;이동혁
    • 한국구조물진단유지관리공학회 논문집
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    • 제10권3호
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    • pp.195-202
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    • 2006
  • 하수시설 콘크리트의 열화현상은 하수시설의 특수한 환경조건상 황산화세균 등의 서식에 의해 발생된 황화수소($H_2S$)에 기인하는 생화학적 부식이 대표적인 것으로 알려져 있으나, 국내의 경우 근본적으로 방지대책이 전혀 고려되지 않은 채 정비사업이 수행되고 있어 근본적으로 황산화세균을 억제할 수 있는 보수재료 공법의 개발이 시급히 필요한 실정이다. 이에 본 연구에서는 항균금속을 포함한 도포형 항균제를 개발한 후, 개발된 항균제의 황산화세균에 대한 항균성능과 항균제를 도포한 단면복구재의 부착강도, 흡수 및 투기저항성, 중성화 깊이, 염화물이온 침투깊이 및 화학저항성 등의 기초물성을 평가하였다.

하수구조물용 항균콘크리트의 개발 및 현장적용 (Development of Antimicrobial Concrete for Sewage Structures and Application to Construction Field)

  • 김무한;김규용;이의배;이승훈;손유신
    • 한국건축시공학회지
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    • 제6권3호
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    • pp.91-97
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    • 2006
  • Sewage facilities are positively necessary for environment improvement such as rainwater removal, sewage disposal, preservation of the qualify of water and health of the citizens in present-day. Meanwhile, a deterioration of the concrete sewer pipe is increasing rapidly due to the chemical and physical attack and especially biochemical attack that is to say biodeterioration. In this study, researches for the development of antibiotics and antimicrobial concrete were conducted to reduce biochemical corrosion of sewage concrete. First of all, desired performance, such as watertightness, antibiosis, homogeneity, workability and harmlessness, was proposed and performance of antibiotics and antimicrobial concrete were evaluated by them. And developed antimicrobial concrete was applied to actual construction field. As results of this study, dispersibility and antibiosis of liquid antibiotics superior to powdery antibiotics. Antibiosis of antimicrobial concrete was verified, and amount of elution of harmful and effective ingredients was little. In workability, setting time of antimicrobial concrete was delayed. Compressive strength and resistance to carbonation of antimicrobial concrete were more increased than ordinary concrete. Finally, as there were no problems in quality and construction progress of antimicrobial concrete produced in plant, applicability of antimicrobial concrete to actual construction field was verified.

항균제를 도포한 콘크리트의 내구특성에 관한 실험적 연구 (An Experimental Study on Durability of Concrete Covered with Antibiotics)

  • 이의배;이동혁;문형재;김재환;김규용;김무한
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2005년도 추계 학술논문 발표대회
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    • pp.97-100
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    • 2005
  • Recently sewage facilities mainly consisted of concrete structures are being deteriorated seriously by biodeterioration originated from sulfur-oxidizing bacteria. In this study, to prevent biochemical corrosion of the sewer concrete, antibiotics which prevent the growth of sulfur-oxidizing bacteria were developed and antimicrobial performance of it was investigated. After that, to consider applicability of antibiotics to concrete, durability such as resistance to carbonation, salt damage and chemical attack of concrete covered with inorganic and complex antibiotics were investigated. As a result of this study, it was proved that the antimicrobial performance of antibiotics was available. Also resistance to carbonation, salt damage and chemical attack of concrete covered with inorganic antibiotics was little improved but, in case of complex antibiotics, was remarkably improved. Moisture content of concrete, as a application condition of antibiotics in whole case, have little effect on performance but covering times of antibiotics have effect on performance only in case of complex antibiotics.

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해상가두리에서 북방전복 Haliotis discus hannai와 둥근전복속 교잡종(왕전복 H. madaka♀*둥근전복 H. discus discus♂)의 생물지표 비교 (Comparison of Biomarkers of Haliotis discus hannai and Hybrid Abalone (H. madaka♀*H. discus discus♂) in Marine Net Cage)

  • 김현진;신소령;김성진;박정준;이정식
    • 한국해양생명과학회지
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    • 제7권2호
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    • pp.163-170
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    • 2022
  • 본 연구에서는 해상가두리 양식장에서 북방전복과 둥근전복속 교잡종(왕전복♀*둥근전복♂)의 생물지표를 분석하여 교잡육종의 결과를 평가하고자 하였다. 생존율은 북방전복과 유사하였으나, 성장(각장)은 교잡종에서 약 10% 빠른 것으로 분석되었다. 패각의 호흡공 기형율은 교잡종이 북방전복보다 약 6% 낮았으며, 패각 함몰 및 부식율은 교잡종이 약 15% 낮았다. 생화학적 조성에서는 조단백질의 경우 교잡종에서 약 3.1% 높았으며, 이를 제외한 나머지에서 유사한 값을 나타냈다. 소화, 흡수 및 해독기능을 수행하는 간췌장의 조직학적 평가에서는 교잡종에서 좋은 결과를 보였다. 이러한 결과로 보아 둥근전복속 교잡종은 추후 양식 환경에 접목하였을 때 높은 양식 생산력을 가질 것으로 판단된다.

무기질 항균제 도포에 의한 콘크리트의 경화성상 및 내구성상 향상에 관한 실험적 연구 (An Experimental Study on Development of Physical Properties and Durability of Concrete Spread with Inorganic Antibiotics)

  • 김무한;길배수;김재환;조봉석;이의배
    • 한국건축시공학회지
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    • 제5권3호
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    • pp.75-82
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    • 2005
  • Sewage facilities are positively necessary for environment improvement such as rainwater removal, sewage disposal, preservation of the quality of water and health of the citizens in present-day. Meanwhile, a deterioration of the concrete sewer pipe is increasing rapidly due to the chemical and physical attack and especially biochemical attack that is to say biodeterioration. So, in advanced countries, prediction techniques and corrosion inhibition system for sewer concrete are developed and are being applied. Also, antibiotics were developed already but application of that is low because it is not economical and has no practical use. But, in domestic, countermeasures for the corrosion of sewage concrete are not sufficient and biochemical attack is not reflected in those essentially. In this study, to prevent biochemical corrosion of the sewer concrete, surface of the concrete was spread with liquefied inorganic antibiotics and then its engineering properties were experimentally investigated. As a result, compressive strength of the specimen spread with antibiotics were similar to those of non spread, Both bond strength and abrasion amount of the specimen spread with antibiotics were inferior to non spread. Properties of absorption and air permeability of the specimen spread with antibiotics were superior to non spread. Finally, carbonation depth, chloride ion penetration depth and weight change ration of the specimen spread with antibiotics were smaller than non spread.

액상 항균제를 도포한 하수시설용 단면복구재의 내구특성에 관한 실험적 연구 (An Experimental Study on the Durability Properties of Repair Mortar for Sewer Spread with Liquefied Antibiotic)

  • 이동혁;장재봉;나철성;조봉석;김재환;김무한
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2005년도 춘계 학술기술논문발표대회 논문집
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    • pp.211-214
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    • 2005
  • Recently, Deterioration of the concrete sewer concrete structures by biochemical corrosion has been issued and a development of the inhibition system of corrosion that has been demanded. The sulfuric acid may react with the hardened cement paste and originate expansive products which can induce swelling and breakless of concrete. Also, a sulphuric acid reacts with calcium hydroxide to from $CaSO_4\;\cdot\;2H_2O$. This reaction accounts for consumption of the calcium hydroxide present in hardened cement paste. In this study, To present from biochemical corrosion of the sewer repair mortar that was spread with liquefied antibiotic and then its experimental properties were experimentally investigated and to estimate the effect of absorbed condition of restorative mortar, the number of coating times and coating contents with antibiotic on the durability properties of restorative mortar spread with antibiotics. Also, testing items such as carbonation depth, choloride ion penetration depth and chemical resistance was tested to estimate the durability properties in third study. In results, the novellus bacillus inhabiting in sewer concrete structures was restrained by antibiotics developed in this study. And carbonation depth, choloride ion penetration depth and chemical resistance of restorative mortar spread with antibiotics was superior to that of plain mortar.

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마그네슘 이온주입 임플란트의 뒤틀림 제거력에 관한 연구 (Removal Torque of Mg-ion Implanted Clinical Implants with Plasma Source Ion Implantation Method)

  • 김보현;김대곤;박찬진;조리라
    • 구강회복응용과학지
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    • 제25권1호
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    • pp.41-52
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    • 2009
  • 골과 임플란트의 기계적인 결합을 증진시키기 위한 다양한 시도가 이루어졌으며, 최근에는 불소 부식법, 양극산화법, 이온주입법 등 생화학적인 골유착을 유도할 수 있는 임플란트의 표면개질이 관심의 대상이 되고 있다. 본 연구는 플라즈마 상태의 이온을 임플란트 표면에 주입하여 이온 피막을 형성하는 방법(plasma source ion implantion, PSII)으로 표면을 개질한 임플란트에 대한 골반응을 흡수성 재료로 블라스팅 처리(resorbable blasting media, RBM)된 임플란트를 대조군으로 하여 평가하고 이온 주입량을 달리하여 비교한 결과를 알아보고자 하였다. 12마리의 뉴질랜드 가토의 경골에 대조군인 RBM 임플란트와 Mg이온 주입량을 달리한 Mg이온주입 임플란트 3개씩을 식립하고 공진주파수를 측정하였으며 6주 후 48개 임플란트의 뒤틀림 제거력과 공진주파수를 측정하였다. 반복측정이 있는 분산분석을 이용하여 95% 유의수준으로 통계적 유의성을 확인하여 다음과 같은 결과를 얻었다. 1. 각 임플란트간 공진주파수의 차이는 없었으나 군에 관계없이 식립 시에 비해 6주 후의 공진주파수는 증가하였다. 2. 초기 낮은 공진주파수를 나타낸 임플란트군의 공진주파수 증가량이 큰 경향을 나타내었다. 3. 이온잔존량 9.4%인 Mg 1 임플란트가 다른 임플란트 보다 통계적으로 유의하게 큰 뒤틀림제거력을 보였다. 이상의 결과를 종합하여 가장 우수한 골반응을 나타내는 이온주입량을 알 수 있었으며 이러한 이온주입 임플란트가 임상적으로 뛰어난 효능을 보이는 RBM 표면에 비해서도 생물학적 골반응이 더 우수하다는 것을 입증하는 결과라 할 수 있다.