• Title/Summary/Keyword: 생물학적 흡착

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Removal of Malodorous Gases Emitted from a Wastewater Pumping Stations by Biological Methods (생물학적 방법에 의한 하수 중계펌프장의 악취제거)

  • 류희욱
    • Microbiology and Biotechnology Letters
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    • v.32 no.3
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    • pp.265-270
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    • 2004
  • To select a promising technologies for removal of odorous gases emitted from a wastewater pump station, four methods such as activated carbon (A/C) adsorption, chemical absorption (acid and alkali scrubber), and two biofilters (polyurethane (PU) and worm cast) were investigated. The average odor removal efficiencies in the PU biofilter and A/C column was over 98%, but in a worm cast biofilter and chemical absorption were below 60-80%. The removal efficiency of PU biofilter was very stable (about 98-99%) in the range of retention times of 4-36s, and a maximum elimination capacity was $1.6${\times}$10^{ 7}$ $OUm^{-3}$$h^{-1}$ Deodorization costs for an activated carbon adsorption and a biofiltration method were investigated. With increasing odor intensity, the operating cost of the A/C column increased linearly, but the operating cost of the biofilteration increased slightly. The capital cost in a biofilter is about two times higher than that in an A/C column, but the operating cost is very lower than that of in A/C column. In conclusion, the biofiltration was evaluated one of the most promising technologies to control odor in a wastewater pump station.

Separation Technologies for the Removal of Nitrate-Nitrogen from Aqueous Solution (수용액으로부터 질산성질소 제거를 위한 기술)

  • Seo, Yang Gon;Jung, Se Yeong
    • Clean Technology
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    • v.23 no.1
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    • pp.1-14
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    • 2017
  • At high nitrate concentrations, water must be treated to meet regulated concentrations because it results in threat to human health and eutrophication of natural water. However, it is almost impossible to remove nitrate by conventional water treatment methods such as coagulation, filtration and precipitation, due to its high water solubility. Therefore, other technologies including adsorption, ion exchange, reverse osmosis, denitrification, and electrodialysis are required to effectively remove nitrate. Each of these technologies has their own strengths and drawbacks and their feasibility is weighted against factors such as cost, water quality improvement, residuals handling, and pre-treatment requirements. An adsorption technique is the most popular and common process because of its cost effectiveness, ease of operation, and simplicity of design. Surface modifications of adsorbents have been enhanced their adsorption of nitrate. The nitrate-selective membrane process of electrodialysis reversal and reverse osmosis have proven over time and at many locations to be highly effective in removing nitrate contaminating problems in aqueous solutions. Both electrodiaysis and reverse osmosis methods generate highly concentrated wastes and need careful consideration with respect to disposal.

Characteristics on the Removal of Emulsified Vegetable Oil in Wastewater using Bio logical Fluidized Bed (생물학적(生物學的) 유동층(流動層)을 이용(利用)한 수중(水中)의 식물성유(植物性油) 제거특성(除去特性))

  • Kim, Hwan Gi;Park, Ro Sam
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.10 no.3
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    • pp.127-136
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    • 1990
  • In this paper, the experimental study was carried out for the removal of olive oil in wastewater by the use of Biological Fluidized Bed(BFB) with the reticulated polypropylene sheets as media. The nonbiodegradable olive oil, one of the animal and vegitable oil, was used bacause of the relative simplicity of constitution. Biological degraciability and removal characteristics of emulsified olive oil were studied by batch and continuous experiments respectively. From the results of batch experiments, it was observed that the emulsified olive oli used in BFB reactor was absorbed by media and sludge in about 12 hours, and degradation of the absorbed olive oli was mostly completed for 24 hours. The functional relationship of Michaelis-Menten's Enzyme reaction equation exists between oil concentration and maximum specific rate of olive oil. From the continuous experiments for the removal of olive oil using BFB reactor, it was proved that the substrate removal rate coefficient $k=0.004d^{-1}$, which is the first order kinetics. It was apperared that oxygen utlization coefficients for synthesis(a') and endogeneous respiration(b') of microorganisms in the reactor are respectively 0.85mg $O_2/mg$ $COD_{cr}$ and 0.011mg $O_2/mg$ BVS. day.

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Biodegradation of Recalcitrant Chlorinated Aromatic Compounds via Microbial Dechlorination (미생물의 탈염소화 작용에 의한 난분해성 염화방향족 오염물질의 분해)

  • 채종찬;김치경
    • Korean Journal of Environmental Biology
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    • v.17 no.2
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    • pp.129-138
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    • 1999
  • Chlorinated aromatic compounds are one of the largest groups of environmental pollutants as a result of world-wide distribution by using them as herbicides, insecticides, fungicides, solvents, hydraulic and heat transfer fluids, plasticizers, and intermediates for chemical synthesis. Because of their toxicity, persistence, and bioaccumulation, the compounds contaminated ubiquitously in the biosphere has attracted public concerns in terms of serious influences to wild lives and a human being, such as carcinogenicity, mutagenicity, and disturbance in endocrine systems. The biological recalcitrance of the compounds is caused by the number, type, and position of the chlorine substituents as well as by their aromatic structures. In general, the carbon-halogen bonds increase the recalcitrance by increasing electronegativity of the substituent, so that the dechlorination of the compounds is focused as an important mechanism for biodegradation of chlorinated aromatics, along with the cleavage of aromatic rings. The removal of the chlorine substituents has been known as a key step for degradation of chlorinated aromatic compounds under aerobic condition. This can occur as an initial step via oxygenolytic, reductive, and hydrolytic mechanisms. The studies on the biochemistry and genetics about microbial dechlorination give us the potential informations for microbial degradation of xenobiotics contaminated in natural microcosms. Such investigations might provide biotechnological approaches to solve the environmental contamination, such as designing effective bioremediation systems using genetically engineered microorganisms.

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Removal of Methylene Blue in Water Phase by Using Juniperus chinensis (향나무를 활용한 수중에서 메틸렌 블루의 제거)

  • Choi, Suk Soon;Ha, Jeong Hyub
    • Applied Chemistry for Engineering
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    • v.29 no.3
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    • pp.278-282
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    • 2018
  • The development of treatment technologies for recycling waste woods generated from tree pruning is required in Gangwon province forest. In this study, according to adsorption experiments using three types (Larix kaemoferi, Juniperus chinensis, Pinus densiflora) of waste woods, Juniperus chinensis as a biosorbent showing an excellent removal ability was selected for the removal of methylene blue in an aqueous phase. When 0.4 g/100 mL of Juniperus chinensis was used to improve the removal efficiency of methylene blue for 4 h, each 100, 200 and 300 mg/L of methylene blue dissolved in the aqueous phase were removed to 98, 93, and 81%, respectively. The adsorption equilibrium data obtained by changing adsorbent concentrations was found to be more consistent with the Langmuir than the Freundlich equation. In addition, based on dynamic experiments by changing the methylene blue concentration, the biosorption kinetics equation was more suitable for a pseudo-second order model. In order to enhance the removal capability of highly concentrated methylene blue, 300 and 400 mg/L of methylene blue were operated for 4 h under 210 rpm of agitation velocity and removal efficiencies were 92 and 76%, respectively. Consequently, these experimental results can be effectively utilized as a new biosorption technology for economically treating methylene blue dissolved in an aqueous phase.

Cytochemical and Biochemical Characteristics of Cellular Adhesion in Amoeba proteus (Amoeba proteus의 표면흡착에 관한 세포화학 및 생화학적 특성)

  • 안태인;곽인희
    • The Korean Journal of Zoology
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    • v.29 no.3
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    • pp.171-180
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    • 1986
  • The effects of proteases, neuraminidase and EDTA on adhesion of amoebae on the substratum, ultrastructure and biochemical composition of the cell surface were studied by concanavalin A (con A) cytochemistry and SDS PAGE. By con A cytochemistry the glycocalyx of the plasmalemma was easily subdivided into outer filamentous (F) layer and the inner amorphous (A) layer. On treatment with neuraminidase, amoebae attached to the substratum and spreaded better than untreated cells exposing the more con A binding sites in A- and F-layer. When the cells were treated with trypsin or proteinase K, cells stayed unattached for 12 and 48 hr, respectively. Con A binding sites of A layer and all of those glycoproteins were removed by proteinase K. On the other hand, trypsin damaged all of the con A binding sites in both A- and F-layer without significant change in PAS-stained profile of the plasmalemma. Some of the mucopolysaccharides of the cell surface were released by these enzymes and EDTA. When the cells were incubated with monovalent con A they did not attch on the substratum and cytolysed. From these results adhesion of amoebae on the substratum appears to be mediated by the interaction of the glycoproteins and mucopolysaccharides of the A layer.

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Operating Parameters and Performance of Biotrickling Filtration for Air Pollution Control (대기오염물질 제어를 위한 생물살수여과법의 운전인자와 성능평가)

  • Won, Yang-Soo
    • Applied Chemistry for Engineering
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    • v.16 no.4
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    • pp.474-484
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    • 2005
  • Biological treatment is a promising alternative to conventional air pollution control methods. Bioreactors for air pollution control have found most of their success in the treatment of dilute and high flow waste air streams containing volatile organic compounds and odor compounds. They offer several advantages over traditional technologies such as incineration or adsorption. These include lower treatment costs, absence of formation of secondary pollutants, no spent chemicals, low energy demand and low temperature treatment. The most widely used bioreactor for air pollution control is biofilter, but it has several limitations. In the past years major progress has been accomplished in the development of vapor phase bioreactor, in particular biotrickling filters. Biotrickling filters are more complex than biofilters, but are usually more effective, especially for the treatment of compounds which are difficult to degrade or compounds that generate acidic by-products. While the level of understanding of biotrickling filtration process for VOCs still remains limited, the evident success of biotreatment of VOC in air stimulated the pursue of acitve research. This paper presents fundamental and theoretical/practical aspect of air pollution control in biotrickling filter. Special emphasis is given to the operating parameters and the factors influencing performance for air pollution control in biotrickling filter.

Effect of Ozonation on Removal of Dissolved Organic Matter by Granular Activated Carbon Process (오존공정이 입상활성탄공정에서 용존유기물질의 제거에 미치는 영향)

  • Ahn, Hyo-Won;Chae, Seon-Ha;Wang, Chang-Keun;Lim, Jae-Lim
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.6
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    • pp.601-608
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    • 2008
  • The objective of this study was to evaluate the effect of ozonation as pretreatment on the removal of dissolved or biodegradable organic matter(DOM or BOM), the variance of DOM fractionation, and microbial regrowth by pilot-scale granular activated carbon processes in which adsorption and biodegradability was proceeding due to long time operation. Regardless of point of ozonation applied, GAC processes with ozonation(i.e., Ozonation combined with GAC Filter-adsorber; Pre O$_3$ + F/A, Ozonation combined with GAC adsorber; Post O$_3$ + GAC) compared with GAC processes without ozonation(i.e., GAC Filter-adsorber; F/A, GAC adsorber; GAC) removed approximately 10 to 20% more of DOC, hydrophilic DOM(HPI), BDOC and AOC after long period of operation that biological activity was assumed to happen. Ozonation was not found to have a significant effect on the removal of DOC, but caused the decrease of AOC by approximately 20%. It was found that the fixed bacterial biomass on GAC media did not show a significant difference between the GAC with ozonation and GAC without ozonation as pre-treatment, whereas the HPC of column effluent was more biostable at Post O$_3$ + GAC compared with F/A or GAC.

A Mathematical Model Proposed for the Prediction of the Fate of Priority Organic Pollutants Spilled in Streams: Dynamic Simulations and Sensitivity Analysis (하천에 유입된 유독성 유기오염물의 농도분포를 예측하기 위한 수학적 모형의 개발: Dynamic simulations 및 민감도 분석)

  • Ko, Kwang Baik
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.2
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    • pp.265-274
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    • 1992
  • A mathematical model was proposed to predict the fate of a priority organic pollutant, anthracene, accidently spilled into a stream. The model consists of 6 differential equations with 5 input variables and 9 rate constants. Volatilization, biodegradation, adsorption/desorption, photodegradation as well as the convective inputs and outputs are included in the model. As a result of a series of dynamic simulations and sensitivity analyses under the given conditions, the concentrations of the organic chemical could be predicted within a detection limit in the stream. It was also suggested that the rate constant for diffusion/transport and adsorption rate constant are the most influential ones for predicting the chemical conentrations in dissolved and particulate phase. The model proposed appears to be a useful tool for assessing chemical spills.

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오존 전처리 공정이 생물활성탄 공정의 효율에 미치는 영향

  • Lee, Sang-Hun;Mun, Sun-Sik;Sin, Jong-Cheol;Choe, Gwang-Geun;Park, Dae-Won;Sim, Sang-Jun;Lee, Jin-Won
    • 한국생물공학회:학술대회논문집
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    • 2002.04a
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    • pp.361-364
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    • 2002
  • BAC (biological activated carbon) process is a combination of biodegradation and active carbon adsorption. Pre-ozonation of raw water increased in biodegradable organic fraction. This study is to investigate the enhancement of dissolved organic matter removals by pre-ozonation process combined with BAC process at a semi-pilot scale. By biodegradation improvement in pre-ozonation process. the charge of adsorption was reduced and the life of biological activated carbon is extended. And, 48 % of total DOC was remove in the upper compartment of BAC column. The removal of the nitrogen-ammonia shows a considerably high removal ratio with 75.9 %.

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